To provide an immunoglobulin purification method which achieves a high immunoglobulin recovery percentage without causing loss of the antibody nature of an immunoglobulin. The immunoglobulin purification method includes an adsorption step and a desorption step. The adsorption step involves adsorption of an immunoglobulin onto porous zirconia particles in a neutral buffer. The desorption step involves desorption of the immunoglobulin adsorbed on the porous zirconia particles from the porous zirconia particles by means of a neutral desorption liquid.

A composite material for use in water treatment. The composite material includes a porous matrix including a resin capable of retaining a catalyst and magnetic material therein, and includes a density regulating portion disposed therein. The catalyst is capable of facilitating a chemical reaction involving a contaminants in the water. The magnetic material and density regulating portion can be used to separate the composite material from treated water. Systems and methods of use involving passive water treatment, continuous water treatment, solar light exposure, UV light exposure, and electrochemical cells, employing photochemical, electrochemical, and photoelectrochemical reactions are described. Methods of manufacture are described.

A mobile phase including a lithium salt flows through a stationary phase including an oxygenated metal compound with affinity to the lithium salt through a Lewis acid-Lewis base interaction so that the oxygenated metal compound captures the lithium salt through the Lewis acid-Lewis base interaction. An eluent flows through the stationary phase to release the lithium salt captured by the oxygenated metal compound into the eluent. The eluent includes a Lewis base or a Lewis acid that disrupts the Lewis acid-Lewis base interaction between the lithium salt and the oxygenated metal compound. The eluent including the released lithium salt is collected after the eluent flows through the stationary phase.

Crosslinked polymers made up of polymerized units of cyclic diaminoalkane, aldehyde and bisphenol-S or melamine. A method for removing heavy metals, such as Pb(II) from an aqueous solution or an industrial wastewater sample with these crosslinked polymers is introduced. A process of synthesizing the crosslinked polymers is also described.

Provided is a method for producing a lithium-containing solution that prevents the dissolution of the whole lithium manganese oxide while maintaining the efficiency of an elution step. The method for producing a lithium-containing solution comprises performing an adsorption step of contacting a lithium adsorbent obtained from lithium manganese oxide with a low lithium-containing liquid for adsorption to give post-adsorption lithium manganese oxide, an elution step of contacting the post-adsorption lithium manganese oxide with an acid solution to give a lithium-containing solution with residual manganese, and a manganese oxidation step of oxidating manganese to give a lithium-containing solution with a suppressed manganese concentration, performed in this order. The acid solution is a 0.5 mol/L or more and 4.0 mol/L or less hydrochloric acid solution. According to the production method, in the elution step, the dissolution of the whole lithium manganese oxide can be suppressed while maintaining the efficiency of exchange reaction between cations including Li.sup.+ and H.sup.+. Thus, the repeated use of the lithium adsorbent becomes possible.

A regeneration solvent comprised of one or more ethylene amines may contact an adsorbent bed that has been used to remove sulfur compounds from a hydrocarbon stream to extract adsorbed sulfur compounds from the adsorbent material in the bed to regenerate it. The one or more ethyleneamines may have structure (I), (II), or (III):

##STR00001##

where R.sup.1, R.sup.2, R.sup.5 and R.sup.6 are, to the extent chemically possible, independently H, C.sub.1-C.sub.4 linear or branched alkyl, amido (RRNC═O), or hydroxyalkyl, where each R in the amido group is independently H or C.sub.1 alkyl, where R.sup.3 and R.sup.4 are alkylene of from 1 to 4 carbon atoms, where x ranges from 0 to 3, y ranges from 1 to 6. The regenerated adsorbent bed may be reused, either alone or in combination with a liquid-liquid extraction column, to remove sulfur compounds from a hydrocarbon stream.

A solvent comprised of (1) a caustic and an alcohol, (2) a caustic and a quaternary ammonium hydroxide, or (3) a caustic, an alcohol, and a quaternary ammonium hydroxide may contact an adsorbent bed that has been used to remove sulfur compounds from a hydrocarbon stream to extract adsorbed sulfur compounds from the adsorbent material in the bed to regenerate it. The regenerated adsorbent bed may be reused, either alone or in combination with a liquid-liquid extraction column, to remove sulfur compounds from a hydrocarbon stream.

A process for deodorizing a rosin ester composition is disclosed. The process employs an adsorptive bed containing an adsorbent material. The adsorbent material comprises silica adsorbent having an average pore size between 50-200 Å, BET surface area of at least 300 mm.sup.2/g, pore volume of 1.20 to 3.00 cc/g, and a silanol [Si—OH] level of 0.5 to 5 unit/nm.sup.2. The deodorized rosin ester composition has an odor intensity reduction of at least 1 unit on odor intensity scale of Offensive Odor Control Act as compared to the rosin ester feedstock. In embodiment, the deodorizing treatment comprises using multi-staged adsorbent system with an adsorbent column having multiple layers of different adsorbent materials.

An object of the present invention is a method for recycling a metal or several metals M selected from among those belonging to the columns 8 to 12 of the periodic table of elements, present at least partially in the form of metal sulphides in a porous material A comprising at least one mineral oxide and having a sulphur content higher than or equal to 2% by weight. Said method comprises the following successive steps: (1) at least one step of heat treatment of the material A in the presence of oxygen, at a temperature comprised within the range from 350° C. to 900° C.; (2) at least one step of washing the material A′ derived from step (1) by means of an aqueous solvent; (3) at least one step of extracting the metal(s) M by setting the material A″ derived from step (2) in contact with a solution S containing at least one carboxylic acid; and (4) at least one step of depositing at least one portion of the metal(s) M over a porous material B different from said material A, by setting the solution S′ derived from step (3) in contact with said material B.

The invention generally relates to a carbon-based boron removal medium with hydroxyl group and amine group, and in particular, to a method for forming the carbon-based boron removal medium. In various embodiments, nitrogen-doped (“N-doped”) graphene oxide is synthesized by a simple two-step process: (1) oxidation of graphite to graphene oxide, and (2) nitrogen-doping (“N-doping”) the graphene oxide to form the amine group. The resultant N-doped graphene oxide can efficiently remove boron from aqueous solutions. The invention also generally relates to a boron sensing medium and its use in conductometric measurement techniques to detect and measure the amount of boron present in aqueous solutions.