A polymer aerogel monolith comprising a polymer aerogel having a nitrogen content of greater than seven weight percent impregnated into a mesh. A method of manufacturing an amine-containing polymer aerogel monolith, includes combining a vinyl-containing cross-linking monomer, a vinyl-containing functional monomer, an organic solvent, and a radical initiator into a liquid mixture, applying the liquid mixture to a mesh fabric to produce a monomer-impregnated mesh, heating the monomer-impregnated mesh to produce a polymer aerogel monolith, washing the polymer aerogel monolith with acid to produce an ammonium-containing polymer aerogel monolith, and applying a base to neutralize the ammonium-containing polymer aerogel monolith to produce an amine-containing polymer aerogel monolith. A direct air capture module has one or more amine-containing polymer aerogel monoliths, one or more air flow channels positioned to pass air through the monolith A monolith comprising a poly(alkylamine-co-divinylbenzene) impregnated mesh.

Solid absorbent compositions and methods for the removal of mercaptan sulfur compounds from hydrocarbon streams are provided. The compositions may include porous granulated activated carbon particles with internal pore surfaces containing bound trinuclear basic iron (III) acetate complex containing the [Fe.sub.3(.sup.3-O)] core structure.

In one aspect, an oxygenated hierarchically porous carbon (an O-HPC) is provided, the O-HPC comprising: a hierarchically porous carbon (an HPC), the HPC comprising a surface, the surface comprising: (A) first order pores having an average diameter of between about 1 m and about 10 m; and (B) walls separating the first order pores, the walls comprising: (1) second order pores having a peak diameter between about 7 nm and about 130 nm; and (2) third order pores having an average diameter of less than about 4 nm, wherein at least a portion of the HPC surface has been subjected to O.sub.2 plasma to oxygenate and induce a negative charge to the surface. In one aspect, the O-HPC further comprises metal nanoparticles dispersed within the first, second, and third order pores. Methods for making and using the metal nanoparticle-impregnated O-HPCs are also provided.

A process for manufacturing particles of water-absorbing material is provided. The process includes providing a powder bed composed of an absorptive powder comprising a water-absorbing polysaccharide onto a surface; releasing an aqueous solution from a solution dispenser so as to contact the powder bed, 5 thereby forming a solution-impregnated humid material; letting the solution-impregnated humid material agglomerate in substantially shear-less conditions to form an agglomerated humid material, the solution-impregnated humid material being supported by the surface; and drying the agglomerated humid material, thereby forming the particles.

Methods for fabricating a membrane with an organosilica material which is a polymer comprising independent units of Formula [Z.sup.3Z.sup.4SiCH.sub.2].sub.3 (I), wherein each Z.sup.3 represents a hydroxyl group, a C.sub.1-C.sub.4 alkoxy group or an oxygen atom bonded to a silicon atom of another unit or an active site on the support and each Z.sup.4 represents a hydroxyl group, a C.sub.1-C.sub.4 alkoxy group, a C.sub.1-C.sub.4 alkyl group, an oxygen atom bonded to a silicon atom of another unit or an active site on the support are provided. Methods of removing a contaminant from a hydrocarbon stream are also provided.

A composite filter aid may include acid-washed diatomaceous earth and a low extractable metal mineral. A method for making a composite material may include blending an acid-washed diatomaceous earth and a low extractable metal mineral, adding a binder to the blended diatomaceous earth and low extractable metal mineral, and forming the composite material from the acid-washed diatomaceous earth, the low extractable metal mineral, and the binder. A method for filtering a liquid may include providing a liquid for filtering and filtering the liquid through a composite filter aid that includes an acid-washed diatomaceous earth and a low extractable metal mineral.

A filter apparatus for removing small molecule chemotherapy agents from blood is provided. The filter apparatus comprises a housing with an extraction media comprised of polymer coated carbon cores. Also provided are methods of treating a subject with cancer of an organ or region comprising administering a chemotherapeutic agent to the organ or region, collecting blood laded with chemotherapeutic agent from the isolated organ, filtering the blood laden with chemotherapeutic agent to reduce the chemotherapeutic agent in the blood and returning the blood to the subject.

The present disclosure provides a composition. In an embodiment, the composition includes (A) from 85 wt % to 99 wt % of an olefin-based polymer and (B) from 15 wt % to 1 wt % of an odor suppressant. The odor suppressant is a blend of (i) particles of zinc oxide, and (ii) zinc ionomer. The zinc oxide particles have a D50 particle size from 100 nm to 3000 nm, a surface area from 1 m.sup.2/g to 9 m.sup.2/g, and a porosity less than 0.020 m.sup.3/g. The composition has a methyl mercaptan odor suppression value of less than 70 at 3 days as measured in accordance with ASTM D5504-12.

A composite filter aid may include diatomaceous earth, natural glass, and a precipitated silica binder, wherein the filter aid has a permeability ranging from 3 to 20 darcys. A composite filter aid may include diatomaceous earth, perlite, and a precipitated silica binder, wherein the filter aid has an alpha density less than 15 lbs/ft.sup.3. A method for making a composite material may include blending diatomaceous earth and perlite, adding alkali silicate to the blended diatomaceous earth and perlite, and precipitating the alkali silicate as a binder to make the composite material. A method for filtering a beverage may include using a composite filter aid and/or composite material.

The present invention provides an improved sorbent and corresponding device(s) and uses thereof for the capture and stabilization of volatile organic compounds (VOC) or semi-volatile organic compounds (SVOC) from a gaseous atmosphere. The sorbent is capable of rapid and high uptake of one or more compounds and provides quantitative release (recovery) of the compound(s) when exposed to elevated temperature and/or organic solvent. Uses of particular improved grades of mesoporous silica are disclosed.