A modified active carbon material for adsorption of airborne lower aldehydes. The activated carbon is impregnated with triethylenediamine (TEDA) and has a copper deposition. A filter media is formed from a method of preparing triethylenediamine (TEDA) activated carbon with deposited copper for removal of toxic formaldehyde from the environment, such as a process of making surface modified granular activated carbon media that is highly efficient in removing formaldehyde.

A xenon adsorbent capable of efficiently adsorbing xenon, even at a low concentration, from a mixture gas is Provided.

A xenon adsorbent comprising a zeolite having a pore size in the range of 3.5 to 5 and a silica alumina molar ratio in the range of 10 to 30.

A capture mass for heavy metals, in particular mercury, contained in a gaseous or liquid feed, said mass comprising: copper which is present at least in part in the sulphide form, Cu.sub.xS.sub.y; a porous support based on alumina;
characterized in that said porous support has a total pore volume (TPV) in the range 0.8 to 1.5 cm.sup.3/g, a mesopore volume (V.sub.6nm-100nm) in the range 0.5 to 1.3 cm.sup.3/g, and a macropore volume (V.sub.100nm) in the range 0.33 to 0.45 cm.sup.3/g,
it being understood that the ratio between the mesopore volume and the macropore volume (V.sub.6nm-100nm/V.sub.100nm) is in the range 1 to 5.

Metal-containing sorbent materials are provided, methods of making the metal-containing sorbent materials, methods of using the metal-containing sorbent materials, and metal complex-containing composite materials resulting from the sorption of basic, nitrogen-containing compounds on the metal-containing sorbent materials are provided. The sorbent materials are prepared by incorporating divalent metals into a precursor material that is formed by treating a porous siliceous material having mesopores with a silane or disilazane surface treatment agent. The metal-containing sorbent materials can be used to capture basic, nitrogen-containing compounds having a molecular weight no greater than 150 grams/mole.

A sorbent precursor is described comprising agglomerates of an inert particulate support material, the agglomerates being bound together with a binder comprising cement and/or clay, said binder being characterized as an agglomerate binder, wherein (a) the agglomerates are coated with a surface layer coating comprising a particulate copper compound and one or more coating binders, and (b) the surface layer has a thickness in a range of from 1 to 1000 m. The sorbent precursor may be sulphided to prepare a sorbent for removing heavy metals from fluid streams.

A composition that absorbs oxygen and emits carbon dioxide in response to absorbing oxygen including ascorbic acid, an organic acid, a catalyst that promotes oxidation of the organic acid and emission of carbon dioxide and a soluble transition metal salt characterized by multiple oxidation states.

A sulfur removal system including a first reactor and a second reactor that are located in series to one another each having an adsorbent that includes cobalt and copper on an activated carbon support, a method of desulfurizing a sulfur-containing hydrocarbon stream via the sulfur removal system, and a method of making the adsorbent. Various embodiments of the sulfur removal system, the desulfurizing method, and the method of making the adsorbent is also provided.

A sulfur removal system including a first reactor and a second reactor that are located in series to one another each having an adsorbent that includes cobalt and copper on an activated carbon support, a method of desulfurizing a sulfur-containing hydrocarbon stream via the sulfur removal system, and a method of making the adsorbent. Various embodiments of the sulfur removal system, the desulfurizing method, and the method of making the adsorbent is also provided.

Methods of sulfurizing metal containing particles in the absence of hydrogen are described. One method includes contacting a bed of metal containing particles with a gaseous stream comprising hydrogen sulfide and inert gas under reaction conditions sufficient to produce sulfided metal containing particles. The gaseous stream is introduced into a vertical reactor at an inlet positioned at the bottom portion of the reactor and any unreacted hydrogen sulfide and inert gas is removed at an outlet positioned above the inlet. The sulfided metal containing particles can be removed from the reactor and stored.

This invention relates in certain aspects to a process for removing oxygenates from a stream, preferably a hydrocarbon stream comprising contacting an organosilica material with the hydrocarbon steam, where the organosilica material is a polymer of at least one monomer of Formula [Z.sup.1OZ.sup.2SiCH.sub.2].sub.3, wherein Z.sup.1 represents a hydrogen atom, a C.sub.1-C.sub.4 alkyl group, or a bond to a silicon atom of another monomer and Z.sup.2 represents a hydroxyl group, a C.sub.1-C.sub.4 alkoxy group, a C.sub.1-C.sub.6 alkyl group or an oxygen atom bonded to a silicon atom of another monomer.