This invention relates to modified MOF materials, methods of preparing them and processes using them. A modified MOF of the invention is modified by impregnating a MOF with an inorganic metal salt. The starting MOF contains at least one linker or ligand which contains an aryl amino group as part of its structure. These modified MOFs are able to adsorb either basic or acidic toxic industrial compounds (TIC). The modified MOFs can be used to remove TICs from various gaseous streams such as air.

A composite sorbent polymer composite article is disclosed for adsorption. The sorbent polymer composite article includes a sorbent and a flexible porous polymer, the sorbent polymer composite article having an adsorptive configuration in which the sorbent polymer composite article is configured to adsorb one or more components of a feed stream, and a desorptive configuration in which the sorbent polymer composite article is configured to remove one or more components from the sorbent polymer composite article.

Complexing or chelating agents that offer strong, selective bonding with uranium as well as a broad pH range of effectiveness, specifically including the pH range around 8.2, together with the acrylic double bonds required for radiation-induced grafting on polymers to remove uranium from a solution such as seawater. The novel adsorbing species are phosphorus-containing molecules, in particular organic phosphates, phosphonates and phosphoric acids. Organic phosphorus compounds, for example, organic phosphates, phosphonates, and phosphoric acids, are attached to polymer fibers to form fibers, fiber fabrics or membranes that are effective, or show activity, in uranium adsorption.

Catalytic and/or sorptive articles comprising a metal fiber felt, the metal felt having an array of metal fibers and voids and a catalyst composition and/or a sorbent composition disposed on the metal fibers and within the voids are described. Such articles can be highly effective towards the abatement of pollutants in exhaust gas streams from internal combustion engines.

A support nanofunctionalised with photocatalytic nanoparticles made of polymeric material, preferably transparent or translucid, characterised by a nanoroughness, measured by means of an electron microscope, comprised between 10 and 150 nm and a macroroughness, measured by means of an electron microscope, comprised between 100 and 600 ?m, wherein said nano and macro-roughness are diffused internally and/or superficially. A process for preparing the nanofunctionalised support is also described. Further, an use of the nanofunctionalised support as a photocatalyst activated by UV and/or visible light, for the decontamination of a fluid, preferably air and/or water, from organic contaminants, bacteria, moulds, odours and a combination thereof is described. Finally, a filtration device comprising at least one nanofunctionalised support of the invention associated with at least one source of UV and/or visible light configured to irradiate said at least one nanofunctionalised support is described.

An oil skimming device for the removal of oil located at the surface of a body of water includes a float, at least one skimming surface, a sorbent material, at least one scraper, and a motor. The float is arranged such that the device rests on the surface of the body of water from which the oil is to be removed. The at least one skimming surface is rotatable about an axis such that when the device is floating in the water a portion of the ridged skimming surface is above and a portion of the skimming surface is below the water surface. The sorbent material is removably attached to and substantially covers the skimming surface. The sorbent material is configured to rotate with the skimming surface and to sorb oil as the skimming surface is rotated.

An adsorption system can be used as part of a climate control system in a vehicle or in any other space requiring heating or cooling.

This invention relates to modified MOF materials, methods of preparing them and processes using them. A modified MOF of the invention is modified by impregnating a MOF with an inorganic metal salt. The starting MOF contains at least one linker or ligand which contains an aryl amino group as part of its structure. These modified MOFs are able to adsorb either basic or acidic toxic industrial compounds (TIC). The modified MOFs can be used to remove TICs from various gaseous streams such as air.

Described are processes and equipment that are useful to remove hydrogen peroxide from a gas, for example from a hospital room as a step of sterilizing the room using hydrogen peroxide, or from a flow of exhaust air that is produced by sterilization equipment that uses hydrogen peroxide as a sterilizing agent.

A method of assessing a membrane includes calculating fluid dynamic characteristics of at least one of a membrane and a material to be passed through the membrane, the membrane includes a plurality of rows and a plurality of teardrop structures arranged in the plurality of rows, the material includes particles; obtaining characteristic of at least one force acting on the particles of the material to be passed through the membrane due to the interaction between the particles and the membrane, the at least one force being an intermolecular force; and combining the calculated fluid dynamic characteristic and the obtained characteristics to assess the flow of the material through the membrane. In some embodiments, the teardrop structures in each row are arranged at substantially the same angle with respect to an anticipated direction of flow through the membrane.