A process and a plant for purifying a crude gas stream containing sulfur components and hydrocarbons by gas scrubbing using a scrubbing medium which is selective for sulfur components in an absorption column. Heavy hydrocarbons and heavy mercaptans are removed from the crude gas in a lower section of the absorption column and the resulting, loaded scrubbing medium stream is fed separately from the other loaded scrubbing medium streams to a hot regeneration column. A vapor stream enriched in water, hydrocarbons and sulfur components is obtained as overhead product from the hot regeneration column and this stream is cooled to below its dew point and is separated in a gas-liquid-liquid phase separation apparatus. The resulting, organic liquid phase contains heavy hydrocarbons and heavy mercaptans and can thus be discharged from the process or the plant, as a result of which accumulation thereof in the scrubbing medium is prevented.

The invention relates to dispersions of porous solids in liquids selected from deep eutectic solvents, liquid oligomers, bulky liquids, liquid polymers, silicone oils, halogenated oils, paraffin oils or triglyceride oils, as well as to their methods of preparation. In embodiments of the invention, the porous solids are metal organic framework materials (MOFs), zeolites, covalent organic frameworks (COFs), porous inorganic materials, Mobil Compositions of Matter (MCMs) or a porous carbon. The invention also relates to the use of porous materials to form dispersions, and to assemblages of such dispersions with a gas or gases. The dispersions can exhibit high gas capacities and selectivities.

Capture of hydrogen sulfide from a gas mixture may be accomplished using an aqueous solution comprising an amine. Certain sterically hindered amines may selectively form a reaction product with hydrogen sulfide under kinetically controlled contacting conditions and afford a light phase and a heavy phase above a critical solution temperature, wherein the hydrogen sulfide may be present in either phase. Upon separation of the light phase from the heavy phase, processing of one of the phases may take place to remove hydrogen sulfide therefrom. Recycling of the amine to an absorber tower may then take place to promote capture of additional hydrogen sulfide.

The disclosure provides an apparatus, as well as associated systems and methods for removing acid gas components from gas streams. The disclosure provides a rotating packed bed (RPB)-based absorber with a non-aqueous liquid solvent contained therein for treatment of the gas streams, wherein the non-aqueous liquid solvent captures acid components from the gas stream. Various advantages, e.g., with respect to spatial considerations and associated expenses can be realized using the apparatus, systems, and methods described herein.

The present disclosure relates to a porous liquid or a porous liquid enzyme that includes a high surface area solid and a liquid film substantially covering the high surface area solid. The porous liquid or porous liquid enzyme may be contacted with a fluid that is immiscible with the liquid film such that a liquid-fluid interface is formed. The liquid film may facilitate mass transfer of a substance or substrate across the liquid-fluid interface. The present disclosure also provides methods of performing liquid-based extractions and enzymatic reactions utilizing the porous liquid or porous liquid enzyme of the present disclosure.

This invention relates to a dispersion comprising porous particles dispersed in a liquid phase, wherein the porous particles comprise a zeolite and the liquid phase is a size-excluded liquid. The invention also relates to a method of adsorbing a gas into a liquid, comprising at least the step of bringing the gas into contact with the dispersion. In addition, the invention relates to an assemblage of the dispersion, the zeolite comprising a cavity and a gas contained within the cavity.

An apparatus includes a housing that defines a first zone, a second zone, a third zone, and a fourth zone. The apparatus includes an inlet, a first outlet, a second outlet, and a conveyor belt. The inlet is configured to receive a carbon dioxide-containing fluid in the first zone. The first outlet is configured to discharge a carbon dioxide-depleted fluid from the first zone. The second outlet is configured to discharge a carbon dioxide-rich fluid from the third zone. The conveyor belt passes through each of the zones. The conveyor belt includes a carbon dioxide sorbent. Within the first zone, the carbon dioxide sorbent is configured to adsorb carbon dioxide from the carbon dioxide-containing fluid to produce the carbon dioxide-depleted fluid. Within the third zone, the carbon dioxide sorbent is configured to desorb the captured carbon dioxide to produce the carbon dioxide-rich fluid.

The disclosure provides an apparatus, as well as associated systems and methods for removing acid gas components from gas streams. The disclosure provides a rotating packed bed (RPB)-based absorber with a non-aqueous liquid solvent contained therein for treatment of the gas streams, wherein the non-aqueous liquid solvent captures acid components from the gas stream. Various advantages, e.g., with respect to spatial considerations and associated expenses can be realized using the apparatus, systems, and methods described herein.

The invention relates to an absorber column and to the use thereof for separation of unwanted, especially acidic, gas constituents, for example carbon dioxide and hydrogen sulfide, from a crude synthesis gas by absorption with an absorbent, especially under low load states of the absorber column in relation to the synthesis gas velocity. According to the invention, a defined concentration of carbon dioxide in the clean synthesis gas is established by mixing at least a portion of the absorbent regenerated by flash regeneration with the absorbent regenerated by means of hot regeneration prior to the recycling thereof into the absorber column.

An absorption column including at least one external heat exchange circuit for cooling or heating the absorption liquid, including one or more serially connected heat exchangers, wherein the junction of the pipeline for withdrawal of the absorption liquid from the column is disposed above the junction of the pipeline into the first heat exchanger in the flow direction, wherein the pipeline also includes a dumped bed.