The present disclosure relates to a method and an apparatus for manufacturing a core-shell catalyst, and more particularly, to a method and an apparatus for manufacturing a core-shell catalyst, in which a particle in the form of a core-shell in which the metal nanoparticle is coated with platinum is manufactured by substituting copper and platinum through a method of manufacturing a metal nanoparticle by emitting a laser beam to a metal ingot, and providing a particular electric potential value, and as a result, it is possible to continuously produce nanoscale uniform core-shell catalysts in large quantities.

In an apparatus producing hydrogen gas by the decomposition reaction of water using photocatalyst, its miniaturization is achieved while suppressing the decrease of production efficiency of hydrogen gas as low as possible or improving the efficiency. The apparatus 1 comprises a container portion 2 receiving water W; a photocatalyst member 3 immersed in the water, having photocatalyst which generates excited electrons and positive holes when irradiated with light, causes a decomposition reaction of the water and generates hydrogen gas; a light source 4 emitting the light irradiated to the photocatalyst member; and a heat exchange device 7 conducting waste heat of the light source to the water in the container portion; wherein the water to be decomposed on the photocatalyst member in the container portion is warmed by the waste heat of the light source by the heat exchange device.

Disclosed is a method of irradiating a composition having water and hydrogen-terminated nanodiamonds with light that generates water-solvated electrons from the nanodiamonds. The method can be used to degrade fluoroalkyl compounds such as perfluorooctane sulfonate.

Compositions are provided that can include nanoscale particles including metal cations such as cerium having an average particle size of less than 10 nm. The nanoscale particles can include cerium and oxygen. Methods for forming nanoparticles are provided. The methods can include exposing a metal cation within a solution to radiation to form metal nanoparticles that can include metal cations. The methods can include exposing a cerium salt solution to radiation to form the nanoparticles. The methods can include exposing solvated metal cations to radiation to precipitate nanoparticles that include metal cations such as Ce. The methods can include exposing the homogeneous solution to radiation to precipitate nanoparticles. The methods can include: providing an aqueous solution comprising metal cations; and increasing the pH of the aqueous solution with radiation to form nanoparticles that include metal cations. Nanoparticle generators are provided. The generators can include: a reactant reservoir comprising a metal cation in solution; a fluid cell in fluid communication with the reactant reservoir; a radiation source operatively aligned with the fluid cell; and a product reservoir in fluid communication with the fluid cell.

The present invention provides a method for producing substoichiometric titanium oxide fine particles, in which the degree of oxidation/reduction of substoichiometric titanium oxide fine particles can be adjusted and which can produce high purity nano-sized substoichiometric titanium oxide fine particles by dispersing substoichiometric titanium oxide (TiOx) fine particles, and especially titanium dioxide (TiO.sub.2), in a liquid substance containing a carbon source, adding water so as to form a slurry, forming the slurry into liquid droplets, supplying the liquid droplets to a hot plasma flame that does not contain oxygen, reacting titanium dioxide with carbon in a substance generated by the hot plasma flame so as to produce substoichiometric titanium oxide, and rapidly cooling the produced substoichiometric titanium oxide so as to produce substoichiometric titanium oxide fine particles.

Supported chromium catalysts with an average valence less than +6 and having a hydrocarbon-containing or halogenated hydrocarbon-containing ligand attached to at least one bonding site on the chromium are disclosed, as well as ethylene-based polymers with terminal alkane, aromatic, or halogenated hydrocarbon chain ends. Another ethylene polymer characterized by at least 2 wt. % of the polymer having a molecular weight greater than 1,000,000 g/mol and at least 1.5 wt. % of the polymer having a molecular weight less than 1000 g/mol is provided, as well as an ethylene homopolymer with at least 3.5 methyl short chain branches and less than 0.6 butyl short chain branches per 1000 total carbon atoms.

A TiO.sub.2-graphene-silver hybrid nanocomposite and a method of preparing the TiO.sub.2-graphene-silver hybrid nanocomposite is disclosed. The TiO.sub.2-graphene-silver hybrid nanocomposite at an average particle size ranging from 12-15 nanometers and having a surface area of 140.5 m.sup.2/g includes titanium oxide, graphene oxide and silver, the silver ranging from about 2 weight % to 10 weight %. The method of preparation includes introducing sol gel to a microwave irradiation to prepare an irradiated sample of TiO.sub.2-graphene oxide sample, wherein the sol gel includes TiO.sub.2 containing gel along with graphene containing sol, followed by adding AgNO.sub.3 solution to the TiO.sub.2-graphene oxide sample for preparing a TiO.sub.2-graphene-silver hybrid suspension. The TiO.sub.2-graphene-silver hybrid suspension undergoes microwave irradiation to prepare dried TiO.sub.2-graphene-silver hybrid composite.

Continuous production equipment for graphene composite material includes a raw material preparation device; a reaction device, a material discharge end of the raw material preparation device being connected to the reaction device; and an extraction device configured to extract and purify crude composite material obtained from the reaction device, a material feed end of the extraction device being connected to the material discharge end of the reaction device, and a material discharge end of the extraction device being configured to convey polyamide monomer extract obtained by extraction to a liquid conveying pipe of the raw material preparation device. The raw material preparation device includes a raw material melting kettle configured to melt polyamide monomer and mix the molten polyamide monomer with graphene, and the raw material melting kettle is provided with a high-shear emulsifying machine and an ultrasonic disperser.

A method of hyperpolarizing diamond particles includes applying a laser to a sample of the diamond particles, irradiating the diamond particles with a sweeping microwave to cause diamond polarization, shuttling the diamond particles through a magnetic field to detect .sup.13C nuclei in the diamond particles, and relaying the diamond polarization to nuclear spins to one of a surrounding solid or fluid.

Supported chromium catalysts with an average valence less than +6 and having a hydrocarbon-containing or halogenated hydrocarbon-containing ligand attached to at least one bonding site on the chromium are disclosed, as well as ethylene-based polymers with terminal alkane, aromatic, or halogenated hydrocarbon chain ends. Another ethylene polymer characterized by at least 2 wt. % of the polymer having a molecular weight greater than 1,000,000 g/mol and at least 1.5 wt. % of the polymer having a molecular weight less than 1000 g/mol is provided, as well as an ethylene homopolymer with at least 3.5 methyl short chain branches and less than 0.6 butyl short chain branches per 1000 total carbon atoms.