The present invention provides an improved sorbent and corresponding device(s) and uses thereof for the capture and stabilization of volatile organic compounds (VOC) or semi-volatile organic compounds (SVOC) from a gaseous atmosphere. The sorbent is capable of rapid and high uptake of one or more compounds and provides quantitative release (recovery) of the compound(s) when exposed to elevated temperature and/or organic solvent. Uses of particular improved grades of mesoporous silica are disclosed.

Provided herein are electret-MOF filter embedded with particles derived from metal-organic frameworks (MOF) and their methods of manufacturing. The methods of manufacturing the electret-MOF filter can include suspending MOF particles in a solvent to form a MOF particle mixture, contacting a charged polymeric fibrous web with the MOF particle mixture, and coating the charged polymeric fibrous web with the MOF particles by flowing the MOF particle mixture through an inverse side of the polymeric fibrous web. The disclosed coating method can deposit MOF particles uniformly, without formation of films at interstitial spaces between fibers. The electret-MOF filter can simultaneously remove fine particulate matters (PMs) and hazardous gaseous pollutants (including volatile organic compounds (VOCs)) with high particle holding and gas adsorption capacities, and with very low air resistance.

The present invention provides for the use of a metal-organic framework (MOF) in removing particular chemical species or compounds, in particular oxy-anions of iodate, from a liquid or liquid stream. In some embodiments, the MOF is a Zr-based MOF, such as NU-1000 or MOF-808. The Zr-based MOF, including NU-1000 or MOF-808 can be used to remove these oxy-anions from various liquid streams or liquids in industrial processes such as a nuclear and fossil fuel power plants.

The present invention relates to the extraction of lithium from liquid resources such as natural and synthetic brines, leachate solutions from minerals, and recycled products.

A method for manufacturing a carbon dioxide adsorbent includes: forming a kneaded product containing a hydrophilic fiber, a powdery porous material, and an aqueous hydrophilic binder dispersion into particles and drying the particles to generate porous material particles containing the hydrophilic fiber and the powdery porous material combined by the hydrophilic binder; and preparing an aqueous amine solution having an amine concentration of 5% or more and 70% or less and a temperature of 10° C. or higher and 100° C. or lower, impregnating the aqueous amine solution into the porous material particles, and aeration-drying the porous material particles impregnating the amine. The carbon dioxide adsorbent contains the porous material particles and the amine carried by the porous material particles, the porous material particles containing the hydrophilic fiber and the powdery porous material combined by the hydrophilic binder.

Disclosed are embodiments of a filter unit containing a water adsorbent material in the form of water adsorbent particles in a packed bed and a gas adsorbent material in the form of gas adsorbent particles in a packed bed. In embodiments, the gas adsorbent material is downstream from the water adsorbent material in a direction of operation. Further disclosed are methods of preparing and using the filter units.

The invention discloses a core-shell structure polymer magnetic nanosphere with a high Cr (VI) adsorption capacity and its preparation method and application. The preparation method includes: adding Fe.sub.3O.sub.4 powder into a mixed solution of water and ethanol, dispersing Fe.sub.3O.sub.4 powder in the solution evenly by ultrasound, sequentially adding resorcinol and formaldehyde into the suspension to adjust a pH, stirring and reacting to obtain Fe.sub.3O.sub.4@RF evenly dispersed in a chitosan solution, dropwise adding the prepared suspension into a mixed solution of paraffin and span 80, stirring for a period of time, adding a glutaraldehyde aqueous solution, stirring and reacting to obtain a magnetic chitosan nanosphere. The magnetic chitosan nanosphere prepared may be applied to adsorbing Cr (VI) in a water solution. Not only the magnetic chitosan nanospheres prepared has a high adsorption capacity for Cr (VI), but also can be quickly separated by an external magnetic field after adsorption.

The method and materials of this invention make possible substantially faster techniques for organic-aqueous extractions and routine chemical reactions work-ups. The inventive material uses silicone elastomer-coated glass powders, magnetic powders, and sponges as absorbents to extract organic products from an aqueous mixture. After separation from the mixture, these different forms now loaded with organic products can serve as a convenient input for flash chromatographic separations or other processing. With these techniques, tedious liquid-liquid extractions are replaced by a simple solid filtration or transfer and emulsion formation is eliminated. These versatile sorbents can also be used for larger scale work-ups, various extractions of organics from an aqueous solution (e.g., water purification) or gas phase and various analytical or other applications.

A composition having the structure of formula I:
[R—Ar—(COOH).sub.2].sub.x[Ar—(COOH).sub.3].sub.2-xM.sub.3.sup.2+  (I)
is provided where M is Mn, Cu, Co, Fe, Zn, Cd, Ni, or Pt; R is a bromine, nitro, a primary amine, C.sub.1-C.sub.4 alkyl secondary amine, C.sub.1-C.sub.4 alkyl oxy, Br—(C.sub.1-C.sub.4 alkyl), NO.sub.2—(C.sub.1-C.sub.4 alkyl), a mercaptan, and reaction products of any of the aforementioned with acyl chlorides of the formulas: CH.sub.3(CH.sub.2).sub.mC(O)Cl, or CH.sub.3(CH(C.sub.1-C.sub.4 alkyl)CH.sub.2).sub.mC(O)Cl, or CH.sub.3(CH.sub.2).sub.m-Ph-(CH.sub.2).sub.pC(O)Cl, where Ph is a C.sub.6 phenyl or C.sub.6 phenyl with one or more hydrogens replaced with F, C.sub.1-C.sub.4 fluoroalkyl, or C.sub.1-C.sub.4 perfluoroalkyl; m is independently in each occurrence an integer of 0 to 12 inclusive; p is an integer of 0 to 36 inclusive, to form an amide, a thioamide, or an ester; Ar is a 1,3,5-modified phenyl, and 1.4>x>0. A process of synthesis thereof and the use to chemically modify a gaseous reactant are also provided.

The present disclosure provides methods and compositions for mitigating residue transfer from diatomaceous earth-based compositions. Some aspects of the disclosure provide a method of reducing residue transfer from a diatomaceous earth-based material by contacting a diatomaceous earth-based material with a content of a layered silicate solution sufficient to reduce residue transfer therefrom. Other aspects of the disclosure provide animal litter compositions including particles of a diatomaceous earth material at least partially coated by a layered silicate. Still other aspects of the disclosure provide a method of preparing an animal litter composition having reduced residue transfer, the method including forming an animal litter composition as a mixture of particles of a diatomaceous earth-based material and a layered silicate.