Disclosed herein is a catalytic process for producing higher olefins including three- to four-carbon olefins from ethene sources by producing an ethene-containing stream from an ethene source, and subjecting the ethene-containing stream to a catalytic oligomerization process. In this catalytic process, the catalytic oligomerization process comprises exposing the ethene-containing stream in contact with a catalyst including a mixture of a zeolite material and a zeotype material.

A process the dehydration of methanol to dimethyl ether in the presence of a solid Brønsted acid catalyst selected from aluminosilicate zeolites which have a maximum free sphere diameter of greater than 3.67 Angstroms and heteropolyacids and a promoter selected from methyl formate, dimethyl oxalate and dimethyl malonate and the molar ratio of promoter to methanol is maintained at less than 1.

Provided is a method for preparing a zeolite having a Si/Al ratio of at least 10 by interzeolite transformation in the absence of an organic structure directing agent. The method is more cost effective and less equipment intensive as it eliminates the costly organic structure directing agent and the waste treatment at the plant.

Provided is a honeycomb catalyst in which a plurality of through holes are provided in proximity to each other in a row arrangement in the lengthwise direction, and are set apart by partitions. A honeycomb unit contains at least two types of inorganic particles and an inorganic binder. The inorganic particles contain zeolite having an SiO2/Al2O3 composition ratio of less than 15 and a CHA structure and an oxide other than zeolite, which has a positive thermal expansion coefficient. The ratio (X:Y) of the volume (X) of zeolite and the volume (Y) of oxide is 50:50 to 80:20. A displacement amount of absorbed water is reduced and cracking is controlled while maintaining high NOx purging performance.

The present invention relates to a method for the preparation of a molecular sieve of the CHA-type as well as catalytic applications thereof.

The present disclosure is directed to processing for preparing crystalline pure-silica and heteroatom-substituted LTA frameworks in fluoride media using a simple organic structure-directing agent (OSDA), having a structure of Formula (I): ##STR00001##
where substituents R.sup.1 to R.sup.9 are defined herein. Aluminosilicate LTA is an active catalyst for the methanol to olefins reaction with higher product selectivities to butenes as well as C5 and C6 products than the commercialized catalysts. Titanosilicate LTA is an active catalyst for the epoxidation of allyl alcohol using aqueous H.sub.2O.sub.2.

This disclosure relates to new crystalline microporous solids (including silicate- and aluminosilicate-based solids), the compositions comprising 8 and 10 membered inorganic rings, particularly those having IWV topologies having a range of Si:Al ratios, methods of preparing these and known crystalline microporous solids using certain quaternized imidazolium cation templates.

The honeycomb structure includes a honeycomb structure body made of a zeolite material containing at least a coarse particle zeolite having a large average particle diameter (coarse zeolite particles). A fine particle zeolite having an average particle diameter smaller than that of the coarse particle zeolite (fine zeolite particles), and an inorganic bonding material, the coarse particle zeolite (the coarse zeolite particles) is a chabazite type zeolite in which an average particle diameter of primary particles is 2 μm or more and 6 μm or less, and in the fine particle zeolite (the fine zeolite particles), an average particle diameter of primary particles is 0.02 μm or more and smaller than 2 μm, and in the zeolite material which is comprised the honeycomb structure body, a ratio of a volume of pores having pore diameters of 0.02 to 0.15 μm to a volume of all pores is 42% or less.

The manufacturing method includes a step of mixing a coarse particle zeolite, a fine particle zeolite, and a raw material of an inorganic bonding material to prepare a zeolite raw material; a step of forming the prepared zeolite raw material into a honeycomb shape to prepare a honeycomb formed body; and a step of firing the prepared honeycomb formed body to prepare the honeycomb structure. In the step of preparing the zeolite raw material, as the coarse particle zeolite, a chabazite type zeolite having a specific average particle diameter, the fine particle zeolite having a specific average particle diameter, the raw material of the inorganic bonding material which includes at least basic aluminum lactate is used.

Hydrocarbon (HC) traps are disclosed. The HC trap may include a first zeolite material having an average pore diameter of at least 5.0 angstroms and configured to trap hydrocarbons from an exhaust stream and to release at least a portion of the trapped hydrocarbons at a temperature of at least 225° C. The HC trap may also include a second zeolite material having an average pore diameter of less than 5.0 angstroms or larger than 7.0 angstroms. One or both of the zeolite materials may include metal ions, such as transition, Group 1A, or platinum group metals. The HC trap may include two or more discrete layers of zeolite materials or the two or more zeolite materials may be mixed. The multiple zeolite HC trap may form coke molecules having a relatively low combustion temperature, such as below 500° C.