An object of the present invention is to provide a composition for forming an undercoat layer capable of forming an undercoat layer that does not easily peel off from the substrate, an undercoat layer formed by the composition, as well as an exhaust gas purification catalyst and an exhaust gas purification apparatus each including the undercoat layer, and, to achieve the object, the present invention provides a composition for forming an undercoat layer, the composition containing tin oxide microparticles and tin oxide nanoparticles, wherein a content of the tin oxide nanoparticles is 8% by mass or more and 30% by mass or less, with respect to a total content of the tin oxide microparticles and the tin oxide nanoparticles, an undercoat layer formed by the composition, as well as an exhaust gas purification catalyst and an exhaust gas purification apparatus each including the undercoat layer.

Described herein are separation articles such as, for example, films, membranes and the like separating at least one component from a gaseous mixture comprising two or more components comprising difluoromethane (HFC-32, CH.sub.2F.sub.2) and pentafluoroethane (HFC-125, C.sub.2F.sub.5H). The disclosed articles include a “selective layer” that is selectively permeable for the desired component to be separated from the gas mixture. The selective layer is composed of an amorphous fluorinated copolymer. Optionally, the article may include other layers which serve various purposes such as, for example, a porous support layer, a “gutter layer,” which allows the permeate gas to pass from the selective layer to the porous layer with minimal flow impedance, and a protective layer, which protects the selective layer from fouling. Each component of the separation articles described herein and methods for making and using the same are provided below.

A gas separation apparatus includes a separation membrane module including at least one gas separation membrane element in a housing, a casing for blocking external air, and a heat source unit for adjusting a temperature of a heat medium with which the casing is filled. The casing holds greater than or equal to two separation membrane modules.

The present invention is directed to a method and system of purifying hydrogen supplied from a storage cavern, particularly to removing methane and other hydrocarbons from the hydrogen withdrawn from the cavern by using selective adsorption. The adsorbed impurities can be removed from the adsorbent by increasing the temperature, reducing the pressure, or a combination of both.

The present invention relates to a method for modifying the crystalline inorganic framework of an adsorbent with coatings to provide rate selectivity for one gas over others is described. The method described herein narrows the effective pore size of crystalline porous solids with pores less than about 5 Å for rate selective separations. This method of the invention comprises treating the hydrated or partially hydrated zeolite with a silicone derived binding agent followed by subsequent heat treatment. The additive content and treatment are adjusted to match effective pore size to specific separations. The superior adsorbent has the added convenience of bead forming simultaneously with pore modification as well as having the treatment result in the yielding of high crush strength products.

Disclosed is a methane oxidation catalyst, and methods of use, the catalyst having a support comprising alumina doped with lanthanum and comprising platinum and palladium as the principle active phases. The platinum and palladium are present in the catalyst in a weight ratio of between 0.20:1.0 and 0.75:1.0, at an amount effective 5 for producing a product gas having reduced levels of methane as compared to a source gas prior to catalysis. Selected catalysts disclosed herein exhibit a capacity for sulfur and water resistance.

A method for recovering C2 components in a methane-containing industrial gas includes the steps of (1) cooling a compressed methane-containing industrial gas and performing gas-liquid separation; (2) absorbing C2 components in the gas phase by using an absorbent to obtain an absorption rich liquid; (3) returning the absorption rich liquid to the compression in step (1) or mixing the absorption rich liquid with the liquid phase obtained in step (1) to obtain a mixed liquid, and depressurizing the mixed liquid or the absorption rich liquid; (4) performing methane desorption on the depressurized stream to obtain a rich absorbent, or performing second gas-liquid separation on the depressurized stream, followed by methane desorption on the second liquid phase to obtain a rich absorbent; and (5) desorbing and separating the rich absorbent to obtain a lean absorbent and an enriched gas, and recycling and reusing the lean absorbent.

The invention relates to dense synthetic membranes made from polymerised phosphonium-based ionic liquids which were found to be particularly suitable for use in gas separation. The membranes are obtainable by copolymerization via UV-curing of a composition comprising a phosphonium-based ionic liquid monomer, a co-monomer, a cross-linker, a surfactant and a photo-initiator, the remainder of the polymerization mixture consisting of water. The invention also relates to a process of manufacturing said membranes, resulting in solid, dense and mechanically stable membranes, and to the use of the membranes so produced in the separation of gas mixtures, particularly gas mixtures containing carbon dioxide.

Hydrogen purification devices and their components are disclosed. In some embodiments, the devices may include at least one foil-microscreen assembly disposed between and secured to first and second end frames. The at least one foil-microscreen assembly may include at least one hydrogen-selective membrane and at least one microscreen structure including a non-porous planar sheet having a plurality of apertures forming a plurality of fluid passages. The planar sheet may include generally opposed planar surfaces configured to provide support to the permeate side. The plurality of fluid passages may extend between the opposed surfaces. The at least one hydrogen-selective membrane may be metallurgically bonded to the at least one microscreen structure. In some embodiments, the devices may include a permeate frame having at least one membrane support structure that spans at least a substantial portion of an open region and that is configured to support at least one foil-microscreen assembly.

A membrane modification method for improving liquid membrane separation of carbon dioxide (CO.sub.2) includes grafting an organic substance containing an amine group on a porous membrane material, and loading water into pore channels of the porous membrane material to prepare a supported liquid membrane for a gas mixture separation experiment of CO.sub.2. In the method, the amine group is introduced through chemical grafting to make the water being alkaline when used as membrane liquid. Compared with an alkaline solution as the membrane liquid, the method can avoid the loss of active alkaline substances and increase the permeation flux of CO.sub.2.