Gas chromatography column comprising a substrate, a channel formed in said substrate, a cover closing said substrate and a stationary phase covering the walls of said channel, wherein said stationary phase is made of SiOxCyHz with x between 1.6 and 1.8, y between 1 and 2.2 and z between 3 and 4, wherein said stationary phase is porous with a porosity of between 10% and 40%.

A method for removing carbon dioxide directly from ambient air, using a sorbent under ambient conditions, to obtain relatively pure CO.sub.2. The CO.sub.2 is removed from the sorbent using process heat, preferably in the form of steam, at a temperature in the range of not greater than about 130 C., to capture the relatively pure CO.sub.2 and to regenerate the sorbent for repeated use. Increased efficiency can be achieved by admixing with the ambient air, prior to contacting the sorbent, a minor amount of a preferably pretreated effluent gas containing a higher concentration of carbon dioxide. The captured carbon dioxide can be stored for further use, or sequestered permanently. The above method provides purified carbon dioxide for further use in agriculture and chemical processes, or for permanent sequestration.

A humidity controlling apparatus comprising: a moisture absorption unit including a base material rotatable about a rotation shaft and a macromolecular moisture absorbent provided in a layer on an outer periphery of the base material; and a heat source partially heating the moisture absorption unit, the macromolecular moisture absorbent having a hydrophilic state capable of absorbing moisture in the air and a hydrophobic state which releases the moisture sorbed in the hydrophilic state, the macromolecular moisture absorbent having a nature such that when temperature rises, the macromolecular moisture absorbent changes from the hydrophilic state to the hydrophobic state, and when the temperature falls, the macromolecular moisture absorbent returns from the hydrophobic state to the hydrophilic state, requires small thermal energy and can efficiently control humidity.

A structure and system for the adsorption of carbon dioxide from air, the system comprising a sorbent structure comprising a porous substrate having a porous alumina coating on the surfaces of said substrate, and the sorbent for carbon dioxide is embedded on the surfaces of said porous alumina coating. The substrate is preferably a porous monolith, formed from silica or mesocellular foam. The sorbent is an amine group-containing material, preferably loaded at 40 to 60 percent by volume relative to the porous alumina coating.

Compositions and methods related to the synthesis and application of poly(aryl ether)s are generally described.

Adsorbent material for use in pressure swing adsorption (PSA) related processing can provide improved purification processing with reduced temperature differentials between adsorption and desorption processing of the bed of adsorbent material. Embodiments can be configured so that adsorbent material has occluded micropores or macropores. The occlusion of the micropores or macropores can be up to 42% of the micropores the adsorbent material in some embodiments. At least one metal acetate can be utilized for the occlusion of the micropores or macropores. Utilization of the adsorbent material having occluded micropores or macropores was surprisingly found to increase the yield for purification of a product gas in spite of the occlusion of the micropores or macropores.

The present disclosure relates to a composition that includes tetrakis(4-hydroxyphenyl)ethylene (THPE), an amino polymer, and a substrate that includes a metal oxide, where the substrate has a pore volume, and the THPE and the amino polymer are positioned within the pore volume.