The present invention relates to a 3D-printed cobalt-based alloy product comprising carbon, tungsten and chromium with very good mechanical and thermal properties as well as a method of preparing the 3D-printed product and a powder alloy. The alloy has a high carbon content leading to high carbide content but small and evenly distributed carbides. A method facilitating 3D printing of high carbide content alloys such as the present alloy is also disclosed.

A production method of particulate materials, through centrifugal atomization (CA) is disclosed. The method is suitable for obtaining fine spherical powders with exceptional morphological quality and extremely low content, or even absence of non-spherical-shape particles and internal voids. A appropriate cost effective method for industrial scale production of metal, alloy, intermetallic, metal matrix composite or metal like material powders in large batches is also disclosed. The atomization technique can be extended to other than the centrifugal atomization with rotating element techniques.

A pre-alloyed powder having a composition consisting of, in weight % (wt. %): C, 0.02-0.04; Si, 0.1-0.4; Mn, 0.1-0.5; Cr, 11-13; Ni, 7-10; Cr+Ni, 19-23; Mo, 1-25; Al, 1.4-2.0; N, 0.01-0.75. Optionally, the pre-alloyed powder contains: Cu, 0.05-2.5; B, 0.002-2.0; S, 0.01-0.25; Nb, 0.01 max; Ti, 2 max; Zr, 2, max; Ta, 2 max; Hf, 2 max; Y, 2 max; Ca, 0.0003-0.009; Mg, 0.01 max; O, 0.003-0.80; and REM, 0.2 max. Fe and impurities comprise the balance.

A metal powder producing apparatus includes a molten metal supply unit, a cylinder body, and a cooling liquid introduction unit. The molten metal supply unit discharges a molten metal. The cylinder body is capable of being formed with a layer of a cooling liquid for cooling the molten metal on an inner circumference surface of the cylinder body. The cooling liquid introduction unit supplies the cooling liquid to an upper inside of the cylinder body. The inner circumference surface of the upper inside of the cylinder body has a substantially elliptical shape.

A metal powder for additive manufacturing having a composition including the following elements, expressed in content by weight: 0.01%≤C≤0.2%, 2.5%≤Ti≤10%, (0.45×Ti)−1.35%≤B≤(0.45×Ti)+0.70%, S≤0.03%, P≤0.04%, N≤0.05%, O≤0.05% and optionally containing: Si≤1.5%, Mn≤3%, Al≤1.5%, Ni≤1%, Mo≤1%, Cr≤3%, Cu≤1%, Nb≤0.1%, V≤0.5% and including eutectic precipitates of TiB.sub.2 and optionally of Fe.sub.2B, the balance being Fe and unavoidable impurities resulting from the elaboration, the metal powder having a mean roundness of at least 0.70. The invention also relates to its manufacturing method by argon atomization.

A continuous process for producing a material of a battery cell using a system having a mist generator, a drying chamber, one or more gas-solid separators and a reactor is provided. A mist generated from a liquid mixture of two or more metal precursor compounds in desired ratio is dried inside the drying chamber. Heated air or gas is served as the gas source for forming various gas-solid mixtures and as the energy source for reactions inside the drying chamber and the reactor. One or more gas-solid separators are used in the system to separate gas-solid mixtures from the drying chamber into solid particles mixed with the metal precursor compounds and continuously deliver the solid particles into the reactor for further reaction to obtain final solid material particles with desired crystal structure, particle size, and morphology.

A method for preparing an oxygen-free passivated titanium or titanium-alloy powder product by means of gas-solid fluidization is provided. The new method includes placing the metal halide and the titanium powder which meet formula requirements into a gasifier and a fluidized bed reactor respectively; heating the gasifier to gasify the metal halide, and introducing dry argon and halide gas into the fluidized bed reactor; opening the fluidized bed, heating the fluidized bed, fluidizing the titanium powder after the introduction of the argon and the metal halide gas, and cooling the product to obtain the titanium powder subjected to oxygen-free passivation using metal chloride; molding the oxygen-free passivated titanium powder into a green body with powder metallurgy technology; and sintering the green body in vacuum or argon atmosphere according to the molding technology, and after temperature rise treatment, performing a densification sintering operation to obtain a high-performance titanium product component.

A method for preparing an oxygen-free passivated titanium or titanium-alloy powder product by means of gas-solid fluidization is provided. The new method includes placing the metal halide and the titanium powder which meet formula requirements into a gasifier and a fluidized bed reactor respectively; heating the gasifier to gasify the metal halide, and introducing dry argon and halide gas into the fluidized bed reactor; opening the fluidized bed, heating the fluidized bed, fluidizing the titanium powder after the introduction of the argon and the metal halide gas, and cooling the product to obtain the titanium powder subjected to oxygen-free passivation using metal chloride; molding the oxygen-free passivated titanium powder into a green body with powder metallurgy technology; and sintering the green body in vacuum or argon atmosphere according to the molding technology, and after temperature rise treatment, performing a densification sintering operation to obtain a high-performance titanium product component.

An alloy powder having an alloy composition represented by Fe.sub.100-a-b-c-d-e-fCu.sub.aSi.sub.bB.sub.cCr.sub.dSn.sub.eC.sub.f, wherein a, b, c, d, e and f are atomic % meeting 0.80≤a≤1.80, 2.00≤b≤10.00, 11.00≤c≤17.00, 0.10≤d≤2.00, 0.01≤e≤1.50, and 0.10≤f≤0.40.

Provided is a Cu-based alloy powder that is suitable for a process involving rapid melting and rapid solidification and that can provide a shaped object superior in characteristics. The powder is composed of a Cu-based alloy, which contains an element M being one or more elements selected from Cr, Fe, Ni, Zr, and Nb: 0.1% by mass or more and 10.0% by mass or less, Si: more than 0% by mass and 0.20% by mass or less, P: more than 0% by mass and 0.10% by mass or less, and S: more than 0% by mass and 0.10% by mass or less, the balance being Cu and inevitable impurities. This powder has a ratio (D50/TD) of the average particle diameter D50 (μm) thereof to the tap density TD (Mg/m.sup.3) is 0.2×10.sup.−5.Math.m.sup.4/Mg or more and 20×10.sup.−5.Math.m.sup.4/Mg or less, and has a sphericity of 0.80 or more and 0.95 or less.