Metal-organic framework materials (MOFs) are highly porous entities comprising a multidentate organic ligand coordinated to multiple metal centers, typically as a coordination polymer. Some highly porous MOFs lack stability at ambient conditions. MOFs having ambient condition stability may comprise a plurality of metal clusters (M.sub.4O clusters, M=a metal), and a plurality of 4-(1H-pyrazol-4-yl)benzoate ligands coordinated to the plurality of metal clusters to define an at least partially crystalline network structure having a plurality of internal pores. Methods for synthesizing these MOFs may comprise combining a metal source, such as a preformed metal cluster, with 4-(1H-pyrazol-4-yl)benzoic acid, and reacting the preformed metal cluster with the 4-(1H-pyrazol-4-yl)benzoic acid to form a MOF having an at least partially crystalline network structure with a plurality of internal pores defined therein and comprising a plurality of metal clusters coordinated to a multidentate organic ligand comprising 4-(1H-pyrazol-4-yl)benzoate.

The invention relates to an improved process for preparing metal-organic framework materials, metal-organic frameworks obtainable by such processes, methods using the same, and the use thereof. The process of the invention provides an improved process for preparing metal-organic frameworks in particular monocrystalline metal-organic frameworks having large crystal sizes. The invention also relates to metal organic frameworks comprising iron or titanium, and their uses.

The present invention concerns methods of treating systemic, regional, or local inflammation from a patient suffering or at risk of inflammation comprising administration of a therapeutically effective dose of a sorbent that sorbs an inflammatory mediator in said patient. In some preferred embodiments, the sorbent is a biocompatible organic polymer.

A carbon dioxide adsorbent including silica gel and an amine compound carried by the silica gel. The silica gel has a spherical shape, a particle size ranging from 1 mm to 5 mm inclusive, an average pore diameter ranging from 10 nm to 100 nm inclusive, a pore volume ranging from 0.1 cm.sup.3/g to 1.3 cm.sup.3/g inclusive, and a waterproof property N that is defined by an expression (1) and that is not lower than 45%,

N=(W/W.sub.0)×100  (1) where N is the waterproof property in percentage (%) of the silica gel, W.sub.0 is a total number of particles of the silica gel immersed in water, W is a number of particles of the silica gel not subjected to breakage out of W.sub.0.

A method of using a nanoporous carbon material for adsorption of one or more PAH and diesel fuel from an aqueous solution is described. The aqueous solution may comprise the one or more PAH at a concentration of 0.1 mg/L-1 g/L, and the diesel fuel at a concentration of 0.1-5 g/L. The nanoporous carbon material may adsorb at least 96 wt % of one or more PAH within 10 minutes. The nanoporous carbon material may be obtained by contacting a carbonized asphalt with a base.

A filter media for implementation in a sugar purification process that allows for a significant increase in sorbent material while maintaining, and enhancing the decolorization and. hydraulic properties. The filter media incorporates sorbent material, fiber having specific properties that allows for small particle sorbent material without jeopardizing the hydraulic properties of the media, and an electrolyte. The sorbent material is an inorganic, an adsorption, or ion exchange media, or a metal-organic framework. The implementation of this filter media in a sugar purification process eliminates the need for a clarification step during refining while providing for enhanced decolorization and hydraulic properties for fluid flow.

A problem to be solved by the present invention is to provide a new form of adsorbent suitable for a motor vehicle canister. An activated carbon fiber sheet satisfies one or two or more of conditions for indices, such as a specific surface area, a pore volume of pores having a given pore diameter, and a sheet density. An embodiment, for example, may have: a specific surface area ranging from 1400 to 2300 m.sup.2/g; a pore volume ranging from 0.20 to 0.70 cm.sup.3/g for pores having pore diameters of more than 0.7 nm and 2.0 nm or less; an abundance ratio R.sub.0.7/2.0, which is a ratio of a pore volume of micropores having pore diameters of 0.7 nm or less occupied in a pore volume of micropores having pore diameters of 2.0 nm or less, ranging from 5% to less than 25%, and a sheet density ranging from 0.030 to 0.200 g/cm.sup.3.

An object is to provide a new form of adsorbent suitable for a high performance canister. An adsorbent including activated carbon is used as the adsorbent for the canister and satisfies the following conditions. P.sub.0.2/100 expressed by Equation 1:

P.sub.0.2/100=X÷Y×100  (Equation 1)

is 18% or more, in Equation 1, X represents an amount of adsorbed n-butane gas per 100 parts by weight of the adsorbent at 25° C. under an atmosphere where a gas pressure of n-butane gas is 0.2 kPa, and Y represents an amount of adsorbed n-butane gas per 100 parts by weight of the adsorbent at 25° C. under an atmosphere where a gas pressure of n-butane gas is 100 kPa.

An object is to provide an adsorbent using activated carbon fiber, the adsorbent being suitable for motor vehicle canisters and enabling reduction in pressure loss.

An activated carbon fiber sheet for a motor vehicle canister fulfils the following conditions (1) to (4). (1) The sheet has a specific surface area ranging from 1100 to 2300 m.sup.2/g. (2) The sheet has a density ranging from 0.010 to 0.200 g/cm.sup.3 or less. (3) The sheet has a thickness ranging from 0.1 to 100.00 mm. (4) The sheet has a fiber size of 13.0 μm or larger.

The present invention provides the use of charged surface reversed phase chromatographic materials along with standard reversed-phase LC and mass spectrometry compatible conditions for the retention, separation, purification, and characterization of acidic, polar molecules, including, but not limited to, organic acids, α-amino acids, phosphate sugars, nucleotides, other acidic, polar biologically relevant molecules. The chromatographic materials of the invention are high purity chromatographic materials comprising a chromatographic surface wherein the chromatographic surface comprises a hydrophobic surface group and one or more ionizable modifier.