Guanidinyl ligand-functionalized polymers, methods of making the same, and substrates bearing a grafted coating of the ligand-functional polymers are described. The grafted polymer has the requisite affinity for binding neutral or negatively charged biomaterials, such as cells, cell debris, bacteria, spores, viruses, nucleic acids, endotoxins and proteins, at pH's near or below the pI's of the biomaterials.

A method for trapping noble gas atoms and molecules in oxide nanocages that includes providing oxide nanocages on a metallic substrate, ionizing a noble gas to form noble gas cations, applying a voltage to the metallic substrate, contacting the oxide nanocages with the noble gas cations, and deionizing the cations to form noble gas atoms and molecules that are trapped within the oxide nanocages. In one embodiment of the present device, polygonal prism organosilicate cages on a ruthenium thin film can trap noble gases.

A method for purifying dye-containing wastewater based on a porous-polymer-modified metal carbon nanotube membrane includes: (1) preparing the porous-polymer-modified metal carbon nanotube membrane; and (2) passing the dye-containing wastewater through the porous-polymer-modified metal carbon nanotube membrane to remove dyes in the dye-containing wastewater. A device for purifying dye-containing wastewater is also disclosed. The device includes the porous-polymer-based metal carbon nanotube membrane.

An apparatus for fabricating a graphene membrane includes a first section having a first fluid chamber for housing a suspension of graphene platelets in a fluid. A second section is positionable adjacent the first section. The second section has a second fluid chamber and a porous support housed in the second fluid chamber for supporting a porous substrate. When the first section is positioned adjacent to the second section and the porous substrate is supported by the porous support, the first fluid chamber and the second fluid chamber are in fluid communication via the porous substrate. The apparatus further includes a pressurizer for creating a pressure differential between the first fluid chamber and the second fluid chamber and thereby forcing the fluid through the porous substrate and into the second fluid chamber and lodging the graphene platelets in the pores of the porous substrate.

In a chemical heat pump involving a sorption process and a matrix holding an active substance, at least the active substance is in a material comprising graphene and/or graphene oxide. This material is designed to take use of the great energy content in some salts and making the whole range from diluted solutions to solid crystals available. The heat transfer to and from the active substance is improved, the ability of the matrix to hold active substance in liquid state is improved, the mechanical strength of the matrix is improved, power and energy can be varied better according to requirements in a specific application, the system pressure becomes more flexible.

Articles with covalently attached thiocarbonylthio-containing groups are provided. More specifically, the articles include a solid polymeric substrate with a plurality of thiocarbonylthio-containing groups covalently attached directly to a carbon atom in a polymeric backbone of the solid polymeric substrate. Methods of making the articles with covalently attached thiocarbonylthio-containing are provided. Additionally, methods of using these articles to generate further articles with covalently attached polymeric chains are provided.

An apparatus for fabricating a graphene membrane includes a first section having a first fluid chamber for housing a suspension of graphene platelets in a fluid. A second section is positionable adjacent the first section. The second section has a second fluid chamber and a porous support housed in the second fluid chamber for supporting a porous substrate. When the first section is positioned adjacent to the second section and the porous substrate is supported by the porous support, the first fluid chamber and the second fluid chamber are in fluid communication via the porous substrate. The apparatus further includes a pressurizer for creating a pressure differential between the first fluid chamber and the second fluid chamber and thereby forcing the fluid through the porous substrate and into the second fluid chamber and lodging the graphene platelets in the pores of the porous substrate.

The present disclosure is directed to absorbent articles with substrates or topsheets having repeating patterns of apertures comprising a plurality of repeat units. Each of the repeat units comprises at least three apertures.

The present invention provides a novel method to fabricate silica nanostructures on thin polymer films based on silica deposition and self-wrinkling induced by thermal shrinkage. These micro- and nano-scale structures have vastly enlarged the specific area of silica, thus the silica nanomembranes can be used for solid phase extraction of nucleic acids. The inventive silica nanomembranes are suitable for nucleic acid purification and isolation and demonstrated better performance than commercial particles in terms of DNA recovery yield and integrity. In addition, the silica nanomembranes have extremely high nucleic acid capacity due to its significantly enlarged specific surface area of silica. Methods of use and devices comprising the silica nanomembranes are also provided.

Polymeric amine solid sorbents with enhanced stability to moisture and/or oxygen for sorptive gas separation processes are disclosed. The polymeric amine solid sorbents can be supported on a porous support or integrated into solid porous polymer networks. Sorptive gas separators can employ contactors with such polymeric amine solid sorbents for separation of a component from a multi-component gas stream.