An apparatus for collecting a gaseous pollutant from air may comprise multiple vertical panel-beds each containing a solid sorbent; a fan to pass the air through the multiple vertical panel-beds and over the solid sorbent; an outlet gate configured to release the solid sorbent from the multiple vertical panel-beds after the fan passes the air over the solid sorbent; a regeneration vessel configured to regenerate the released solid sorbent by recovering the gaseous pollutant from the released solid sorbent; and a conveyor configured to return the regenerated solid sorbent to the multiple vertical panel-beds.

Metal Organic Framework (MOF) materials and methods of making MOF materials. The methods include grinding of mixtures of metal hydroxide(s) and ligand(s). The MOF materials may have at least two different ligands. The MOF materials may have open metal sites. The MOF materials can be used in gas storage applications.

A membrane including a polymer substrate having pore channels and a metal-organic framework disposed on the polymer substrate. Methods of producing the membrane are described. Methods of separating gases using the membrane are also provided.

Processes and apparatuses for recovering a high purity carbon dioxide stream. A first separation zone that may include a cryogenic fractionation column provides the high-purity CO.sub.2 stream. A vapor stream from the cryogenic fractionation column is passed to a second separation zone to separate the CO.sub.2 from the other components. The second separation zone may include a pressure swing adsorption unit or a solvent separation unit. The second separation zone provides a hydrogen enriched gas stream that may be used in a gas turbine. The second stream from the second separation zone includes carbon dioxide and, after a pressure increase in a compressor, may be recycled to the first separation zone.

A membrane is described for purifying or separating hydrogen from a multi-component gas stream such as syngas. This membrane uses a molecular pre-treatment, a transition metal, fluorine containing polymer, carbon fibers and carbon matrix sintered on a supportive screen. The membrane may be a bilayer membrane comprised of a layer containing high surface area carbon and another layer containing lower surface area carbon. Methods for purifying hydrogen are also described.

A carbon molecular sieve (CMS) membrane having improved separation characteristics for separating olefins from their corresponding paraffins is comprised of carbon with at most trace amounts of sulfur and a transition metal, wherein the transition metal is one or more of a group 4-10 and 12 transition metal. The CMS membrane may be made by pyrolyzing a precursor polymer devoid of sulfur in which the precursor polymer has had a transition metal incorporated into it. The pyrolyzing for the precursor having the transition metal incorporated into it is performed in a nonoxidizing atmosphere and at a heating rate and temperature such that the metal has a valence greater than zero (i.e., not metal bonded) to a valence desirably closer to its maximum valence.

A design is provided to convert a gas subcooled process plant to a recycle split vapor process for recovering ethane and propane from natural gas. When in operation, the recovery of ethane and propane can exceed 97 to 99 wt. % of the stream being processed. A second smaller demethanizer column is added to the gas subcooled process plant as well as the addition of several cryogenic pumps.

Methods and systems to decarbonize natural gas using sulfur to produce hydrogen and polymers are provided. Sulfur can be introduced in elemental form or as hydrogen sulfide, as may be desired. Decarbonization of natural gas involves introducing natural gas and H.sub.2S to a first reactor to produce first reactor products including CS.sub.2 and H.sub.2. The CS.sub.2 can subsequently be polymerized and the H.sub.2 recovered in a purified form with little or no carbon emissions.

Methods of contacting a fluid comprising a light hydrocarbon with a metal-organic framework adsorbent having bis(pyrazolyl) ethanediimine ligands and internal pores; adsorbing the fluid in at least a portion of the internal pores of the metal-organic framework thereby creating an adsorbed fluid; storing the adsorbed fluid in the internal pores of the metal-organic framework; and releasing the adsorbed fluid from the internal pores of the metal-organic framework, wherein the metal-organic framework adsorbent undertakes a reversible phase transition upon adsorbing the fluid. Systems of a metal-organic framework having bis(pyrazolyl) ethanediimine ligands and internal pores, wherein the metal-organic framework undertakes a reversible phase transition upon adsorption and desorption of a light hydrocarbon fluid; wherein the fluid is stored in the internal pores of the metal-organic framework.

A membrane modification method for improving liquid membrane separation of carbon dioxide (CO.sub.2) includes grafting an organic substance containing an amine group on a porous membrane material, and loading water into pore channels of the porous membrane material to prepare a supported liquid membrane for a gas mixture separation experiment of CO.sub.2. In the method, the amine group is introduced through chemical grafting to make the water being alkaline when used as membrane liquid. Compared with an alkaline solution as the membrane liquid, the method can avoid the loss of active alkaline substances and increase the permeation flux of CO.sub.2.