Described are composite adsorption media that contain two or more different types of adsorbent material in binder, that may preferably be prepared by additive manufacturing techniques, as well as methods of preparing the structures by additive manufacturing methods.

Described are composite adsorption media that contain two or more different types of adsorbent material in binder, that may preferably be prepared by additive manufacturing techniques, as well as methods of preparing the structures by additive manufacturing methods.

The present invention relates to a food waste dryer comprising: a main body in which a drying space is formed so that a portion thereof is open to the outside; a front door for closing the open portion of the main body; a drying basket which is disposed in the drying space of the main body and in which food is accommodated; an air circulation unit which includes a heater capable of heating the air of the drying space, and which suctions the air inside the drying space, and then blows, at the food waste, the air heated by the heater so as dry the food waste; a circulation pipe capable of discharging, to the outside through an exhaust pipe, the air that includes steam vaporized during a food waste drying process, and recirculating, to the drying space through a blowing pipe, the air heated by the heater; and a deodorizing device mounted on the outside of the main body so as to adsorb odor particles from the air discharged to the outside through the circulation pipe, thereby enabling the air to be deodorized, wherein the deodorizing device includes a deodorant comprising activated carbon and zeolite. According to the present invention, a fixed amount of steam, which is generated by vaporization and evaporation during the food waste drying process, is maintained, and the adsorption and deodorization performance of the odor particles can be improved.

The present invention relates to a food waste dryer comprising: a main body in which a drying space is formed so that a portion thereof is open to the outside; a front door for closing the open portion of the main body; a drying basket which is disposed in the drying space of the main body and in which food is accommodated; an air circulation unit which includes a heater capable of heating the air of the drying space, and which suctions the air inside the drying space, and then blows, at the food waste, the air heated by the heater so as dry the food waste; a circulation pipe capable of discharging, to the outside through an exhaust pipe, the air that includes steam vaporized during a food waste drying process, and recirculating, to the drying space through a blowing pipe, the air heated by the heater; and a deodorizing device mounted on the outside of the main body so as to adsorb odor particles from the air discharged to the outside through the circulation pipe, thereby enabling the air to be deodorized, wherein the deodorizing device includes a deodorant comprising activated carbon and zeolite. According to the present invention, a fixed amount of steam, which is generated by vaporization and evaporation during the food waste drying process, is maintained, and the adsorption and deodorization performance of the odor particles can be improved.

A composite comprising a hydroxyapatite and at least one additive which is present during hydroxyapatite synthesis. The additive may be embedded or incorporated into or coated onto the hydroxyapatite. The additive preferably increases the hydroxyapatite porosity, e.g., providing a higher pore volume and/or BET surface area than a hydroxyapatite material without additive. The additive preferably comprises an activated carbon, chitosan, hopcalite, clays, zeolites, sulfur, and/or a metal such as Al, Sn, Ti, Fe, Cu, Zn, Ni, Cu, Zr, La, Ce, in the form of metal, salt, oxide, oxyhydroxide, and/or hydroxide. The hydroxyapatite may be calcium-deficient. The composite is in the form of particles having a D50 of at least 20 μm, a BET surface area of at least 120 m.sup.2/g; and/or a total pore volume of at least 0.3 cm.sup.3/g. An adsorbent material comprising a composite or a blend of composite with a hydroxyapatite without additive, and its use for removal of contaminants such as Hg, Se, As, and/or B from an effluent.

The present invention generally relates to a pressure swing adsorption process for separating an adsorbate impurity from a feed stream comprising product gas, said process comprising feeding the feed stream to an adsorbent bed at a pressure of from about 60 psig to 2000 psig, wherein said adsorbent bed comprises adsorbent having: An isosteric heat of adsorption of from about 5 kJ/mol to about 30 kJ/mol, as determined by the LRC method, for the adsorbate, and an equivalent 65 kJ/mol or less isosteric heat of adsorption for the product,
wherein the adsorbent has a rate of adsorption for the adsorbate impurity that is at least 10 times greater than the rate of adsorption for the product gas as determined by the TGA method and recovering said product gas with a reduced a level of said adsorbate impurity. The invention also related to an adsorbent useful in PSA separations, particularly separating N.sub.2 from methane, CO.sub.2 from methane O.sub.2 from N.sub.2 and the like.

The present invention generally relates to a pressure swing adsorption process for separating an adsorbate impurity from a feed stream comprising product gas, said process comprising feeding the feed stream to an adsorbent bed at a pressure of from about 60 psig to 2000 psig, wherein said adsorbent bed comprises adsorbent having: An isosteric heat of adsorption of from about 5 kJ/mol to about 30 kJ/mol, as determined by the LRC method, for the adsorbate, and an equivalent 65 kJ/mol or less isosteric heat of adsorption for the product,
wherein the adsorbent has a rate of adsorption for the adsorbate impurity that is at least 10 times greater than the rate of adsorption for the product gas as determined by the TGA method and recovering said product gas with a reduced a level of said adsorbate impurity. The invention also related to an adsorbent useful in PSA separations, particularly separating N.sub.2 from methane, CO.sub.2 from methane O.sub.2 from N.sub.2 and the like.

Modified crystalline zeolite materials have a zeolite framework with both tetra-coordinate Lewis aluminum single sites and Brønsted aluminum sites. The tetra-coordinate Lewis aluminum single sites include aluminum atoms covalently bonded to a variable group and to two oxygen atoms and further coordinated to a third oxygen atom. The variable group may be alkyl, hydride, or hydroxyl. Methods for incorporating tetra-coordinate Lewis aluminum single sites into a crystalline zeolite material include contacting the crystalline zeolite material with a dialkylaluminum hydride R.sub.2AlH, where each R is alkyl, to react the dialkylaluminum hydride with the zeolite framework and form tetra-coordinate alkyl aluminum single sites. Heating the alkyl-aluminum zeolite induces β-hydride elimination of the alkyl groups, whereby tetra-coordinate aluminum hydride single sites are formed. By oxidizing the hydride-aluminum zeolite, at least a portion of the tetra-coordinate aluminum hydride single sites are converted to tetra-coordinate aluminum hydroxide single sites.

Modified crystalline zeolite materials have a zeolite framework with both tetra-coordinate Lewis aluminum single sites and Brønsted aluminum sites. The tetra-coordinate Lewis aluminum single sites include aluminum atoms covalently bonded to a variable group and to two oxygen atoms and further coordinated to a third oxygen atom. The variable group may be alkyl, hydride, or hydroxyl. Methods for incorporating tetra-coordinate Lewis aluminum single sites into a crystalline zeolite material include contacting the crystalline zeolite material with a dialkylaluminum hydride R.sub.2AlH, where each R is alkyl, to react the dialkylaluminum hydride with the zeolite framework and form tetra-coordinate alkyl aluminum single sites. Heating the alkyl-aluminum zeolite induces β-hydride elimination of the alkyl groups, whereby tetra-coordinate aluminum hydride single sites are formed. By oxidizing the hydride-aluminum zeolite, at least a portion of the tetra-coordinate aluminum hydride single sites are converted to tetra-coordinate aluminum hydroxide single sites.

A method for separating classes of hydrocarbon compounds from a feed stream including a hydrocarbon mixture is disclosed. The method includes the steps of passing a feed stream through a plurality of separation units arranged in a series in any order, wherein each separation unit has an adsorbent material; and separating classes of hydrocarbon compounds from the feed stream. When one of the plurality of separation units comprises an adsorbent material that is a metal organic framework selected from a zirconium, hafnium, cerium, or titanium-based metal organic framework, then another plurality of separation units includes an adsorption material that is different from the metal organic framework. The method is conducted in a liquid phase. The method can also use a single separation unit with a continuous cyclic bed apparatus. The method can be combined with refining and downstream processes.