Disclosed are metal organic frameworks (MOFs) for adsorbing guest species, methods for the separation of gases using the MOFs, and systems comprising the MOFs. The MOFs comprise a plurality of secondary building units (SBUs), each SBU comprising a repeating unit of one metal cation connected to another metal cation via a first moiety of an organic linker; a layer of connected adjacent SBUs in which a second moiety of the linker in a first SBU is connected to a metal cation of an adjacent SBU, and wherein adjacent layers are connected to each other via linker-to-linker bonding interactions

The invention relates to an adsorbent comprising a zeolite-based phase and a non-zeolite-based phase, said adsorbent having: an outer surface area of less than or equal to 30 m.sup.2.Math.g.sup.−1, preferably less than or equal to 20 m.sup.2.Math.g.sup.−1, a zeolite-based phase comprising at least one zeolite of FAU structure of X type, and a pore diameter distribution, determined by mercury intrusion according to standard ASTM D 4284-83 and expressed by the volume distribution dV/d log DHg, in which DHg is the apparent pore diameter and V is the pore volume, the mode of which is between 100 nm and 250 nm, limits inclusive.

The invention also relates to a process for preparing the said adsorbent and to the uses thereof, especially for separating xylene isomers.

The present invention relates to a zeolite-based adsorbent comprising at least one zeolite of FAU structure of LSX type and comprising barium and/or potassium, in which the outer surface area of said zeolite-based adsorbent, measured by nitrogen adsorption, is between 20 m.sup.2.Math.g.sup.−1 and 100 m.sup.2.Math.g.sup.−1, limits inclusive. The present invention also relates to the use of such a zeolite-based adsorbent as an adsorption agent, and also to the process for separating para-xylene from aromatic isomer fractions containing 8 carbon atoms.

Provided is a method for manufacturing a mesoporous inorganic oxide, which includes preparing a mixture of a metal salt selected from the group consisting of at least one kind of alkali metal-containing compound, at least one kind of alkaline earth metal-containing compound, and any combination thereof and an amorphous inorganic oxide; sintering the mixture of a metal salt and an amorphous inorganic oxide; and removing the metal salt contained in the sintered mixture, and a mesoporous inorganic oxide that is manufactured by the above method and is composed of an aggregate of inorganic oxide particles having a size of from 2 nm to 5 nm.

According to the present invention, it is possible to provide a method for manufacturing a mesoporous inorganic oxide which has a simplified manufacturing process, has a short period of manufacturing time of about 1 day, does not generate secondary environmental contaminants to be environmentally friendly, and enables mass production, and a mesoporous inorganic oxide which has a dramatically decreased particle size and thus has an increased specific surface area and increased active sites.

A catalyst system comprising a combination of: 1) one or more catalyst compounds comprising at least one oxygen linkage, such as a phenoxide transition metal compound; 2) a support comprising an organosilica material, which may be a mesoporous organosilica material; and 3) an optional activator. Useful catalysts include biphenyl phenol catalysts (BPP). The organosilica material may be a polymer of at least one monomer of Formula [Z.sup.1OZ.sup.2SiCH.sub.2].sub.3 (I), where Z.sup.1 represents a hydrogen atom, a C.sub.1-C.sub.4 alkyl group, or a bond to a silicon atom of another monomer and Z.sup.2 represents a hydroxyl group, a C.sub.1-C.sub.4 alkoxy group, a C.sub.1-C.sub.6 alkyl group, or an oxygen atom bonded to a silicon atom of another monomer. This invention further relates to processes to polymerize olefins comprising contacting one or more olefins with the above catalyst system.

Provided herein are an adsorbent and method of treating water using the adsorbent. The adsorbent includes thermally- and chemically-treated lignite coal. The method includes contacting wastewater with the treated lignite coal.

Disclosed in certain embodiments are sorbents for capturing heavy hydrocarbons via thermal swing adsorption processes.

In an activated carbon for adsorbing a noble metal from an aqueous solution containing the noble metal, the difference (absolute value) between a zeta-potential in a 10 mmol/L aqueous solution of sodium tetraborate and a zeta-potential in a 0.01 mmol/L aqueous solution of sodium tetraborate is adjusted to not more than 18 mV and the pore volume of pores with a pore radius of not more than 1 nm is adjusted to 150 to 500 mm.sup.3/g. The activated carbon of the present invention may have a carbohydrate solution decolorizing performance of not less than 30%. The aqueous solution containing the noble metal may be a plating wastewater. According to the present invention, a noble metal can efficiently be adsorbed (or recovered) from a solution containing the noble metal.

There is provided an absorbent for decreasing the leakage of halogen compound gases in subsequent processes, at high temperatures and in the presence of high concentrations of water vapor in the process of heating and gasifying a fuel, such as coal, to produce a synthesis gas.

The adsorbent includes a halogen compound absorbent containing 30 to 90% by mass of a basic calcium compound and 10 to 70% by mass of a metal compound other than basic calcium compounds and/or of a clay mineral. A method for producing synthesis gas using the absorbent is also disclosed.

The present disclosure provides a method for synthesizing fibrous silica nanospheres, the method can include, in sequence, the steps of: a) providing a reaction mixture comprising a silica precursor, a hydrolyzing agent, a template molecule, a cosurfactant and one or more solvents; b) maintaining the reaction mixture under stirring for a length of time; c) heating the reaction mixture to a temperature for a length of time; d) cooling the reaction mixture to obtain a solid, and (e) calcinating the solid to pro duce fibrous silica nanospheres, wherein desirable product characteristics such as particle size, fiber density, surface area, pore volume and pore size can be obtained by controlling one or more parameters of the method. The present disclosure further provides a method for synthesizing fibrous silica nanospheres using conventional heating such as refluxing the reactants in an open reactor, thereby eliminating the need for microwave heating in a closed reactor or the need for any pressure reactors.