In one aspect, an oxygenated hierarchically porous carbon (an O-HPC) is provided, the O-HPC comprising: a hierarchically porous carbon (an HPC), the HPC comprising a surface, the surface comprising: (A) first order pores having an average diameter of between about 1 m and about 10 m; and (B) walls separating the first order pores, the walls comprising: (1) second order pores having a peak diameter between about 7 nm and about 130 nm; and (2) third order pores having an average diameter of less than about 4 nm, wherein at least a portion of the HPC surface has been subjected to O.sub.2 plasma to oxygenate and induce a negative charge to the surface. In one aspect, the O-HPC further comprises metal nanoparticles dispersed within the first, second, and third order pores. Methods for making and using the metal nanoparticle-impregnated O-HPCs are also provided.

The present disclosure relates to hydrocarbon emission control systems. More specifically, the present disclosure relates to substrates coated with hydrocarbon adsorptive coating compositions and evaporative emission control systems for controlling evaporative emissions of hydrocarbons from motor vehicle engines and fuel systems. The hydrocarbon adsorptive coating compositions include particulate carbon having a BET surface area of at least about 1300 m.sup.2/g, and at least one of (i) a butane affinity of greater than 60% at 5% butane; (ii) a butane affinity of greater than 35% at 0.5% butane; (iii) a micropore volume greater than about 0.2 mug and a mesopore volume greater than about 0.5 ml/g.

In one aspect, an oxygenated hierarchically porous carbon (an O-HPC) is provided, the O-HPC comprising: a hierarchically porous carbon (an UPC), the HPC comprising a surface, the surface comprising: (A) first order pores having an average diameter of between about 1 m and about 10 m; and (B) walls separating the first order pores, the walls comprising: (1) second order pores having a peak diameter between about 7 nm and about 130 nm; and (2) third order pores having an average diameter of less than about 4 nm, wherein at least a portion of the HPC surface has been subjected to O.sub.2 plasma to oxygenate and induce a negative charge to the surface. In one aspect, the O-HPC further comprises metal nanoparticles dispersed within the first, second, and third order pores. Methods for making and using the metal nanoparticle-impregnated O-HPCs are also provided.

The present invention relates to calcium hydroxide particles having a total pore volume greater than 0.18 cm.sup.3/g, said total pore volume being calculated with the BJH method for a range of pores having a diameter of between 20 and 1000 , said particles being characterized in that the BJH partial pore volume for the range of pores having a diameter of between 20 and 100 corresponds to more than 20% of said BJH total pore volume.

An object of the present invention is to provide a porous body having excellent adsorption performance, an adsorbent including the porous body, and a method of removing a metal and/or a metal ion from a liquid to be treated, with the adsorbent, and, in order to achieve the object, the present invention provides a porous body having a co-continuous structure formed by: a ceramic skeleton including mesopores; and macropores, wherein a surface of the ceramic skeleton is modified by a metal- and/or metal ion-adsorbable nitrogen atom-containing group, wherein the nitrogen atom-containing group is at least one selected from a primary amino group, a secondary amino group, a tertiary amino group, a quaternary ammonium group, an imino group, a nitrilo group and a nitrogen atom-containing heterocyclic group, and wherein an amount of the nitrogen atom-containing group contained in the porous body is 1.5 mmol/g or more and 5.4 mmol/g or less.

Thiol-functionalized, hyper-crosslinked vinylbenylchloride-divinybenzene (VBC-DVB) copolymers having high mesopore volumes are provided. Also provided are methods of making the hyper-crosslinked copolymers and methods of using the hyper-crosslinked copolymers in the capture and remediation of metals, including heavy metals.

The invention relates to zeolitic absorbents based on at least one zeolite with hierarchical porosity, containing barium or barium and potassium, to the uses thereof for separating para-xylene from aromatic fractions containing 8 carbon atoms, and to the method for separating para-xylene from aromatic fractions containing 8 carbon atoms.

The present invention relates to an organic polymer adsorbent, an organic polymer adsorbent composition, and a method for preparing an organic polymer adsorbent and, more specifically, to an organic polymer adsorbent to be used for a ventilation device such as a desiccant dehumidifier. According to the present invention, an adsorbent material is changed to an organic polymer adsorbent such that the mechanical stability and durability of the material itself can be ensured, and the specific surface area of interconnected inner pores and adsorbents and the size of formed pores can be controlled since toluene is contained as a pore generator of the adsorbent. Therefore, the adsorbent of the present invention has superior adsorption performance over that of other conventional organic polymer adsorbents containing a salt-type carboxyl group and has remarkably improved desorption performance, and thus has an effect of very remarkable energy efficiency.

The present invention provides novel chromatographic materials, e.g., for chromatographic separations, processes for their preparation and separations devices containing the chromatographic materials. The preparation of the inorganic/organic hybrid materials of the invention wherein a surrounding material is condensed on a superficially porous hybrid core material will allow for families of different hybrid packing materials to be prepared from a single core hybrid material. Differences in hydrophobicity, ion-exchange capacity, chemical stability, surface charge or silanol activity of the surrounding material may be used for unique chromatographic separations of small molecules, carbohydrates, antibodies, whole proteins, peptides, and/or DNA.

A capture mass for heavy metals, in particular mercury, contained in a gaseous or liquid feed, said mass comprising: copper which is present at least in part in the sulphide form, Cu.sub.xS.sub.y; a porous support based on alumina;
characterized in that said porous support has a total pore volume (TPV) in the range 0.8 to 1.5 cm.sup.3/g, a mesopore volume (V.sub.6nm-100nm) in the range 0.5 to 1.3 cm.sup.3/g, and a macropore volume (V.sub.100nm) in the range 0.33 to 0.45 cm.sup.3/g,
it being understood that the ratio between the mesopore volume and the macropore volume (V.sub.6nm-100nm/V.sub.100nm) is in the range 1 to 5.