This invention relates to heterogeneous catalysts useful for selective hydrogenation of unsaturated hydrocarbons, comprising palladium and optionally a promoter, supported on a substrate, having an uncoated BET surface area of 9 m.sup.2/g, the surface being coated with an ionic liquid. Also described are methods of making the catalysts and methods of selective hydrogenation of acetylene and/or dienes in front-end mixed olefin feed streams.

This invention relates to heterogeneous catalysts useful for selective hydrogenation of unsaturated hydrocarbons, comprising palladium and optionally a promoter, supported on a substrate, having an uncoated BET surface area of 9 m.sup.2/g, the surface being coated with an ionic liquid. Also described are methods of making the catalysts and methods of selective hydrogenation of acetylene and/or dienes in front-end mixed olefin feed streams.

A method for fabricating carbon cryogel exhibiting high surface area, an increased mesopore ratio, and cost-efficiency, utilizing biomass-derived, low-cost tannin and formaldehyde. Furthermore, this method incorporates calcium salt as a catalyst, a deviation from the widely used sodium carbonate. The resulting carbon cryogel possesses high surface area, an enhanced mesopore ratio, and improved sulfur loading capacity, rendering them ideal sulfur hosts for LiS batteries. The present method disclosed herein constitutes a significant improvement over the existing state-of-the-art carbon cryogel for LiS batteries, with potential implications for the progression of high-performance, cost-effective LiS batteries.

A method of controlling a hydrocarbon conversion process is described. The method involves introducing a reactant into a reaction zone containing an ionic liquid catalyst. The reaction zone has at least two zones. The mass transfer resistance in the second zone is greater than the mass transfer resistance in the first zone.

An electrocatalytic process for carbon dioxide conversion includes combining a Catalytically Active Element and a Helper Polymer in the presence of carbon dioxide, allowing a reaction to proceed to produce a reaction product, and applying electrical energy to said reaction to achieve electrochemical conversion of said carbon dioxide reactant to said reaction product. The Catalytically Active Element can be a metal in the form of supported or unsupported particles or flakes with an average size between 0.6 nm and 100 nm. The reaction products comprise at least one of CO, HCO.sup., H.sub.2CO, (HCO.sub.2).sup., H.sub.2CO.sub.2, CH.sub.3OH, CH.sub.4, C.sub.2H.sub.4, CH.sub.3CH.sub.2OH, CH.sub.3COO.sup., CH.sub.3COOH, C.sub.2H.sub.6, (COOH).sub.2, (COO.sup.).sub.2, and CF.sub.3COOH.

The instant disclosure relates to liquid salts such as but not limiting to ionic liquids; and method for recovering liquid salts including ionic liquids. Ionic liquids get deactivated due to presence of various contaminants or impurities. The present disclosure deals with recovery and regeneration of ionic liquids using compounds containing at least one coordinating agent to form adduct with metal compounds. The instant disclosure also includes an assembly for carrying out the recovery and regeneration of the ionic liquids.

The present disclosure relates to ionic liquid-solvent complex comprising cation and anion and are prepared in the presence of a solvent. The present disclosure also relates to the process for preparing ionic liquid-solvent complex and also to a process for producing linear alkyl benzene using the ionic liquid-solvent complex. The present disclosure also relates to various applications of the ionic liquid-solvent complex.

The present invention relates to a catalytic composition in the form of what is known as a Pickering emulsion, said composition comprising a first non-aqueous liquid phase L1 comprising hydrocarbon compounds, within which droplets of a second liquid phase L2 are stabilized by solid particles, said second liquid phase L2 comprising at least one ionic liquid of formula Q.sup.+A.sup., Q.sup.+ being an organic cation and A.sup. being an anion, and in which a Brnsted acid HB is dissolved.

A method of controlling a hydrocarbon conversion process is described. The method involves introducing a reactant into a reaction zone containing an ionic liquid catalyst. The reaction zone has at least two zones. The mass transfer resistance in the second zone is greater than the mass transfer resistance in the first zone.

Disclosed herein are embodiments of a process which generally includes contacting i) a monomer or mixture of monomers, ii) a haloaluminate ionic liquid, and iii) one or more halide components in a reaction zone, and oligomerizing the monomer or mixture of monomers in the reaction zone to form an oligomer product. The combination of the haloaluminate ionic liquid and halide component can constitute a catalyst system which is used in embodiments of the process to produce the oligomer product.