A microsphere of oxide has an opening on its surface connected to a hollow core inside, forming a cavity. The oxide the microsphere is made of is selected from the group consisting of alumina, silica, zirconia, magnesium oxide, calcium oxide and titania. The microsphere of oxide shows better mass and heat transfer characteristics, and has strength significantly higher than that of existing products with similar structures. A FT synthesis catalyst has the microsphere of oxide as a support and an active metal component disposed on the support. The active metal component is one or more selected from the group consisting of Co, Fe, and Ru.

Disclosed is a ruthenium-based catalyst for ammonia synthesis, preparation method and use thereof. The ruthenium-based catalyst comprises Ru—Ba-A core-shell structure which comprises a ruthenium nanoparticle as a core covered with a first shell and a second shell sequentially, wherein the first shell consists of a barium nanoparticle, and the second shell consists of a metal oxide. The Ru—Ba-A core-shell structure can effectively preventing agglomerations of ruthenium nanoparticles during the use of the catalyst and avoiding direct contact between the ruthenium nanoparticles and the metal oxides. In addition, barium nanoparticles have a promoting effect as an electronic promoter, which can effectively improve the stability and catalytic activity of ruthenium-based catalyst for ammonia synthesis, especially in the system for synthesizing ammonia from a coal gas.

This invention provides an anisotropic nanostructure represented by the formula:
Ru.sub.xM.sub.1-x,
wherein 0.6≤x≤0.999, and M represents at least one member selected from the group consisting of Ir, Rh, Pt, Pd, and Au, and wherein Ru and M form a solid solution at the atomic level, and the anisotropic nanostructure has an anisotropic hexagonal close-packed structure (hcp).

This invention relates to a method for preparing 1,4-cyclohexanedimethanol (CHDM), more specifically to a method for preparing 1,4-cyclohexanedimethanol having a high rate of trans isomers without an isomerization reaction step, wherein two-step hydrogenation reactions and a purification step are conducted using terephthalic acid as starting material.

This invention relates to a method for preparing 1,4-cyclohexanedimethanol(CHDM), more specifically to a method for preparing 1,4-cyclohexanedimethanol having a high rate of trans isomers without an isomerization reaction step.

The present disclosure generally relates to a process for coating a scaffold, and in particular a process for coating a scaffold of a static mixer using catalytic liquid suspensions. The present disclosure also generally relates to a process for preparing a catalytically coated scaffold comprising applying a catalytic liquid suspension to a surface of a scaffold to provide a coating containing catalytically reactive sites on the surface of the coated scaffold.

Irradiating a film of a thiophene polymer that is a pure organic compound with light allows the thiophene polymer film to act as a light absorber and catalyst that produces hydrogen peroxide from water and water-dissolved air (oxygen) at extremely high efficiency, and this film can work in alkaline water in which a film of a general-purpose inexpensive water-oxidizing catalyst, which is used as a counter electrode, is active. Provided is an environmentally compatible and simple method for producing hydrogen peroxide at extremely high efficiency, including combining a film of a catalyst for light absorption and oxygen reduction that consists of a thiophene polymer with a catalyst for water oxidation, immersing the combination in alkaline water, and irradiating the light-absorbing oxygen reduction catalyst film with light.

The present invention relates to a catalyst in which a catalytic metal is supported on a support including a single-crystalline hexagonal material, and a preparation method therefor, wherein the catalyst can be effectively used in ammonia dehydrogenation or ammonia synthesis.

An automotive catalytic converter includes a three-way catalyst having Rh as the only precious metal configured as a front zone and a three-way catalyst having a mixture of Rh and Pd, Pt, or both configured as a rear zone, such that an exhaust gas from an internal combustion engine passes through the front zone before passing through the rear zone to minimize sulfur poisoning of the catalytic converter.

Disclosed herein are a calcium salts-supported metal catalyst, a method for preparing the same, and a method for the hydrodeoxygenation reaction of oxygenates using the same. The catalyst, in which a metal catalyst is supported on a carrier of a calcium salt, for example, calcium carbonate, has the effect of increasing the efficiency of hydrodeoxygenation reaction of oxygenates.