Patent classifications
B01J29/7007
Process for dehydrating methanol to dimethyl ether
A process for dehydrating methanol to dimethyl ether using a Brønsted acid catalyst which is a 1-dimensional or a 3-dimensional aluminosilicate zeolite or a heteropolyacid, and a promoter of Formula I C.sub.nH.sub.(2n+1)CO.sub.2CH.sub.3 wherein n=1 to 11 or Formula II C.sub.mH.sub.2m(CO.sub.2CH.sub.3).sub.2 wherein m=2 to 7 and the molar ratio of promoter to methanol is maintained at less than 1.
Method for producing 2-furaldehyde
An object of the present invention is to provide a method for suppressing the corrosion of a reactor and reducing waste in the production of 2-furaldehyde from a sugar raw material containing a hexose as a constituent component, and another object of the invention is to provide an industrially advantageous method for producing 2-furaldehyde, which suppresses a decrease in the activity of a catalyst in a case of using an acid catalyst and provides a higher yield. The present invention relates to a method for producing 2-furaldehyde comprising heating a sugar raw material containing a hexose as a constituent component in an aprotic polar solvent in the presence of a solid acid catalyst.
Method for Preparing Methyl Formate and Coproducing Dimethyl Ether
Method for preparing methyl formate and coproducing dimethyl ether by reacting a formaldehyde and methanol raw material (molar ratio range of 1:4 to 1:0.05) in a First Reaction Region at ranges from 50° C. to 100° C. with Catalyst A resulting in post-reaction material separated into Constituent I. Reacting Constituent I in a Second Reaction Region at ranges from 50° C. to 200° C. and from 0.1 MPa to 10 MPa with Catalyst B resulting in post-reaction material, which is separated into methyl formate, dimethyl ether and Constituent II. At least 1% of dimethyl ether is product, and recycling the rest to the First Reaction Region. Constituent II is recycled to the Second Reaction Region. Each component is gaseous phase and/or liquid phase, independently. The method shows long catalyst life, mild reaction condition, high utilization ratio of raw materials, continuous production and large scale industrial application potential.
Catalytic system and process for the hydroconversion of heavy oil products
Catalytic system which can be used in processes for the hydroconversion of heavy oils by means of hydrotreatment in slurry phase, characterized in that it comprises: a catalyst, having the function of hydrogenating agent, containing MoS.sub.2 or WS.sub.2 or mixtures thereof in lamellar form or an oil-soluble precursor thereof; a co-catalyst, having nanometric or micronic particle-sizes, selected from cracking and/or denitrogenation catalysts. The co-catalyst preferably consists of zeolites having small-sized crystals and with a low aggregation degree between the primary particles, and/or oxides or sulfides or precursors of sulfides of Ni and/or Co in a mixture with Mo and/or W.
MODIFIED BETA ZEOLITIC (*BEA) CATALYST FOR ISOMERIZATION OF ALKYLATED AROMATICS, AND METHOD FOR ISOMERIZATION OF ALKYLATED AROMATICS
The present invention relates to a catalyst for isomerization of alkylated aromatics such as mixed xylenes, using xylene isomerization catalyst particles including post-framework modified *BEA zeolite in which zirconium atoms and/or hafnium atoms, optionally in combination with titanium atoms, form a part of a framework of a beta-type zeolite.
Catalytic cracking process and catalyst system therefor
A catalytic cracking process includes a step of contacting a cracking feedstock with a catalytic cracking catalyst in the presence of a radical initiator for reaction under catalytic cracking conditions. The radical initiator contains a dendritic polymer and/or a hyperbranched polymer. The dendritic polymer and the hyperbranched polymer each independently has a degree of branching of about 0.3-1, and each independently has a weight average molecular weight of greater than about 1000. The catalytic cracking process is beneficial to enhancing and accelerating the free radical cracking of petroleum hydrocarbon and promoting the regulation of cracking activity and product distribution; by using the process disclosed herein, the conversion of catalytic cracking can be improved, the yields of ethylene and propylene can be increased, and the yield of coke can be reduced.
Process for producing BTX by catalytic pyrolysis from biomass with injection of oxygenated compounds
A process is described for producing a BTX cut from biomass comprising at least one step of catalytic pyrolysis of said biomass in a fluidized-bed reactor in which a stream comprising at least one oxygenated compound selected from alcohols having 2 to 12 carbon atoms, alcohol acids having 2 to 12 carbon atoms, diols having 2 to 12 carbon atoms, carboxylic acids having 2 to 12 carbon atoms, ethers having 2 to 12 carbon atoms, aldehydes having 2 to 12 carbon atoms, esters having 2 to 12 carbon atoms and glycerol, alone or mixed, is fed into the catalytic pyrolysis reactor.
SYNTHESIS OF N-(2,4-DINITROPHENYL)-4-NITROBENZAMIDE (TNBA) USING SOLID ACID CATALYSTS
A method of making N-(2,4-dinitrophenyl)-4-nitrobenzamide from a mixture of 2,4-dinitroaniline, 4-nitrobenzoyl chloride, and solid acid catalyst in an organic solvent, wherein the solid acid catalyst is not soluble in the organic solvent, the solid acid catalyst being an acidic clay, an ion exchange resin, a beta zeolite, a sulfonated tetrafluoroethylene-based fluoropolymer-copolymer, or some mixture of these.
Process for producing a catalyst and catalyst as such
To be able to produce an SCR catalyst (2), in particular one having a zeolite fraction (Z) as catalytically active fraction, in a reliable process and at the same time achieve good catalytic activity of the catalyst (2), an inorganic binder fraction (B) which is catalytically inactive in the starting state and has been treated to develop catalytic activity is mixed into a catalyst composition (4). The inorganic binder component for the binder fraction (B) is, in the starting state, preferably porous particles (10), in particular diatomaceous earth, which display mesoporosity. To effect catalytic activation, the individual particles (10) are either coated with a catalytically active layer (12) or transformed into a catalytically active zeolite (14) with maintenance of the mesoporosity.
DIESEL ENGINE EXHAUST GAS PURIFICATION CATALYST, PRODUCTION METHOD THEREFOR, AND EXHAUST GAS PURIFICATION METHOD USING THE SAME
It is an object to provide a catalyst that can effectively purify exhaust gas, in particular, carbon monoxide (CO) in exhaust gas, emitted from a diesel engine, a production method therefor, and an exhaust gas purification method using the same. A diesel engine exhaust gas purification catalyst for purifying exhaust gas emitted from a diesel engine of the present invention comprises a precious metal and alumina and/or zeolite supported on a three-dimensional structure, and has peaks for not less than three different pore sizes in a pore size distribution measured by the mercury intrusion method, wherein one of the peaks is a peak 2 at a pore size of not less than 0.3 μm and less than 1.0 μm, and the pore volume of the peak 2 being greater than 3.1% of the total pore volume.