A treated water drying device 20 for vaporizing treated water by heat of a combustion gas, the device 20 including a housing 21, a combustion gas supply port 26 for supplying the combustion gas to the housing 21, a water supply portion 27 for vaporizing the treated water by bringing the treated water into contact with the combustion gas supplied to the housing 21, and an exhaust port 28 for discharging a water-containing gas including the vaporized treated water to an outside of the housing 21. The exhaust port 28 is disposed at a lowermost part of the housing 21 and opens in a direction crossing a vertical direction. The housing 21 has a bottom 22 including an inclined portion 23 formed toward the exhaust port 28.

An integrated mercaptan extraction and/or sweetening and thermal oxidation and flue gas treatment process for a wide variety of sulfur, naphthenic, phenolic/cresylic contaminated waste streams is described. It provides comprehensive treatment for the safe disposal of sulfidic, naphthenic, phenolic/cresylic spent caustic streams, disulfide streams, spent air streams, spent mixed amine and caustic streams (also known as COS solvent streams) from sulfur treating processes. It allows the use of regenerated spent caustic in the sulfur oxide removal section of the thermal oxidation system reducing the need for fresh NaOH. It may also contain an integrated make-up water system. The integration allows the use of the liquefied petroleum gas or other hydrocarbon feeds to the respective extraction or sweetening process to offset external fuel gas requirements for the thermal oxidation system and for the push/pull system of the spent caustic surge drum and optional hydrocarbon surge drum.

A water treatment tank includes: a tank body including a bottom surface extending in a horizontal direction; an overflow wall partitioning the inside of the tank body into an upstream tank into which treatment water having absorbed sulfur from an exhaust gas is introduced and a downstream tank into which the treatment water overflowing from the upstream tank is introduced to flow therein; and an inclined part that is provided between the bottom surface of the tank body and the overflow wall in the downstream tank and is inclined downward as it goes from the overflow wall toward a downstream side inside the downstream tank to be connected to the bottom surface of the tank body.

This invention provides a continuous liquid phase type wet exhaust gas treatment method for removing sulfur oxides from exhaust gas and collecting it as gypsum, which method is simple and humidifying liquid is uniformly sprayed into exhaust gas with it. The method is characterized in that humidifying liquid is injected downwardly in a region where exhaust gas flows vertically downwardly.

A desulfurization gas process includes water vapor, CO.sub.2 and SO.sub.x (x=2 and/or 3). In a treatment unit, the gas contacts a cooled alkaline aqueous solution having a temperature lower than an initial gas temperature, water and a carbonate of an alkali metal, to cool the gas, condense some water vapor and absorb SO.sub.x in the carbonate-containing solution, produce an SO.sub.x-depleted gas and an acidic aqueous solution including sulfate and/or sulfite ions. The SO.sub.x-depleted gas and a portion of the acidic aqueous solution can then be withdrawn from the treatment unit. Carbonate of the alkali metal can be added to remaining acidic aqueous solution to obtain a made-up alkaline aqueous solution. This solution can be cooled and reused as the cooled alkaline aqueous solution. An SO.sub.x absorbent solution includes a bleed stream from a CO.sub.2-capture process, sodium or potassium carbonate, and an acidic aqueous solution obtained from desulfurization.

A method of reducing selenium contamination in a waste water stream is described herein. The method includes channeling a flue gas stream through an absorber, contacting the flue gas stream with an aqueous alkaline-based slurry, such that any selenium byproduct in the flue gas stream forms a selenium compound within the aqueous alkaline-based slurry, controlling oxidation of the selenium compound in the aqueous alkaline-based slurry, and adding a precipitation agent to the aqueous alkaline-based slurry to cause the selenium compound within the aqueous alkaline-based slurry to precipitate.

The disclosure provides seven integrated methods for the chemical sequestration of carbon dioxide (CO.sub.2), nitric oxide (NO), nitrogen dioxide (NO.sub.2) (collectively NO.sub.x, where x=1, 2) and sulfur dioxide (SO.sub.2) using closed loop technology. The methods recycle process reagents and mass balance consumable reagents that can be made using electrochemical separation of sodium chloride (NaCl) or potassium chloride (KCl). The technology applies to marine and terrestrial exhaust gas sources for CO.sub.2, NOx and SO.sub.2. The integrated technology combines compatible and green processes that capture and/or convert CO.sub.2, NOx and SO.sub.2 into compounds that enhance the environment, many with commercial value.

The invention is a device and method for purifying sulfur dioxide and nitrogen oxide in flue gas with an electrolysis-chemical advanced oxidation enhanced ammonia method. The device includes a thermal activation reactor, ammonium hydroxide storage tank, absorption tower, electrolytic bath and crystallization separator. The method takes raw material part of an ammonium sulfate solution that is a reaction product of ammonia and sulfur oxide in flue gas, and an ammonium persulfate solution prepared by electrolysis of an electrolytic bath as an oxidant to enhance the efficiency of purifying sulfur dioxide and nitrogen oxide in the flue gas with an ammonia method. A thermal activation reactor activates an ammonium persulfate containing solution to generate a strong oxidizing SO4..sup., so that NO.sub.x and SO.sub.2 in the flue gas may be more efficiently converted into a product having higher solubleness for enhanced removal of sulfur dioxide and nitrogen oxide in the flue gas.

An integrated mercaptan extraction and/or sweetening and thermal oxidation and flue gas treatment process for a wide variety of sulfur, naphthenic, phenolic/cresylic contaminated waste streams is described. It provides comprehensive treatment for the safe disposal of sulfidic, naphthenic, phenolic/cresylic spent caustic streams, disulfide streams, spent air streams, spent mixed amine and caustic streams (also known as COS solvent streams) from sulfur treating processes. It allows the use of regenerated spent caustic in the sulfur oxide removal section of the thermal oxidation system reducing the need for fresh NaOH. It may also contain an integrated make-up water system. The integration allows the use of the liquefied petroleum gas or other hydrocarbon feeds to the respective extraction or sweetening process to offset external fuel gas requirements for the thermal oxidation system and for the push/pull system of the spent caustic surge drum and optional hydrocarbon surge drum.

A flue gas denitration system includes a catalytic reactor accommodating a plurality of catalytic modules, into which a flue gas flows, and a flue gas heater provided on an upstream side of the catalytic reactor in a flow direction of the flue gas. In the flue gas denitration system, switched are a first denitration state in which the flue gas is denitrated by using the plurality of catalytic modules in the catalytic reactor and a second denitration state in which the flue gas is denitrated by using a catalytic module(s) less than those used in the first denitration state while a temperature of the flue gas flowing into the catalytic reactor is made higher than that in the first denitration state by using the flue gas heater. Thus, by making the temperature of the flue gas flowing into the catalytic reactor higher, it is possible to suppress deterioration in denitration performance in the case of using part of the plurality of catalytic modules for denitration.