A porous aluminum-based metal-organic framework (MOF) comprises inorganic aluminum chains linked via carboxylate groups of 1H-pyrazole-3,5-dicarboxylate (HPDC) linkers, and of formula: [Al(OH)(C.sub.5H.sub.2O.sub.4N.sub.2)(H.sub.2O)].

Embodiments of the present disclosure pertain to methods of sorption of H.sub.2O from an environment by associating the environment with a porous material such that the association results in the sorption of H.sub.2O to the porous material. The porous material includes a (M)-2,4-pyridinedicarboxylic acid coordination polymer, where M is a divalent metal ion selected from the group consisting of Mn, Fe, Co, Ni, Mg, and combinations thereof. The coordination polymer has a one-dimensional pore structure and shows reversible soft-crystal behavior. The porous material may be a Mg(II) 2,4-pyridinedicarboxylic acid coordination polymer (i.e., Mg-CUK-1). The methods of the present disclosure may also include one or more steps of releasing the sorbed H.sub.2O from the porous material and reusing the porous material after the releasing step for sorption of additional H.sub.2O from the environment.

The present disclosure provides for alkyl-aryl amine-rich small molecules that are prepared by nucleophilic substitution from tri- and hexa-bromine-substituted aromatic cores with various aliphatic diamines. The resulting products can be subsequently subjected by solution impregnation into solid mesoporous supports. Various types of alkyl-aryl amine-rich small molecules can fill the support's pores up to ˜90% and displayed good thermal stability

Activated carbon, e.g., from waste tires, modified by bimetallic Fe and Ce nanoparticles can provide high surface area and active sites for enhanced dye adsorption. Such nanocomposites can offer magnetic removal from aqueous solutions containing, e.g., Methylene Blue or Rhodamine B. Adsorption equilibrium data fit well to the Langmuir isotherm model, with an adsorption capacity was 324.6 mg/g. Rhodamine B adsorption by such activated carbon-Fe—Ce magnetic adsorbents has an endothermic character and pseudo-second-order kinetics. In ethanol solution, rhodamine B was desorbed at high efficiency and such materials, which could be recycled up to 5 cycles. Such magnetic nanocomposites are adsorbents for treating dyes such as rhodamine B in wastewater, even in large scale adsorption systems. Polyamides can be grafted to such nanocomposites.

A problem to be solved by the present invention is to provide a new form of adsorbent suitable for a motor vehicle canister. An activated carbon fiber sheet satisfies one or two or more of conditions for indices, such as a specific surface area, a pore volume of pores having a given pore diameter, and a sheet density. An embodiment, for example, may have: a specific surface area ranging from 1400 to 2300 m.sup.2/g; a pore volume ranging from 0.20 to 0.70 cm.sup.3/g for pores having pore diameters of more than 0.7 nm and 2.0 nm or less; an abundance ratio R.sub.0.7/2.0, which is a ratio of a pore volume of micropores having pore diameters of 0.7 nm or less occupied in a pore volume of micropores having pore diameters of 2.0 nm or less, ranging from 5% to less than 25%, and a sheet density ranging from 0.030 to 0.200 g/cm.sup.3.

An object is to provide a new form of adsorbent suitable for a high performance canister. An adsorbent including activated carbon is used as the adsorbent for the canister and satisfies the following conditions. P.sub.0.2/100 expressed by Equation 1:

P.sub.0.2/100=X÷Y×100  (Equation 1)

is 18% or more, in Equation 1, X represents an amount of adsorbed n-butane gas per 100 parts by weight of the adsorbent at 25° C. under an atmosphere where a gas pressure of n-butane gas is 0.2 kPa, and Y represents an amount of adsorbed n-butane gas per 100 parts by weight of the adsorbent at 25° C. under an atmosphere where a gas pressure of n-butane gas is 100 kPa.

An object is to provide an adsorbent using activated carbon fiber, the adsorbent being suitable for motor vehicle canisters and enabling reduction in pressure loss.

An activated carbon fiber sheet for a motor vehicle canister fulfils the following conditions (1) to (4). (1) The sheet has a specific surface area ranging from 1100 to 2300 m.sup.2/g. (2) The sheet has a density ranging from 0.010 to 0.200 g/cm.sup.3 or less. (3) The sheet has a thickness ranging from 0.1 to 100.00 mm. (4) The sheet has a fiber size of 13.0 μm or larger.

The present invention relates to an activated carbon, having a pore volume (A) of 0.3 to 0.7 mL/g at a pore diameter of 6.5 to 50 nm as determined by mercury intrusion porosimetry, a pore volume (B) of 0.23 mL/g or less at a pore diameter of 750 to 4,000 nm as determined by mercury intrusion porosimetry, and a pore volume ratio (A)/(B) of 1.7 or higher.

The present invention provides the use of charged surface reversed phase chromatographic materials along with standard reversed-phase LC and mass spectrometry compatible conditions for the retention, separation, purification, and characterization of acidic, polar molecules, including, but not limited to, organic acids, α-amino acids, phosphate sugars, nucleotides, other acidic, polar biologically relevant molecules. The chromatographic materials of the invention are high purity chromatographic materials comprising a chromatographic surface wherein the chromatographic surface comprises a hydrophobic surface group and one or more ionizable modifier.

A continuous desulfurization process and process system are described for removal of reduced sulfur species at gas stream concentrations in a range of from about 5 to about 5000 ppmv, using fixed beds containing regenerable sorbents, and for regeneration of such regenerable sorbents. The desulfurization removes the reduced sulfur species of hydrogen sulfide, carbonyl sulfide, carbon disulfide, and/or thiols and disulfides with four or less carbon atoms, to ppbv concentrations. In specific disclosed implementations, regenerable metal oxide-based sorbents are integrated along with a functional and effective process to control the regeneration reaction and process while maintaining a stable dynamic sulfur capacity. A membrane-based process and system is described for producing regeneration and purge gas for the desulfurization.