An object is to provide an adsorbent using activated carbon fiber, the adsorbent being suitable for motor vehicle canisters and enabling reduction in pressure loss.

An activated carbon fiber sheet for a motor vehicle canister fulfils the following conditions (1) to (4). (1) The sheet has a specific surface area ranging from 1100 to 2300 m.sup.2/g. (2) The sheet has a density ranging from 0.010 to 0.200 g/cm.sup.3 or less. (3) The sheet has a thickness ranging from 0.1 to 100.00 mm. (4) The sheet has a fiber size of 13.0 μm or larger.

Provided are certain activated carbonaceous materials which have been treated with dilute mineral acids to modify their surface chemistry and morphology. The modified activated carbonaceous materials of the disclosure are useful in removing certain contaminants from gaseous streams. In one embodiment, the contaminants are compounds containing silicon and oxygen moieties, such as alkyl silanols and alkyl siloxanes. The modified activated carbonaceous materials can be incorporated into filters and filter systems.

A sorbent product, including from about 1 wt % to about 99 wt %, based on the total weight of the sorbent product, of at least one base sorbent material; and from about 1 wt % to about 99 wt %, based on the total weight of the sorbent product, of at least one binder. The sorbent product may further include at least from about 0 wt % to about 99% wt %, based on the total weight of the sorbent product, of at least one additional additive. Methods for making same and methods and systems for controlling multiple pollutants are also included.

A method of preparing a magnetic particle having a polymer matrix (P) and at least one magnetic core (M), preferably at least two magnetic cores (M), wherein the polymer matrix (P) comprises at least one hypercrosslinked polymer, wherein the method comprises (i) providing at least one magnetic core (M), preferably at least two magnetic cores (M), (ii) providing polymer precursor molecules, (iii) polymerizing the polymer precursor molecules according to (ii) in the presence of the at least one magnetic core (M), thereby forming a particle comprising the at least one magnetic core (M) is disclosed. Further, particles obtained or obtainable by this method as well as to the use of these particles are disclosed. In a further aspect, a method for determining at least one analyte in a fluid sample having the step of contacting of the magnetic particle with a fluid sample having or suspected of having the at least one analyte is disclosed.

The present invention relates to an activated carbon, having a BET specific surface area (A) of 1,250 to 1,800 m.sup.2/g as determined from a carbon dioxide adsorption isotherm, and a ratio (B)/(C) of 0.640 or lower between a pore volume (B) mL/g at a pore diameter of 0.4 to 0.7 nm and a pore volume (C) mL/g at a pore diameter of 0.7 to 1.1 nm as determined by performing a grand canonical Monte Carlo simulation on a carbon dioxide adsorption-desorption isotherm.

In one aspect, an oxygenated hierarchically porous carbon (an “O-HPC”) is provided, the O-HPC comprising: a hierarchically porous carbon (an “HPC”), the HPC comprising a surface, the surface comprising: (A) first order pores having an average diameter of between about 1 μm and about 10 μm; and (B) walls separating the first order pores, the walls comprising: (1) second order pores having a peak diameter between about 7 nm and about 130 nm; and (2) third order pores having an average diameter of less than about 4 nm, wherein at least a portion of the HPC surface has been subjected to O.sub.2 plasma to oxygenate and induce a negative charge to the surface. In one aspect, the O-HPC further comprises metal nanoparticles dispersed within the first, second, and third order pores. Methods for making and using the metal nanoparticle-impregnated O-HPCs are also provided.

This invention relates to a Cu-BTC MOF which is water stable. The Cu-BTC MOF has been modified by substituting some of the BTC ligand (1,3,5, benzene tricarboxylic acid) with 5-aminoisophthalic acid (AIA). The resultant MOF retains at least 40% of its as synthesized surface area after exposure to liquid water at 60° C. for 6 hours. This is an unexpected result versus the MOF containing only the BTC ligand. This MOF can be used to abate contaminants such as ammonia in gas streams and especially air streams.

A permanently porous vanadium(II)-containing metal-organic framework (MOF) with vanadium(II) centers and methods for synthesis of such MOF frameworks are provided. Methods for using such compounds to selectively react with N.sup.2 over CH.sub.4 are provided. In the synthetic methods, a vanadium source, such as VY.sub.2(tmeda).sub.2, where Y is a halogen and tmeda is N,N,N′,N′-tetramethylethane-1,2-diamine and a H.sub.2(ligand) are reacted in the presence of acid in a solvent at between 110° C. and 130° C. to form an intermediate product. The intermediate product is collected and washed with a washing agent, such as DMF and acetonitrile, and the vanadium(II) based MOF is activated by heating the washed intermediate product to at least 160° C. under dynamic vacuum.

The present disclosure relates to hydrocarbon emission control systems. More specifically, the present disclosure relates to substrates coated with hydrocarbon adsorptive coating compositions and evaporative emission control systems for controlling evaporative emissions of hydrocarbons from motor vehicle engines and fuel systems.

An adsorbent composition comprising particles consisting of a core which is at least partially coated with an adsorbent material is disclosed. The core is selected so that it has at least one of: (i) wear resistance; (ii) resistance to corrosive conditions; (iii) at least one thermoplastic material; and (iv) a low porosity. A suitable core material is polystyrene. Adsorbent materials suitable for the coating include activated carbon and metal oxides such as silica and alumina. The adsorbent composition may be used for the adsorption of metals and metal ions in ore processing, for instance for the separation of precious metals such as gold.