A process for large scale and energy efficient product on of oxygenates from sugar is disclosed in which a sugar feedstock is introduced into a thermolytic fragmentation reactor comprising a fluidized stream of heat carrying particles. The heat carrying particles may be separated from the fluidized stream prior to cooling the fragmentation product and may be directed to a reheater to reheat the particles and recirculate the heated particles to the fragmentation reactor.

A heat receiver, a reactor, and a heater utilize the heat of concentrated solar light for thermal decomposition and/or chemical reaction of coals, etc. The heat receiver includes: a side portion forming a substantially cylindrical side surface; a substantially circular bottom portion connected to the lower edge of the side portion; and a ceiling connected to the upper edge of the side portion. A substantially circular aperture is formed in the center of the ceiling. The heat receiver has a substantially cylindrical cavity and the opening portion is open. When the cavity has a diameter of D and a length of L, and the aperture has a diameter of d, d=D/2 or less and L=2D or more. Concentrated solar light entering the heat receiver is to be contained in the heat receiver to effectively utilize the solar light.

A process for producing black powder oxygen carriers for use in a chemical looping combustion unit includes the steps of: (a) removing and collecting the black powder waste material that was formed in a gas pipeline; (b) pre-treating the collected black powder to adjust its spherical shape to avoid attrition and fines production; and (c) activating the black powder to increase its reactivity rate and produce the black powder oxygen carrier that is suitable for use in the chemical looping combustion process as an oxygen carrier.

A system and method for producing ethylene, including dehydrogenating ethane to ethylene via an ODH catalyst in the presence of oxygen in an ODH reactor, discharging an effluent (including at least ethylene, water, and acetic acid) from the ODH reactor, recovering heat from the effluent for processing feed including ethane for the ODH reactor, recovering water from the effluent as recycle water for addition to the feed in performing water dilution of the feed, and adding oxygen to the feed to give a mixed feed including ethane, oxygen, and recycle water to the ODH reactor.

Systems and methods for monitoring a particle/fluid mixture are provided. The method can include flowing a mixture comprising charged particles and a fluid past a particle accumulation probe. The method can also include measuring electrical signals detected by the probe as some charged particles pass the probe without contacting the probe while other charged particles contact the probe. The measured electrical signals can be manipulated to provide an output. The method can also include determining from the output if the charged particles contacting the probe have, on average, a different charge than the charged particles that pass the probe without contacting the probe.

The invention relates to a process and to a unit for chemical looping oxidation-reduction combustion of a hydrocarbon feed, wherein heat exchanges are controlled through a level variation of a dense fluidized bed of active mass particles in an external heat exchanger (E1, E2), positioned on a transport line carrying particles circulating between a reduction zone (210) and an oxidation zone (200) for the particles in the chemical loop. The bed level variation is allowed through controlled application of a pressure drop on a fluidization gas outlet in the heat exchanger, said pressure drop being compensated by the level variation of an active mass particle bed in a reservoir zone provided on the particle circuit in the chemical loop.

A mixing tee assembly suitable for phosphate acid attack reaction is described. The mixing tee assembly comprises an outer pipe having a mixing end and a tee end, wherein a tee structure is formed near the tee end to connect with additional piping; an inner pipe comprising a nozzle end connected to a nozzle and a open end; wherein the inner pipe is lined with a corrosion-resistant material on its inside surface; wherein when the inner pipe is assembled within the outer pipe, the nozzle extends beyond the mixing end of the outer pipe by at least of the inside diameter of the outer pipe.

Reactor vessel and a feed nozzle assembly for feeding a gas and a liquid into such reactor vessel. The feed nozzle assembly comprises an outer tube supplying a first liquid feed, such as oil, an inner tube supplying a dispersion gas, such as steam, a third tube supplying a second liquid feed, such as biomass, and a nozzle end. A catalytic cracking process wherein two or more hydrocarbon liquids are jointly dispersed into a dispersion gas and jetted via the same feed nozzle assembly into a catalytic cracking reactor.

This invention relates to processes and systems for converting acyclic hydrocarbons to alkenes, cyclic hydrocarbons and/or aromatics, for example converting acyclic C.sub.5 hydrocarbons to cyclopentadiene in a reactor system. The process includes contacting a feedstock comprising acyclic hydrocarbons with a catalyst material in at least one reaction zone to convert at least a portion of the acyclic hydrocarbons to a first effluent comprising alkenes, cyclic hydrocarbons and/or aromatics. A co-feed comprising H.sub.2, C.sub.1-C.sub.4 alkanes and/or C.sub.1-C.sub.4 alkenes may also be provided to the at least one reaction zone.

Reactor vessel and a feed nozzle assembly for feeding a gas and a liquid into such reactor vessel. The feed nozzle assembly comprises an outer tube supplying a first liquid feed, such as oil, an inner tube supplying a dispersion gas, such as steam, a third tube supplying a second liquid feed, such as biomass, and a nozzle end. A catalytic cracking process wherein two or more hydrocarbon liquids are jointly dispersed into a dispersion gas and jetted via the same feed nozzle assembly into a catalytic cracking reactor.