The use of a palladium-doped zeolite for the adsorption of volatile organic compounds is described wherein the zeolite has a CHA framework type and is polymer-bound. Such zeolites have been found to have particular utility as packaging materials for the adsorption of volatile organic compounds, such as those originating from organic matter.

An adsorbent system including a body having or defining a channel therein, wherein the body is configured to be coupled to a humidity-controlled environment such that a first end of the channel is in selective fluid communication with the ambient environment and such that a second end of the channel is in fluid communication with said humidity-controlled environment. The system further includes an adsorbent material in the channel, wherein the channel and adsorbent material are configured such that inlet fluid flowing from the first end to the second end through the channel is flowable over the adsorbent material, and such that outlet fluid flowing from the second end to the first end is flowable over a majority of the adsorbent material that is flowable over by the inlet fluid. The system also includes a valve system positioned at or adjacent to or in fluid communication with the first end of the channel.

An adsorbent system including a body having or defining a channel therein, wherein the body is configured to be coupled to a humidity-controlled environment such that a first end of the channel is in selective fluid communication with the ambient environment and such that a second end of the channel is in fluid communication with said humidity-controlled environment. The system further includes an adsorbent material in the channel, wherein the channel and adsorbent material are configured such that inlet fluid flowing from the first end to the second end through the channel is flowable over the adsorbent material, and such that outlet fluid flowing from the second end to the first end is flowable over a majority of the adsorbent material that is flowable over by the inlet fluid. The system also includes a valve system positioned at or adjacent to or in fluid communication with the first end of the channel.

A zeolite molded article includes 100 parts by weight of zeolite, 35 parts by weight or more and 70 parts by weight or less of clay, 5 parts by weight or more and 40 parts by weight or less of a silica sol and 0.5 parts by weight or more and 10 parts by weight or less of a water-soluble sodium salt, having an abrasion resistance of 90% or more, an angle of repose of 40° or less, an aerated bulk density on the surface of the zeolite molded article of 0.5 kg/L or more, and a sphericity of the zeolite molded article of 1 or more and 3 or less. The zeolite contains at least one type of zeolite having Si/Al.sub.2 of 10 or more and 100,000 or less and a moisture adsorption amount of 10 (g/100 g) or less at 25° C. under a relative pressure of 0.5.

Method and systems are disclosed for selectively removing naturally-occurring sugars in beverages in an effective, affordable and scalable manner.

Method and systems are disclosed for selectively removing naturally-occurring sugars in beverages in an effective, affordable and scalable manner.

A food package suitable for manufacturing as a closed packaging system contains an amine-absorbent element comprising ammonium-exchanged mordenite (MOR) type zeolites and optionally further comprises ZnO-doped Faujasite (FAU) type zeolites and/or CuO-doped ZSM-5 type zeolites.

A binderless zeolite adsorbent for separation of oxygen from a gaseous stream. The adsorbent is a blend of a lithium exchanged zeolite 13X, a lithium exchanged low silica zeolite X zeolite, and halloysite clay. Also disclosed is a process of making the binderless zeolite adsorbent. Further disclosed is a process for production of oxygen from a gaseous stream utilizing the binderless zeolite adsorbent.

The present invention relates to a method for modifying the crystalline inorganic framework of an adsorbent with coatings to provide rate selectivity for one gas over others is described. The method described herein narrows the effective pore size of crystalline porous solids with pores less than about 5 Å for rate selective separations. This method of the invention comprises treating the hydrated or partially hydrated zeolite with a silicone derived binding agent followed by subsequent heat treatment. The additive content and treatment are adjusted to match effective pore size to specific separations. The superior adsorbent has the added convenience of bead forming simultaneously with pore modification as well as having the treatment result in the yielding of high crush strength products.

Ammonia is made in a system that includes a conversion reactor for performing a Haber-Bosch process. Effluent streams from the conversion reactor, which include an ammonia component and excess hydrogen and nitrogen reactants, are fed to a membrane separator that includes NaA zeolite membranes disposed on one or more hollow porous supports. The NaA zeolite membranes are highly selective for the ammonia component, allowing the ammonia to be collected from a lumen of the membranes as a product and enriching the excess hydrogen and nitrogen reactants for reuse in the conversion reactor. These systems and the methods of their use are effective to replace and/or modify the energy-intensive condensation/recycling steps in the traditional Haber-Bosch process used to condense NH3 from the exiting stream of the reactor. The selective removal of ammonia by high quality NaA membranes helps to shift the ammonia evolution reaction.