The present invention is related to a process for manufacturing a sorbent suitable for a use in a circulating dry scrubber device comprising the steps of: providing quicklime and water in an hydrator; slaking said quicklime via a non-wet route in the hydrator; collecting a lime based sorbent at an exit of the hydrator. The process is characterized in that it comprises a further step of adding at least a first additive comprising: a compound comprising silicon, and/or, a compound comprising aluminum, and/or a compound comprising silicon and aluminum before or during said slaking step, at a molar ratio between silicon or aluminum or a combination thereof and the calcium provided to said hydrator equal to or below 0.2 and equal to or above 0.02. In some other aspects, the present invention is related to a sorbent, a premix, and a flue gas treatment process.

Herein are disclosed compositions of matter, processes of manufacture and processes of use of solid state admixtures that include an inorganic base and a sulfide selected from the group consisting of an ammonium sulfide, an alkali metal sulfide, an alkali-earth metal sulfide, transition metal sulfide, and a mixture thereof. The composition can include solid state inorganic bases (e.g., calcium hydroxide and sodium sesquicarbonate) and/or gaseous bases (e.g., ammonia) and, optionally, a support material for one or more of the inorganic base and sulfide. The compositions are useful for capturing environmental contaminants, for example, from the flue gas of a coal fired power plant.

A sorbent product, including from about 1 wt % to about 99 wt %, based on the total weight of the sorbent product, of at least one base sorbent material; and from about 1 wt % to about 99 wt %, based on the total weight of the sorbent product, of at least one binder. The sorbent product may further include at least from about 0 wt % to about 99% wt %, based on the total weight of the sorbent product, of at least one additional additive. Methods for making same and methods and systems for controlling multiple pollutants are also included.

In one embodiment, a method for separating acidic gases from a gas mixture includes exposing the gas mixture to a separation membrane at an elevated temperature, where the separation membrane includes a porous support and at least one molten alkali metal hydroxide disposed within pores of the porous support.

In one embodiment, a separation membrane includes: a porous support structure, wherein the porous support structure comprises a system of continuous pores connecting an inlet of the separation membrane to an outlet of the separation membrane; and at least one alkali metal hydroxide disposed within pores of the porous support structure. Other aspects and embodiments of the disclosed inventive concepts will become apparent from the detailed description, which, when taken in conjunction with the drawings, illustrate by way of example the principles of the invention.

An agent for removing a halogen gas, such as chlorine, in a waste gas by means of reduction; a method for producing this agent; a method for removing a halogen gas by use of this agent; and a system for removing a halogen gas. The agent for removing the halogen gas contains at least pseudo-boehmite, that serves as a host material, and a sulfur-containing reducing agent, that serves as a guest material. 1-8% by weight of the reducing agent, in terms of elemental sulfur, based on the total amount of the pseudo-boehmite and sulfur-containing reducing agent is present in the agent. At least one inorganic compound selected from among oxides, carbonates salts and hydrocarbon salts of alkaline earth metal elements, transition metal elements and zinc group elements is additionally contained in the agent as a third component.

The novel sorbents for capturing acid and greenhouse gases converts red mud into a sorbent material that can be used to remove acid and greenhouse gases, utilizing a series of chemical reactions. The first set of reactions entail sorption of the acid/greenhouse gases and subsequent neutralization by the alkali content of the red mud. The salts generated by the neutralization reactions decompose to release the acid gases which are immediately converted to environmentally benign elemental products (N2, O2, S) by thermo-catalytic reactions. In a different set of reactions, the alkaline earth oxides (CaO and MgO) present in the sorbent capture the acid/greenhouse gases and convert them to nitrate, nitrite, carbonate and sulfite salts. The salts (beside carbonate) decompose to yield the acid gases which are converted to elemental products by thermo-catalytic reactions. The loaded sorbents are thermally regenerated to the oxide forms for re-capturing the gases.

Finely atomized alkaline sorbent salt solutions are injected into a hot flue gas stream to remove SO.sub.2. Flash evaporation of the droplets produces very fine dried sorbent particles, which react efficiently with SO.sub.2 in the flue gas. The liquid sorbent may be sodium carbonate, sodium hydroxide, sodium sulfite, potassium carbonate, potassium hydroxide or the like. In a coal-fired boiler, the liquid sorbent may be injected after the economizer section, where the flue gas temperature is below 850 F., and upstream of a particulate collection device. The dried sorbent particles react with SO.sub.2 and then are removed from the flue gas stream in the particulate collection device, producing a cleaned flue gas stream.

A powdery calcium-magnesium compound used as a sorbent composition in flue gas treatment, compatible with electrostatic precipitators. The calcium magnesium compound is doped with calcium nitrate or nitric acid to reduce the electrical resistivity of the particles, increasing their collection efficiency.

A mobile emissions control system having an emission capturing system and emission control system is provided for diesel engines operated on ocean-going ships at-berth. The emissions control system may be mounted on a towable chassis or mounted on a barge, allowing it to be placed alongside ocean-going ships at-berth. A crane or boom transfers a duct of the emissions capturing system extending from the emissions control system to the ship to capture exhaust from its engine. Alternatively, the system may be mounted on an automated guided vehicle (AGV) equipped with a tower and a crane. The crane mounted on the AGV then lifts the duct forming part of the emissions capture system to the ship's exhaust system to capture exhaust from the ship's diesel engine and transfers it to the emissions control system, which cleans the exhaust and then passes clean air into the atmosphere through an exhaust outlet.