B01J29/7015

AEI TYPE ZEOLITE, METHOD FOR PRODUCING SAME, AND USES THEREOF

Provided is a method for producing an inexpensive, high-performance AEI type zeolite and an AEI type zeolite having a Si/Al ratio of 6.5 or less by using neither an expensive Y type zeolite as a raw material nor dangerous hydrofluoric acid. The method for producing an AEI type zeolite having a Si/Al ratio of 50 or less includes: preparing a mixture including a silicon atom material, an aluminum atom material, an alkali metal atom material, an organic structure-directing agent, and water; and performing hydrothermal synthesis of the obtained mixture, in which a compound having a Si content of 20% by weight or less and containing aluminum is used as the aluminum atom material; and the mixture includes a zeolite having a framework density of 14 T/1000 Å.sup.3 or more in an amount of 0.1% by weight or more with respect to SiO.sub.2 assuming that all Si atoms in the mixture are formed in SiO.sub.2.

Catalyst and method for converting carbon-containing stream to C2 to C5 paraffins using it

A process for preparing C.sub.2 to C.sub.5 paraffins includes introducing a feed stream comprising hydrogen gas and a carbon-containing gas into a reaction zone of a reactor, and converting the feed stream into a product stream comprising C.sub.2 to C.sub.5 paraffins in the reaction zone in the presence of a hybrid catalyst. The hybrid catalyst includes a metal oxide catalyst component and a microporous catalyst component. The metal oxide catalyst component satisfies: an atomic ratio of Cu/Zn from 0.01 to 3.00; an atomic ratio of Cr/Zn from 0.01 to 1.50; and percentage of (Al+Cr) from greater than 0.0 at % to 50.0 at % based on a total amount of metal in the metal oxide catalyst component.

Process for producing a catalyst and catalyst as such

To be able to produce an SCR catalyst (2), in particular one having a zeolite fraction (Z) as catalytically active fraction, in a reliable process and at the same time achieve good catalytic activity of the catalyst (2), an inorganic binder fraction (B) which is catalytically inactive in the starting state and has been treated to develop catalytic activity is mixed into a catalyst composition (4). The inorganic binder component for the binder fraction (B) is, in the starting state, preferably porous particles (10), in particular diatomaceous earth, which display mesoporosity. To effect catalytic activation, the individual particles (10) are either coated with a catalytically active layer (12) or transformed into a catalytically active zeolite (14) with maintenance of the mesoporosity.

Method

A method for modifying the surface of a molecular sieve, comprising reacting a molecular sieve with an aminosilane, wherein the reaction is carried out in an aqueous solvent. A modified molecular sieve obtained by the method is also described.

Catalyst and method for preparing light olefin using direct conversion of syngas

A catalyst for preparing light olefin using direct conversion of syngas is a composite catalyst and formed by compounding component I and component II in a mechanical mixing mode. The active ingredient of component I is a metal oxide; and the component II is one or more than one of zeolite of CHA and AEI structures or metal modified CHA and/or AEI zeolite. A weight ratio of the active ingredients in the component I to the component II is 0.1-20. The reaction process has high product yield and selectivity, wherein the sum of the selectivity of the propylene and butylene reaches 40-75%; and the sum of the selectivity of light olefin comprising ethylene, propylene and butylene can reach 50-90%. Meanwhile, the selectivity of a methane side product is less than 15%.

CHA-TYPE ZEOLITE AND MANUFACTURING METHOD THEREOF

CHA-type zeolite in which the molar ratio of silica to alumina is less than 13, and the content of sodium is 100 ppm or more and 2000 ppm or less is provided. Such a CHA-type zeolite is obtained by a manufacturing method including obtaining a crystallized product by crystallizing a composition which includes a structure-directing agent source containing at least N,N,N-trialkylcyclohexylammonium cation, an alumina source, a silica source, a sodium source, and water and in which the molar ratio of silica to alumina is 20 or less and in which the molar ratio of potassium to sodium is less than 0.05, removing N,N,N-trialkylcyclohexylammonium cation from the crystallized product, and contacting the crystallized product with an ammonium-salt-containing solution having an ammonium concentration of 1 mass percent or more.

PROCESS

A process for dehydrating methanol to dimethyl ether product in the presence of a catalyst and a promoter, wherein the catalyst is at least one aluminosilicate zeolite, wherein:—the aluminosilicate zeolite is selected from: (i) a zeolite having a 2-dimensional framework structure comprising at least one channel having a 10-membered ring, and having a maximum free sphere diameter of at least 4.8 Angstroms; (ii) a zeolite having a 3-dimensional framework structure comprising at least one channel having a 10-membered ring; or (iii) a zeolite comprising at least one channel having a 12-membered ring;—the promoter is selected from one or more compounds of Formula I: (I) wherein Y is selected from a C.sub.1-C.sub.4 hydrocarbyl substituent, and wherein each of X and any or all of the Z's may independently be selected from hydrogen, halide, a substituted or unsubstituted hydrocarbyl substituent, or a compound of the formula —CHO, —CO.sub.2R, —COR, or —OR, where R is hydrogen or a substituted or unsubstituted hydrocarbyl substituent, and wherein the molar ratio of promoter to methanol is maintained at less than 1.

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LOW TEMPERATURE CO OXIDATION CATALYST
20220161248 · 2022-05-26 ·

The present disclosure is directed to a low temperature carbon monoxide (LT-CO) oxidation catalyst composition for abatement of exhaust gas emissions from a lean burn engine. The LT-CO oxidation catalyst composition includes an oxygen storage component (OSC), a first platinum group metal (PGM) component, and a promoter metal, wherein the OSC is impregnated with the first PGM component and the promoter metal and the LT-CO oxidation catalyst composition is effective for oxidizing carbon monoxide (CO) and hydrocarbons (HC) under cold start conditions. Further provided are catalytic articles including the LT-CO oxidation catalyst composition, which may optionally further include a diesel oxidation catalyst (DOC) composition (giving an LT-CO/DOC article). Further provided is an exhaust gas treatment system including such catalytic articles, and methods for reducing a HC or CO level in an exhaust gas stream using such catalytic articles.

Diesel oxidation catalyst and exhaust system

An oxidation catalyst for treating an exhaust gas from a diesel engine, which oxidation catalyst comprises: a first washcoat region comprising platinum (Pt), manganese (Mn) and a first support material; a second washcoat region comprising a platinum group metal (PGM) and a second support material; and a substrate having an inlet end and an outlet end; wherein the second washcoat region is arranged to contact the exhaust gas at the outlet end of the substrate and after contact of the exhaust gas with the first washcoat region.

SELECTIVE AMMONIA OXIDATION CATALYST

The invention relates to a selective ammonia oxidation catalysts comprising a platinum group metal and a support comprising TiO2 doped with 0-10% by weight of SiO.sub.2, WO.sub.3, ZrO.sub.2, Y.sub.2O.sub.3, La.sub.2O.sub.3, or a mixture thereof. The invention further comprises methods for the manufacture of the selective ammonia oxidation catalysts, and integrated catalyst systems comprising the selective ammonia oxidation catalysts for treating an exhaust gas stream.