The present invention disclosed a method for underground separation of components in sulfur-containing flue gas and sequestration of carbon dioxide and sulfides, comprising: injecting sulfur-containing flue gas into injection well which is arranged in a well pattern of a sequestrated aquifer in advance; transiting and injecting formation water into the formation at a first preset injection speed by injection well of the well pattern after injecting the sulfur-containing flue gas for a first preset time, maintaining the first formation pressure, and conducting water drainage and gas production by a production well of the well pattern in a mode of a fixed bottom hole flowing pressure; and determining the well shut-in time according to the nitrogen molar concentration of the production well and conducting well shut-in. The separated N.sub.2 is produced, while the separated CO.sub.2 and sulfides are sequestered in aquifer, achieving effective underground separation of the flue gas components.

A sour gas stream is sub-stoichiometrically combusted to produce soot and a sour syngas stream. At least 10% of the carbon in the sour gas stream is converted into the soot. At least a portion of the hydrogen sulfide of the sour syngas stream is reacted with sulfur dioxide to produce a syngas stream comprising the carbon dioxide, the carbon monoxide, the hydrogen, water, elemental sulfur vapor, a residual portion of the hydrogen sulfide, and a residual portion of the sulfur dioxide. The syngas stream is reacted with steam to produce a shifted sour gas stream including more carbon dioxide, more hydrogen, more hydrogen sulfide, and less carbon monoxide in comparison to the syngas stream. Water and hydrogen sulfide is separated from the shifted sour gas stream to produce a sweet gas stream. The sweet gas stream is separated into a hydrogen product stream and an exhaust stream.

A process to produce a sulfur-free hydrocarbon product stream from a liquid hydrocarbon disulfide product, e.g., of the Merox Process, includes subjecting the hydrocarbon disulfide to a catalytic oxidation step to produce SO.sub.2 which is separated from the remaining desulfurized hydrocarbons that form the clean sulfur-free hydrocarbon product stream; the SO.sub.2 is introduced into a Claus processing unit with the required stoichiometric amount of hydrogen sulfide (H.sub.2S) gas to produce elemental sulfur.

A process for simultaneous removal of hydrogen sulfide (H.sub.2S) and heavy metals from mixture includes charging a contaminated aqueous composition containing heavy metal ions to a reactor. The process also includes passing a H.sub.2S-containing gas composition via a plurality of gas spargers through the contaminated aqueous composition present in the reactor to form a H.sub.2S-containing contaminated aqueous composition and a purified gas composition. The process further includes reacting the H.sub.2S from the H.sub.2S-containing contaminated aqueous composition with the heavy metal ions in the H.sub.2S-containing contaminated aqueous composition to form a metal sulfide precipitate in a metal-sulfide-containing contaminated aqueous composition. In addition, the process includes at least partially introducing the metal-sulfide-containing contaminated aqueous composition to a solid-liquid separator and removing the metal sulfide precipitate from the metal-sulfide-containing contaminated aqueous composition to form a purified aqueous composition.

A sour gas stream is sub-stoichiometrically combusted to produce soot and a sour syngas stream. At least 10% of the carbon in the sour gas stream is converted into the soot. At least a portion of the hydrogen sulfide of the sour syngas stream is reacted with sulfur dioxide to produce a syngas stream comprising the carbon dioxide, the carbon monoxide, the hydrogen, water, elemental sulfur vapor, a residual portion of the hydrogen sulfide, and a residual portion of the sulfur dioxide. The syngas stream is reacted with steam to produce a shifted sour gas stream including more carbon dioxide, more hydrogen, more hydrogen sulfide, and less carbon monoxide in comparison to the syngas stream. Water and hydrogen sulfide is separated from the shifted sour gas stream to produce a sweet gas stream. The sweet gas stream is separated into a hydrogen product stream and an exhaust stream.

The removal of acid gases (e.g., non-carbon dioxide acid gases) using sorbents that include salts in molten form, and related systems and methods, are generally described.

A process for production of elemental sulfur from a feedstock gas including from 15% to 100 vol % H2S and a stream of sulfuric acid, the process including: a) providing a Claus reaction furnace feed stream substoichiometric oxygen with respect to the Claus reaction, b) directing to a reaction furnace zone operating at elevated temperature such as above 900 C., c) directing to a sulfuric acid evaporation zone downstream said reaction furnace zone, d) cooling to provide a cooled Claus converter feed gas, e) directing to contact a material catalytically active in the Claus reaction, f) withdrawing a Claus tail gas and elemental sulfur, g) directing to a Claus tail gas treatment plant, with the associated benefit of a process involving injection of sulfuric acid in a sulfuric acid evaporation zone allowing high temperature combustion of said feedstock gas, including impurities, without cooling from evaporation and decomposition of sulfuric acid.