The present invention provides an integrated hydrogen production and charging system, including a hydrogen generator, a compressor, a heat exchanger, a pressure swing adsorption device, a vacuum pump, and a hydrogen charger. The hydrogen generator generates hydrogen by methanol reforming. The hydrogen generator makes the generated hydrogen pass through a palladium membrane purification device in the hydrogen generator for a first purification. The compressor compresses the hydrogen from the hydrogen generator. The heat exchanger, connected to the compressor, cools down the compressed hydrogen. The pressure swing adsorption device, connected to the heat exchanger, performs a second purification on the cooled down hydrogen by adsorption. The vacuum pump, connected to the pressure swing adsorption device, depressurizes the pressure swing adsorption device during desorption. The hydrogen charger charges the hydrogen from the pressure swing adsorption device into one or more metal alloy hydrogen storage tanks.

A system and method for producing hydrogen, including providing hydrocarbon and steam into a vessel to a region external to a tubular membrane in the vessel. The method includes steam reforming the hydrocarbon in the vessel via reforming catalyst to generate hydrogen and carbon dioxide. The method includes diffusing the hydrogen through the tubular membrane into a bore of the tubular membrane, wherein the tubular membrane is hydrogen selective.

Disclosed herein is a porous membrane comprising a porous substrate; a porous ceramic coating disposed on the porous substrate; where an average pore size of pores in the porous substrate are larger than an average pore size of pores in the porous coating. Disclosed herein is a method of manufacturing a porous membrane comprising disposing upon a porous substrate a porous ceramic coating, where the porous ceramic coating has an average pore size that is less than an average pore size of the porous substrate.

A process for recycling and reusing supported Pd membranes includes the separation of the Pd (or Pd alloy) layer from the support by contacting the Pd membrane with hydrogen under pressure and at low temperature and then with a second gas that is different from hydrogen. The Pd layer separated from the support can then be treated to solubilize the Pd and, where appropriate, the alloy metal(s) to obtain salts that can be reused, for example in the preparation of new Pd membranes. The recovered supports are also reusable.

The disclosure relates to a method of producing a multi-metal catalyst film and of producing a reactor system for catalytic removal of a wide variety of contaminants (for example, nitrate, nitrite, perchlorate, chlorate, chromate, selenate, chlorophenols, 2,4-D, dicamba, atrazine, trichloroacetic acid, bromochloroiodomethane, NDMA, TCE, TCA, chloroform, freons, RDX, HMX, TNT, PFOA, and PFOS) from water and wastewater. The disclosure also relates to a method of using the multi-metal catalyst for the removal of such contaminants and a system comprising the multi-metal catalyst film for removing such contaminants.

Disclosed herein are catalytic proton transport membranes and methods of making an use thereof. The catalytic proton transport membranes comprising a two-dimensional (2D) material having a top surface and a bottom surface, wherein the top surface further comprises a catalytic material deposited thereon, wherein the membrane allows for proton transport through the membrane.

The present invention relates to processes for recovering H.sub.2 from converting NH.sub.3 in an apparatus, the processes comprising one or more process stages, and an apparatus for these processes.

A method can include performing a series of reactions in a closed cycle, the series of reactions consisting of a hydrolysis reaction where a redox reagent is oxidized to a corresponding oxidized redox reagent with water contemporaneously with the production of hydrogen; and a reduction reaction where the oxidized redox reagent is reduced to the redox reagent using a sulfurous reactant contemporaneously with production of sulfur dioxide.

The present disclosure provides systems and methods for the processing of exhaust gas of a fusion reactor by direct internal recycling using metal foil pumps. One aspect of the disclosure is a system for the continuous or semi-continuous processing of plasma exhaust of a fusion reactor, comprising one or more metal foil pumps, the one or more metal foil pumps configured to operate at a temperature withing a range of approximately 25 C. to approximately 200 C. Another aspect is a system for direct internal recycling of deuterium and tritium, comprising: a feed region, a permeate region, and one or more metal foil pumps, configured to selectively allow hydrogen isotopes in the plasma exhaust to permeate therethrough into the permeate region, and to selectively absorb or repel helium in the plasma exhaust The one or more metal foil pumps may comprise a material selected from the group consisting of palladium, a palladium-copper alloy, a palladium-silver alloy, iron, and combinations thereof.

A process includes feeding atmospheric air to an air separation unit to produce a flow of nitrogen and a flow of oxygen; combining the oxygen with a hydrocarbon flow and water in an auto-thermal reformer to produce a retentate stream to a membrane water gas shift reactor (M-WGSR); generating, from the retentate stream to the M-WGSR, a permeate stream from the M-WGSR that includes a first flow of carbon dioxide and a first combined flow of hydrogen and nitrogen; feeding a retentate stream to a membrane steam methane reformer (M-SMR) to produce a permeate stream from the M-SMR that includes a second flow of carbon dioxide and a second combined flow of hydrogen and nitrogen; feeding the first and second combined flows to an ammonia synthesis unit to produce ammonia; and feeding the first and second flows of carbon dioxide and the ammonia to a urea synthesis unit to produce a flow of urea by fully utilizing the carbon dioxide.