Patent classifications
B01D53/523
Method for production of elemental sulfur by part or fully catalytic oxidation of Claus tail gas
A process and a process plant for production of elemental sulfur from a feedstock gas including from 15 vol % to 100 vol % H2S and a stream of sulfuric acid, the process including a) providing a Claus reaction furnace feed stream with a substoichiometric amount of oxygen, b) directing s to a reaction furnace operating at elevated temperature, c) cooling, d) directing to contact a material catalytically active in the Claus reaction, e) withdrawing a Claus tail gas and elemental sulfur, f) directing to a means for sulfur oxidation, g) directing to contact a material catalytically active in SO2 oxidation to SO3, h) converting to concentrated sulfuric acid, i) recycling to the Claus reaction furnace, wherein an amount of combustibles, in the Claus tail gas, is oxidized in the presence of a material catalytically active in sulfur oxidation, at an inlet temperature below 400° C.
Methods for Absorbing a Targeted Compound from a Gas Stream for Subsequent Processing or Use
The present invention describes methods for absorbing a targeted chemical compound from a gas stream into a scrubbing solution for various uses and with various benefits. Methods are described to produce a gas stream that can be further processed with operational benefits, such as through condensing and wastewater treatment with a lower load on the wastewater treatment system. Methods are described for adsorbing the targeted compound with reduced condensation of water from the gas stream. Methods are described for producing a liquid stream comprising an absorbed form of the targeted compound for use as a saleable product, such as adsorbing ammonia for the production of a fertilizer, wherein the concentration of the absorbed form may be increased through reduced condensation from the gas stream. Methods are described for producing a lower volume liquid waste stream from the absorption process through the use of reduced condensation of the gas stream.
METHOD FOR PRODUCTION OF ELEMENTAL SULFUR AND SULFURIC ACID
A process for production of elemental sulfur from a feedstock gas including from 15% to 100 vol % H2S and a stream of sulfuric acid, the process including: a) providing a Claus reaction furnace feed stream substoichiometric oxygen with respect to the Claus reaction, b) directing to a reaction furnace zone operating at elevated temperature such as above 900° C., c) directing to a sulfuric acid evaporation zone downstream said reaction furnace zone, d) cooling to provide a cooled Claus converter feed gas, e) directing to contact a material catalytically active in the Claus reaction, f) withdrawing a Claus tail gas and elemental sulfur, g) directing to a Claus tail gas treatment plant, with the associated benefit of a process involving injection of sulfuric acid in a sulfuric acid evaporation zone allowing high temperature combustion of said feedstock gas, including impurities, without cooling from evaporation and decomposition of sulfuric acid.
METHOD FOR PRODUCTION OF ELEMENTAL SULFUR BY PART OR FULLY CATALYTIC OXIDATION OF CLAUS TAIL GAS
A process and a process plant for production of elemental sulfur from a feedstock gas including from 15 vol % to 100 vol % H2S and a stream of sulfuric acid, the process including a) providing a Claus reaction furnace feed stream with a substoichiometric amount of oxygen, b) directing s to a reaction furnace operating at elevated temperature, c) cooling, d) directing to contact a material catalytically active in the Claus reaction, e) withdrawing a Claus tail gas and elemental sulfur, f) directing to a means for sulfur oxidation, g) directing to contact a material catalytically active in SO2 oxidation to SO3, h) converting to concentrated sulfuric acid, i) recycling to the Claus reaction furnace, wherein an amount of combustibles, in the Claus tail gas, is oxidized in the presence of a material catalytically active in sulfur oxidation, at an inlet temperature below 400° C.
Methods for absorbing a targeted compound from a gas stream for subsequent processing or use
The present invention describes methods for absorbing a targeted chemical compound from a gas stream into a scrubbing solution for various uses and with various benefits. Methods are described to produce a gas stream that can be further processed with operational benefits, such as through condensing and wastewater treatment with a lower load on the wastewater treatment system. Methods are described for adsorbing the targeted compound with reduced condensation of water from the gas stream. Methods are described for producing a liquid stream comprising an absorbed form of the targeted compound for use as a saleable product, such as adsorbing ammonia for the production of a fertilizer, wherein the concentration of the absorbed form may be increased through reduced condensation from the gas stream. Methods are described for producing a lower volume liquid waste stream from the absorption process through the use of reduced condensation of the gas stream.
TREATMENT OF ACID GASES USING MOLTEN ALKALI METAL BORATES, AND ASSOCIATED METHODS OF SEPARATION
The removal of acid gases (e.g., non-carbon dioxide acid gases) using sorbents that include salts in molten form, and related systems and methods, are generally described.
REVAMPING OF A CLAUS PLANT WITH A SULFURIC ACID PLAN
A revamp process for modifying a sulfur abatement plant including a Claus process plant, the Claus process plant including a Claus reaction furnace and one or more Claus conversion stages, each Claus conversion stage including a conversion reactor and a means for elemental sulfur condensation, and a means of Claus tail gas oxidation configured for receiving a Claus tail gas from said Claus process plant and configured for providing an oxidized Claus tail gas, the process revamp including: a) providing a sulfuric acid producing tail gas treatment plant producing sulfuric acid, and b) providing a means for transferring an amount or all of the sulfuric acid produced in said sulfuric acid producing tail gas treatment plant to said Claus reaction furnace, wherein the moles of sulfur in the transferred sulfuric acid relative to the moles of elemental sulfur withdrawn from the Claus process plant is from 3% to 25%.
Treatment of acid gases using molten alkali metal borates and associated methods of separation
The removal of acid gases (e.g., non-carbon dioxide acid gases) using sorbents that include salts in molten form, and related systems and methods, are generally described.
Purification of gases containing sulfur compounds
A system includes a purification unit configured to process a vapor stream including sulfur dioxide. The purification unit includes an inlet configured to allow the vapor stream to enter the purification unit. The purification unit includes a steam coil configured to circulate steam and provide a source of heat. The purification unit includes a packed bed. The purification unit includes a tray configured to accumulate sulfur. The purification unit includes an absorber section configured to remove at least a portion of the sulfur dioxide from the vapor stream. The purification unit includes an outlet configured to allow an effluent with a lower sulfur dioxide content than the vapor stream to exit the purification unit. The system includes a sulfur tank including a vent line in fluid communication with the inlet. The vent line is configured to allow vapor to flow from the sulfur tank to the purification unit.
PELLETS OF SORBENT SUITABLE FOR CARBON DIOXIDE CAPTURE
The present invention relates to methods for the preparation of pellets of sorbent suitable for carbon dioxide capture, to said pellets of sorbent, and to the use of said pellets of sorbent in carbon dioxide capture.