The invention relates to porous polymeric cellulose prepared via cellulose crosslinking. The porous polymeric cellulose can be incorporated into membranes and/or hydrogels. In preferred embodiments, the membranes and/or hydrogels can provide high dynamic binding capacity at high flow rates. Membranes and/or hydrogels comprising the porous polymeric cellulose are particularly suitable for filtration, separation, and/or functionalization media.

The present invention provides a hydrocarbon adsorption device 10 configured to circulate a fluid and adsorb hydrocarbons in the fluid. The hydrocarbon adsorption device 10 includes a first hydrocarbon adsorption section 20 containing zeolite, and a second hydrocarbon adsorption section 30 which is provided downstream of the first hydrocarbon adsorption section 20 in the flowing direction of the fluid. The pore diameter P1 of the zeolite contained in the first hydrocarbon adsorption section 20 is smaller than the pore diameter P2 of the zeolite contained in the second hydrocarbon adsorption section 30 (i.e., P1<P2).

The present invention relates to a method for reducing the HTO concentration in a tritium-containing aqueous solution. The present invention includes bringing water vapor or the like of a tritium-containing aqueous solution into contact with a porous material having pores in a pore diameter range of 500 Å or less, selectively occluding the HTO in the tritium-containing aqueous solution in the porous material, and obtaining a tritium-containing aqueous solution in which the HTO concentration thereof is reduced. The present invention relates to a device used for reducing the HTO concentration in a tritium-containing aqueous solution. The present invention includes a reservoir for a raw tritium-containing aqueous solution, a means for generating water vapor or the like of the tritium-containing aqueous solution, an occlusion means in which is accommodated a porous material having pores in a pore diameter range of 500 Å or less, and a means for recovering the tritium-containing aqueous solution in which the HTO concentration is reduced. The present invention furthermore includes a transfer means for transferring the water vapor or the like to the occlusion means, and a means for transferring the tritium-containing aqueous solution in which the HTO concentration is reduced from the occlusion means to a recovery means.

A filter-drier unit for a refrigerant includes an exterior housing formed of a hard material, and a desiccant material supported within the exterior housing and being formed of a metal-organic framework material having inorganic metal ions and bridging ligands that link the metal ions. The metal-organic framework has a three-dimensional permanently porous structure that has at least one chemically tunable characteristic, such as pore size, pore volume, and surface area.

This disclosure relates generally relates to methods and systems useful for continuous synthesis of materials in super-critical carbon dioxide (sCO.sub.2). More particularly, this disclosure relates to methods and systems useful for continuous synthesis of coordination polymers, such as metal-organic frameworks (MOFs) and/or covalent organic frameworks (COFs), in sCO.sub.2.

Embodiments of the present disclosure provide for metal-organic materials (MOMs), systems that exhibit permanent porosity and using hydrophobic MOMs to separate components in a gas, methods of separating CO.sub.2 from a gas, and the like.

Provided herein are electret-MOF filter embedded with particles derived from metal-organic frameworks (MOF) and their methods of manufacturing. The methods of manufacturing the electret-MOF filter can include suspending MOF particles in a solvent to form a MOF particle mixture, contacting a charged polymeric fibrous web with the MOF particle mixture, and coating the charged polymeric fibrous web with the MOF particles by flowing the MOF particle mixture through an inverse side of the polymeric fibrous web. The disclosed coating method can deposit MOF particles uniformly, without formation of films at interstitial spaces between fibers. The electret-MOF filter can simultaneously remove fine particulate matters (PMs) and hazardous gaseous pollutants (including volatile organic compounds (VOCs)) with high particle holding and gas adsorption capacities, and with very low air resistance.

Provided are: an exhaust gas purifying composition that contains a phosphorus-containing BEA-type zeolite and has further improved heat resistance; and a production method therefor.

The exhaust gas purifying composition contains a phosphorus-containing BEA-type zeolite, wherein the phosphorus-containing BEA-type zeolite has a pore volume ratio (V2/V1) of a micropore volume V2 having a pore diameter in a range of 2 nm or less, as measured by a SF method, to a mesopore volume V1 having a pore diameter in a range of 2 nm or more and 100 nm or less, as measured by a BJH method, of 2.0 or more.

Disclosed in certain embodiments are hydrocarbon adsorbents and evaporative emission control systems incorporating the same to reduce hydrocarbon bleed emissions from fuel systems. In one embodiment, a hydrocarbon adsorbent structure comprises a zeolite having a silica-to-alumina ratio of at least 20.

Novel radioactive iodide molecular traps, in which one or more metal atoms are functionalized by coordinating to an amine containing two or more nitrogens, and methods of using the molecular traps to capture radioactive iodide.