Methods, apparatus, and compositions for cleaning gas. The use of segmented multistage ammonia-based liquid spray with different oxidation potentials to remove sulfur compounds from gas. The use of different oxidation potentials may reduce unwanted ammonia slip.

A method for the purification of a raw gas stream by selective catalytic oxidation, in which organic and inorganic sulfur compounds, halogenated and non-halogenated volatile organic compounds are selectively oxidized without substantially oxidizing the lower hydrocarbons and the sulfur containing compounds present in the gas to sulfur trioxide and excess of oxygen is removed by oxidation of lower alcohols, ethers or hydrogen added to the raw gas stream upstream the catalytic oxidation.

Oxygen is removed from a gas feed such as a landfill gas, a digester gas or an industrial CO.sub.2 off-gas by heating the feed gas, optionally removing siloxanes and silanols from the heated feed gas, optionally removing part of the sulfur-containing compounds in the heated feed gas, injecting one or more reactants for oxygen conversion into the heated feed gas, carrying out a selective catalytic conversion of any or all of the volatile organic compounds (VOCs) present in the gas, including sulfur-containing compounds, chlorine-containing compounds and any of the reactants injected, in at least one suitable reactor, and cleaning the resulting oxygen-depleted gas. The reactants to be injected comprise one or more of H.sub.2, CO, ammonia, urea, methanol, ethanol and dimethyl ether (DME).

A zero discharge process for separating sludge and salt from desulfurization wastewater includes a pretreatment process, a membrane treatment process and an evaporative crystallization process; in the pretreatment process, the desulfurization wastewater enters a raw water tank, an aeration fan introduces compressed air into the raw water tank, and the wastewater is lifted to first-stage reaction and clarification by a raw water pump; in the membrane treatment process, the incoming wastewater is first filtered by ultrafiltration, then enters a pH adjustment tank, and is pumped into a nanofiltration membrane separation system and a reverse osmosis membrane separation system; in the evaporative crystallization process, the incoming wastewater is first subjected to two-stage preheating, then enters a degasser, and finally enters an evaporative concentration system and a crystallization system.

Finely atomized alkaline sorbent salt solutions are injected into a hot flue gas stream to remove SO.sub.2. Flash evaporation of the droplets produces very fine dried sorbent particles, which react efficiently with SO.sub.2 in the flue gas. The liquid sorbent may be sodium carbonate, sodium hydroxide, sodium sulfite, potassium carbonate, potassium hydroxide or the like. In a coal-fired boiler, the liquid sorbent may be injected after the economizer section, where the flue gas temperature is below 850 F., and upstream of a particulate collection device. The dried sorbent particles react with SO.sub.2 and then are removed from the flue gas stream in the particulate collection device, producing a cleaned flue gas stream.

The present invention relates generally to the field of emission control equipment for boilers, heaters, kilns, or other flue gas-, or combustion gas-, generating devices (e.g., those located at power plants, processing plants, etc.) and, in particular to a new and useful method and apparatus for reducing and/or eliminating various liquid discharges from one or more emission control equipment devices (e.g., one or more wet flue gas desulfurization (WFGD) units). In another embodiment, the method and apparatus of the present invention is designed to reduce and/or eliminate the amount of liquid waste that is discharged from a WFGD unit by subjecting the WFGD liquid waste to one or more drying processes, one or more spray dryer (or spray dry) absorber processes, and/or one or more spray dryer (or spray dry) evaporation processes.

The present invention relates to a process for concurrently removing CO.sub.2 and SO.sub.2 from flue gas produced by a combustion process, comprising: (a) performing a combustion process by combusting a fuel and air in a combustion apparatus, thereby creating an exhaust stream comprising CO.sub.2 and SO.sub.2; (b) compressing the exhaust stream in a first compression step, thereby producing a first compressed gas stream; (c) providing a first membrane having a feed side and a permeate side, and being selectively permeable to CO.sub.2 and SO.sub.2 over nitrogen and to CO.sub.2 and SO.sub.2 over oxygen; (d) passing at least a portion of the first compressed gas stream across the feed side; (e) withdrawing from the feed side a CO.sub.2- and SO.sub.2-depleted residue stream; (f) withdrawing from the permeate side at a lower pressure than the first compressed gas stream, a first permeate stream enriched in CO.sub.2 and SO.sub.2; (g) passing the first permeate stream to a separation process that produces a stream enriched in CO.sub.2 and a stream enriched in SO.sub.2.

The invention pertains to methods of reducing dissolved elements such as arsenic, selenium and mercury in aqueous solutions using, for example, various barium compounds to partition said elements to a solid phase. Such methods are particularly useful for reducing such elements at various points in coal and oil-fired power plants prior to final waste water treatment.

A carbon dioxide recovery system includes: a first heat exchanger that is disposed between a boiler and a desulfurization device, cools exhaust gas g flowing from the boiler to the desulfurization device, and heats a first heat medium w1; and a carbon dioxide recovery device that, when supplied with heat of the first heat medium w1, separates and recovers carbon dioxide from an absorber having absorbed the carbon dioxide.

The invention is a device and method for purifying sulfur dioxide and nitrogen oxide in flue gas with an electrolysis-chemical advanced oxidation enhanced ammonia method. The device includes a thermal activation reactor, ammonium hydroxide storage tank, absorption tower, electrolytic bath and crystallization separator. The method takes raw material part of an ammonium sulfate solution that is a reaction product of ammonia and sulfur oxide in flue gas, and an ammonium persulfate solution prepared by electrolysis of an electrolytic bath as an oxidant to enhance the efficiency of purifying sulfur dioxide and nitrogen oxide in the flue gas with an ammonia method. A thermal activation reactor activates an ammonium persulfate containing solution to generate a strong oxidizing SO4.sup., so that NO.sub.x and SO.sub.2 in the flue gas may be more efficiently converted into a product having higher solubleness for enhanced removal of sulfur dioxide and nitrogen oxide in the flue gas.