Three-dimensional polymeric article (100) having first (101) and second (102) opposed major surfaces, a base body (103) having a first dimension, a second dimension perpendicular to the first dimension, and a thickness, wherein the thickness is orthogonal to the first and second dimensions, wherein the base body (103) comprises a plurality of alternating, adjacent first (107) and second (108) polymeric regions along the first dimension, wherein the second dimensions of the first (107) and second (108) regions extend at least partially across the second dimensions, wherein the first regions (107) have a first crosslink density, wherein the second regions (108) have a second crosslink density, wherein the second crosslink density of the second regions (108) are less than the first crosslink density of the first regions (107), wherein the first and second regions extend perpendicularly in two directions from a central plane (115) in the base body (103) parallel to the first and second dimensions of the polymeric article (100), and wherein the second regions (108) extend in each of said two directions further than does the first regions (107). Embodiments of the three-dimensional polymeric article described herein are useful for providing a dual sided, textured wrapping film such that greater grip is realized both on an item wrapped by the film and the wrapped item itself.

The invention provides a process for producing a modified molded article capable of providing a diaphragm that is less likely to generate particles. The process for producing a modified molded article includes: molding modified polytetrafluoroethylene containing a tetrafluoroethylene unit and a modifying monomer unit based on a modifying monomer copolymerizable with tetrafluoroethylene to provide a molded article; and irradiating the molded article with not lower than 30 kGy but lower than 70 kGy of radiation at 270 C. to 310 C. to provide a modified molded article.

A system for additively manufacturing a composite part comprises a delivery guide, movable relative to a surface. The delivery guide is configured to deposit at least a segment of a continuous flexible line along a print path. The continuous flexible line comprises a non-resin component and a thermosetting-resin component. The thermosetting-resin component comprises a first part and a second part. The non-resin component comprises a first element and a second element. The system further comprises a first resin-part applicator, configured to apply the first part to the first element, and a second resin-part applicator, configured to apply the second part to the second element. The system also comprises a feed mechanism, configured to pull the first element through the first resin-part applicator, to pull the second element through the second resin-part applicator, and to push the continuous flexible line out of the delivery guide.

Method of making a golf ball comprising: providing a subassembly and a thermoset polymer composition; partially curing the thermoset polymer composition and elongating same while in a partial cure state; forming a layer about the subassembly comprising the thermoset polymer composition; and further curing the thermoset polymer composition. A moldable thermoset polymer composition may be elongated while in state of partial cure. The thermoset polymer composition may be stepwise elongated by: stretching a thermoset polymer composition in at least one plane while in partial cure state and before forming into first and second half shells; forming the thermoset polymer composition into first and second half shells and elongating the thermoset polymer composition in three dimensions while in the partial cure state and before mating the first and second half shells about the subassembly; and mating the first and second half shells about the subassembly and forming a stepwise-elongated thermoset layer.

A method of additively manufacturing a composite part comprises depositing a segment of a continuous flexible line along a print path. The continuous flexible line comprises a non-resin component and further comprises a photopolymer-resin component that is uncured. The method further comprises delivering a predetermined or actively determined amount of curing energy at least to a portion of the segment of the continuous flexible line at a controlled rate while advancing the continuous flexible line toward the print path and after the segment of the continuous flexible line is deposited along the print path to at least partially cure at least the portion of the segment of the continuous flexible line.

Additive manufacturing fiber composites comprise a bundle of elongate fibers and a matrix material that holds or encompasses the elongate fibers of the additive manufacturing fiber tow. The matrix material includes an energy-emissive dopant that emits a curing energy in response to receiving an activating energy. The curing energy effects curing of the solidifiable matrix material so that it solidifies to a rigid or semi-rigid matrix material. Methods of additively manufacturing an article include dispensing an additive manufacturing fiber tow, a solidifiable matrix material, and an energy-emissive dopant to form a solidifiable composite, and applying the activating energy to the energy-emissive dopant to activate the energy-emissive dopant to emit the curing energy. Systems to additively manufacturing an article may be configured to employ such additive manufacturing fiber composites and/or methods.

A hydrophilic laminate, including: a substrate made of a resin; and a hydrophilic resin layer on the substrate made of a resin, wherein the hydrophilic resin layer comprises micro convex portions or micro concave portions in a surface thereof, and wherein a pure water contact angle of the surface of the hydrophilic resin layer is less than 40.

A method of additively manufacturing a composite part comprises applying a liquid photopolymer resin to a non-resin component to create a continuous flexible line by pulling the non-resin component through a vessel, containing a volume of the liquid photopolymer resin. The continuous flexible line comprises the non-resin component and a photopolymer-resin component that comprises at least some of the liquid photopolymer resin applied to the non-resin component. The method further comprises routing the continuous flexible line into a delivery guide, pushing the continuous flexible line out of the delivery guide, depositing, via the delivery guide, a segment of the continuous flexible line along a print path, and delivering curing energy at least to a portion of the segment of the continuous flexible line.

A method of additively manufacturing a composite part is disclosed. The method comprises pushing a continuous flexible line through a delivery guide. The continuous flexible line comprises a non-resin component and a thermosetting-epoxy-resin component that is partially cured. The method also comprises depositing, via the delivery guide, a segment of the continuous flexible line along a print path. The method further comprises maintaining the thermosetting-epoxy-resin component of at least the continuous flexible line being pushed through the delivery guide below a threshold temperature prior to depositing the segment of the continuous flexible line along the print path.

A method of additively manufacturing a composite part is disclosed. The method comprises depositing a segment of a continuous flexible line along a print path. The continuous flexible line comprises a non-resin component and a thermosetting resin component that is not fully cured. The method further comprises, while advancing the continuous flexible line toward the print path, delivering a predetermined or actively determined amount of curing energy at least to a portion of the segment of the continuous flexible line at a controlled rate after the segment of the continuous flexible line is deposited along the print path to at least partially cure at least the portion of the segment of the continuous flexible line.