A pressure swing adsorption process for producing a gas stream enriched in a compound X from a feed gas stream is provided. The process includes at least 2 adsorbers, with each adsorber being subjected to a pressure cycle having a high pressure and a low pressure. The process includes adsorption at the high pressure with production of the gas stream enriched in compound X; then depressurization; then elution at the low pressure; and finally repressurization to the high pressure. The elution gas is made up fractions of gas stream resulting from the depressurization of an adsorber and the gas stream enriched in compound X. The pressure cycle has a phase time corresponding to the duration of a pressure cycle divided by the number of adsorbers and the fraction of the gas stream enriched in compound X is determined as a function of the phase time.

A pressure swing adsorption process for producing a gas stream enriched in a compound X from a feed gas stream is provided. The process includes at least 2 adsorbers, with each adsorber being subjected to a pressure cycle having a high pressure and a low pressure. The process includes adsorption at the high pressure with production of the gas stream enriched in compound X, depressurization to the low pressure with production of at least one portion of an elution gas, c) elution at the low pressure, and repressurization to the high pressure. The pressure cycle has a phase time corresponding to the duration of a pressure cycle divided by the number of adsorbers. The pressure of the pressure cycle is modified to keep the phase time of the PSA equal to or within 5% of the nominal phase time.

The present disclosure relates to a pressure swing adsorption apparatus for high purity hydrogen purification from ammonia decomposition and a hydrogen purification method using the same, and more specifically, the pressure swing adsorption apparatus includes a plurality of adsorption towers including a guard bed unit and a hydrogen purification unit, in which each adsorption tower is packed with different adsorbents, to purify high purity hydrogen from mixed hydrogen gas produced after ammonia decomposition, make it easy to replace the adsorbent for ammonia removal, minimize the likelihood that the lifetime of the adsorbent in the hydrogen purification unit is drastically reduced by trace amounts of ammonia, efficiently recover hydrogen of the guard bed unit, thereby maximizing the hydrogen recovery rate compared to a conventional pressure swing adsorption process including a pretreatment unit and a hydrogen purification unit, and respond to a large change in ammonia concentration in the raw material.

Provided herein is a method for improving a gas recovery rate during generation of a high-purity gas. The method includes providing three or more adsorption towers filled with an adsorbent that adsorbs an adsorption target gas. Performing a pressure lowering equalization process in a first adsorption tower in which an adsorption process has been finished, and in a source gas supply state in which a source gas is supplied to at least a second adsorption tower in which a pressure increasing equalization process has been finished and the adsorption process is to be subsequently performed; and transferring a non-adsorbed gas from an upper portion of the first adsorption tower to the upper portion of the second adsorption tower, thereby performing an adsorption and pressure lowering equalization process in the first adsorption tower and an adsorption and pressure increasing equalization process in the second adsorption tower.