B01J8/226

METHOD FOR CARRYING OUT A HETEROGENEOUSLY CATALYSED REACTION

A process for performing a heterogeneously catalysed reaction in a three-phase reactor, where there is at least one liquid phase, at least one gaseous phase and at least one solid phase in the reactor and the reactor has at least two zones, with the reaction mixture being conveyed downward in zone 1, the reaction mixture being conveyed upward in zone 2, zones 1 and 2 being separated from one another by a dividing wall, and in that the ratio between the average catalyst concentrations in zone 2 and in zone 1 is greater than 2.

Processing vacuum residuum and vacuum gas oil in ebullated bed reactor systems
10208261 · 2019-02-19 · ·

A process for upgrading vacuum residuum and vacuum gas oil hydrocarbons is disclosed. The process may include: contacting a heavy distillate hydrocarbon fraction and hydrogen with a zeolite selective hydrocracking catalyst in a first ebullated bed hydrocracking reaction zone to convert at least a portion of the vacuum gas oil to lighter hydrocarbons. Contacting a residuum hydrocarbon fraction and hydrogen with a non-zeolite base metal hydroconversion catalyst in a second ebullated bed hydroconversion reaction zone may produce a vapor stream containing unconverted hydrogen, acid gases and volatilized hydrocarbons which may be fed along with the vacuum gas oil in the first ebullated bed hydrocracking zone.

Systems and methods for hydroprocessing heavy oil

A system and method for preparing and conditioning a heavy oil feedstock for hydroprocessing in a hydroprocessing system includes forming metal sulfide catalyst particles in situ within the heavy oil feedstock. The metal sulfide catalyst particles are formed in situ by (1) premixing a catalyst precursor with a hydrocarbon diluent to form a diluted precursor mixture, (2) mixing the diluted precursor mixture with the heavy oil feedstock to form a conditioned feedstock, and (3) heating the conditioned feedstock to decompose the catalyst precursor and cause or allow metal from the precursor to react with sulfur in the heavy oil feedstock to form metal sulfide catalyst particles in situ in the heavy oil feedstock. The in situ formed metal sulfide catalyst particles catalyze beneficial upgrading reactions between the heavy oil feedstock and hydrogen and eliminates or reduces formation of coke precursors and sediment.

LIGHT PARTICLE OR MIXED PARTICLE SYSTEM FOR WASTEWATER TREATMENT
20180280907 · 2018-10-04 ·

The present disclosure provides a light particle system or a mixed particle system for wastewater treatment comprising a contactor. The contactor includes a gas-liquid-solid three-phase region, and the gas-liquid-solid three-phase region includes gas phase, liquid phase, and solid phase. The liquid phase is a continuous phase and the solid phase is light particles or mixed particles. The mixed particles include light particles and heavy particles. The density of the light particles is lower than the density of the liquid phase and the density of the heavy particles is higher than the density of the liquid phase. The light particles or mixed particles are able to carry some microorganisms on their surfaces at least. The light/mixed particle-suspension system in the present invention applied in wastewater treatment can increase the concentration of microorganisms significantly, improve the ability to bear impact load, produce less sludge, and without sludge expansion. The ability to suspend particles under the combined effect of gas and liquid is able to reduce energy consumption to a larger extent. Therefore, this system features both high efficiency and low energy consumption.

Light particle or mixed particle system for wastewater treatment

The present disclosure provides a light particle system or a mixed particle system for wastewater treatment comprising a contactor. The contactor includes a gas-liquid-solid three-phase region, and the gas-liquid-solid three-phase region includes gas phase, liquid phase, and solid phase. The liquid phase is a continuous phase and the solid phase is light particles or mixed particles. The mixed particles include light particles and heavy particles. The density of the light particles is lower than the density of the liquid phase and the density of the heavy particles is higher than the density of the liquid phase. The light particles or mixed particles are able to carry some microorganisms on their surfaces at least. The light/mixed particle-suspension system in the present invention applied in wastewater treatment can increase the concentration of microorganisms significantly, improve the ability to bear impact load, produce less sludge, and without sludge expansion. The ability to suspend particles under the combined effect of gas and liquid is able to reduce energy consumption to a larger extent. Therefore, this system features both high efficiency and low energy consumption.

Method and Device for Lightening Heavy Oil by Utilizing A Suspension-Bed Hydrogenation Process

A method and device for lightening heavy oil by utilizing a suspension-bed hydrogenation process are provided. In the process, a part of a raw oil is mixed with a suspension-bed hydrocracking catalyst to form a first mixture, then the first mixture is subjected to first shear and second shear in sequence so as to realize high dispersion and mixing of the catalyst and the raw oil; through pretreatment of the raw oil, the device can prevent the raw oil from coking in the hydrogenation process; through the adoption of a suspension-bed reactor with a liquid phase self-circulation function or a cold-wall function; and light and heavy components are separated from the suspension-bed hydrogenated product in advance and only medium component is subjected to fixed-bed hydrogenation, thereby reducing the load of the fixed-bed hydrogenation, prolonging the service life of the fixed-bed catalyst, improving the yield and quality of gasoline and diesel, and being beneficial for energy conservation and emission reduction of the whole system.

Method for upgrading ebullated bed reactor and upgraded ebullated bed reactor
09920261 · 2018-03-20 · ·

A hydrocracking system is upgraded by modifying an existing ebullated bed initially utilizing a supported ebullated bed catalyst to thereafter utilize a dual catalyst system that includes metal sulfide catalyst particles and supported ebullated bed catalyst. The upgraded hydrocracking system achieves at least one of: (1) hydroprocess lower quality heavy oil; (2) increase conversion of higher boiling hydrocarbons that boil at 524 C. (975 F.) or higher; (3) reduce the concentration of supported ebullated bed catalyst required to operate an ebullated bed reactor at a given conversion level; and/or (4) proportionally convert the asphaltene fraction in heavy oil at the same conversion level as the heavy oil as a whole. The metal sulfide catalyst may include colloidal or molecular catalyst particles less than 1 micron in size and formed in situ within the heavy oil using a catalyst precursor well-mixed within the heavy oil and decomposed to form catalyst particles.

Process for ethylene polymerization with improved ethylene feed system

The present disclosure relates to a process for the preparation of polyethylene by polymerizing in a slurry ethylene and optionally one or more C.sub.3 to C.sub.10 alpha-olefins. In some embodiments, the polymerization is carried out in a cylindrical polymerization reactor equipped with an agitator for mixing the contents of the reactor and inducing a flow of the slurry, the ethylene is fed into the reactor by an ethylene injection system comprising one or more injection nozzles which project through the bottom reactor head or through the reactor wall and extend from 0.02-0.5 times the inner diameter D into the reactor, and the ethylene exits the injection nozzle with an exit velocity from 10-200 m/s.

System for contacting gases and liquids

A system for contacting gases and liquids includes a vessel containing inert particles, wherein the total volume of the inert particles is from 1 to 20% of the total working volume of the vessel.

PLUG FLOW REACTOR WITH INTERNAL RECIRCULATION FLUIDIZED BED

A reactor comprises an outer sidewall and a bottom wall enclosing a hollow chamber comprising a lower fluidized bed zone and an upper freeboard zone. A plurality of inlets is provided for injecting at least one fluidizing medium into the fluidized bed zone and creating a swirling flow. At least one feed inlet communicates with the fluidized bed zone; and at least one product outlet is provided for removing a product from the chamber, the outlet(s) communicating with either the fluidized bed zone or the freeboard zone. The reactor has at least one internal barrier located inside the hollow chamber, and at least partly located in the fluidized bed zone. The internal barrier(s) have at least one opening within the fluidized bed zone, such as an underflow opening, to permit internal recirculation of material from the product zone to the feed zone, thereby simplifying reactor structure.