This disclosure relates to nanoporous pure silica zeolite (PSZ) adsorbents and uses thereof.

A method for forming an integrated composite comprises providing a three-dimensional substrate having at least one channel; coating the substrate with a phenolic resin, wherein coating comprises dispersing the phenolic resin on the substrate, impregnating the phenolic resin in the substrate or a combination of both; curing the substrate and the phenolic resin; heating the cured substrate and cured phenolic resin to a temperature in a range of about 600? C. to about 1100? C. in an inert environment thereby pyrolyzing the phenolic resin, forming a conductive carbon network on, in, or both on and in the substrate; and coating a support material on, in, or both on and in the substrate to form an integrated composite.

The invention relates to a noxious gas purificant and its preparation and purification method for removing nitrogen oxides from gas streams thereof. The preparing method is characterized in that: mixing, according to a predetermined ratio and a process, a salt of iron, manganese, cobalt, or copper, and a related derivative thereof, an alkali or alkaline substance and a related derivative thereof, water and a forming agent, so as to obtain a solid compound or mixture; drying and activating the solid compound or mixture to produce a solid product as the purificant; and introducing the purificant into a gas-solid reactor, and removing noxious gases in a gas stream by performing, in a preconfigured temperature and using the purificant, a gas-solid reaction on the harmful gases in the gas stream. The purificant can be recycled and reused.

Disclosed are metal organic frameworks (MOFs) for adsorbing guest species, methods for the separation of gases using the MOFs, and systems comprising the MOFs. The MOFs comprise a plurality of secondary building units (SBUs), each SBU comprising a repeating unit of one metal cation connected to another metal cation via a first moiety of an organic linker; a layer of connected adjacent SBUs in which a second moiety of the linker in a first SBU is connected to a metal cation of an adjacent SBU, and wherein adjacent layers are connected to each other via linker-to-linker bonding interactions.

A hydrogen feed stream comprising oxygen and one or more impurities selected from the group consisting of nitrogen, argon, methane, carbon monoxide, carbon dioxide, and water, is purified using a cryogenic temperature swing adsorption (CTSA) process with high overall recovery of hydrogen. The CTSA is regenerated using an inert gas to prevent an explosive mixture of hydrogen and oxygen from occurring.

Acid gas compounds are removed from a process gas such as, for example, syngas or natural gas, by flowing a feed gas into a desulfurization unit to remove a substantial fraction of sulfur compounds from the feed gas and flowing the resulting desulfurized gas into a CO.sub.2 removal unit to remove a substantial fraction of CO.sub.2 from the desulfurized gas.

Disclosed herein are systems and methods for regenerating media in a siloxane removal system. In particular, the present disclosure relates to a method for regenerating an adsorption medium, comprising receiving a source gas stream comprising at least one hydrocarbon and carbon dioxide; separating the source gas stream into a carbon dioxide-rich gas stream, and a substantially carbon dioxide-free gas stream; directing the carbon dioxide-rich gas stream into a regeneration vessel containing an adsorption medium having one or more adsorbed impurities on the adsorption medium; desorbing impurities from the adsorption medium by contacting the adsorption medium with the carbon dioxide-rich gas stream to generate a carbon dioxide-rich gas containing desorbed impurities and a regenerated adsorption medium; and directing the carbon dioxide-rich gas stream containing desorbed impurities out of the regeneration vessel.

A system for recovering nitrogen during regeneration of a treater, the system including an adsorbent bed downstream of the treater, wherein the adsorbent bed comprises an adsorbent operable to adsorb at least one impurity from a treater bed regeneration effluent stream comprising nitrogen to provide a nitrogen product having a higher nitrogen purity than a nitrogen purity of the treater bed regeneration effluent stream. A method for recovering nitrogen during regeneration of a treater is also provided.

A dual function material is provided that captures carbon dioxide from ambient air, i.e., direct air capture, and converts the CO.sub.2 to a desired product such as methane. The material includes a high surface area carrier such as Al.sub.2O.sub.3 upon which catalysts and alkaline adsorbents are positioned proximate each other. In the presence of reactive gas such as hydrogen, the catalysts reduce the adjacent adsorbents to generate additional active sites and enhance the amount of CO.sub.2 captured by the material. Once the material becomes saturated with CO.sub.2, hydrogen is reintroduced to reduce the catalyst, such as ruthenium, at which time the adsorbed CO.sub.2 can migrate from the adsorbent to the catalyst for catalytic conversion to methane. The materials can be employed in isothermal, cyclic reactor systems where target species are bound and then desorbed to reactivate the material, e.g., bind more target species for desorption and/or conversion to additional product.

This present disclosure relates to processes for removing contaminants from hydrocarbon streams, e.g. removing chlorides, CO.sub.2, COS, H.sub.2S, AsH.sub.3, methanol, mercaptans and other S- or O-containing organic compounds from olefins, paraffins, aromatics, naphthenes and other hydrocarbon streams. The process involves contacting the stream with an adsorbent which comprises a zeolite, an alumina component and a metal component e.g. sodium, in an amount at least 30% of the zeolite's ion exchange capacity.