Patent classifications
B01J20/183
ZEOLITE-BASED ADSORBENTS BASED ON ZEOLITE X WITH A LOW BINDER CONTENT AND A LOW OUTER SURFACE AREA, PROCESS FOR PREPARING THEM AND USES THEREOF
The invention relates to an adsorbent comprising a zeolite-based phase and a non-zeolite-based phase, said adsorbent having: an outer surface area of less than or equal to 30 m.sup.2.Math.g.sup.−1, preferably less than or equal to 20 m.sup.2.Math.g.sup.−1, a zeolite-based phase comprising at least one zeolite of FAU structure of X type, and a pore diameter distribution, determined by mercury intrusion according to standard ASTM D 4284-83 and expressed by the volume distribution dV/d log DHg, in which DHg is the apparent pore diameter and V is the pore volume, the mode of which is between 100 nm and 250 nm, limits inclusive.
The invention also relates to a process for preparing the said adsorbent and to the uses thereof, especially for separating xylene isomers.
ZEOLITE-BASED ADSORBENTS BASED ON LSX ZEOLITE OF CONTROLLED OUTER SURFACE AREA, PROCESS FOR PREPARING THEM AND USES THEREOF
The present invention relates to a zeolite-based adsorbent comprising at least one zeolite of FAU structure of LSX type and comprising barium and/or potassium, in which the outer surface area of said zeolite-based adsorbent, measured by nitrogen adsorption, is between 20 m.sup.2.Math.g.sup.−1 and 100 m.sup.2.Math.g.sup.−1, limits inclusive. The present invention also relates to the use of such a zeolite-based adsorbent as an adsorption agent, and also to the process for separating para-xylene from aromatic isomer fractions containing 8 carbon atoms.
METHOD FOR SYNTHESIZING ZEOLITIC SOLIDS CONTAINING MESOPORES AND CONTROLLED-SIZE PARTICLES
The present invention relates to a method of synthesis of zeolitic LTA adsorbents containing intercrystalline mesoporosity and controlled particle size, which can, for example, be used in natural gas dehydration processes, seeking to comply not only with the specifications on moisture content in the natural gas, but also improving the efficiency of the gas drying process in regard to the adsorption kinetics, not compromising the adsorption capacity, water selectivity, and the regeneration cycles of the adsorbent. Another possible application of these compounds is as the support for catalysts for oil refining processes. The method of obtaining the zeolitic adsorbent solids, the purpose of this invention, consists of including an aging step of the reaction mixture in conjunction with the addition of N,N-dimethyl-N-[3-(trimethoxysilane)propyl]octadecyl ammonium chloride (TPOAC) to the reaction mixture.
HYDROCARBON ADSORBENT
A hydrocarbon adsorbent according to one exemplary embodiment of the present invention includes a beta zeolite containing copper, in which a Si/Al molar ratio of the beta zeolite is 12.5 to 150, and the amount of the copper contained is 1 wt % to 10 wt %.
ZEOLITE NANOCRYSTAL AGGREGATES
The present invention relates to a zeolite material in the form of FAU zeolite nanocrystal aggregates, to the method for preparing said material, to the zeolite agglomerates prepared from said material with a binder, and to the uses of said material and agglomerate as adsorbents for gas-phase or liquid-phase separation operations, and particularly in methods for separating gas or liquid flows.
Spherical agglomerates based on zeolite(s), process for the production thereof and use thereof in adsorption processes or in catalysis
The present invention relates to spherical agglomerates based on zeolite(s) and clay(s), having controlled size and morphology, in particular a size of less than or equal to 600 μm, very good sphericity, and a high content of zeolitic material, to the process for the production thereof. These agglomerates are particularly suitable for uses in gas-phase and/or liquid-phase adsorption processes.
Adsorbent materials and methods of use
Adsorbent materials comprising a core, for example CHA, and at least one coating, for example DDR, are provided herein. Adsorbent contactors and gas separation processes using the adsorbent materials are also provided herein.
COLORED ZEOLITE ADSORBENT
The present invention concerns a zeolitic adsorbent comprising a zeolitic agglomerate comprising at least one zeolite and at least one agglomeration binder, said agglomerate being coated with a coating comprising at least one pigment.
METHOD FOR SEPARATING META-XYLENE USING A ZEOLITIC ADSORBENT WITH A LARGE EXTERNAL SURFACE AREA
The invention relates to a method for separating meta-xylene from C8 aromatic fractions, using a zeolitic adsorbent based on sodium-exchanged or sodium-and-lithium-exchanged agglomerated crystals of zeolite Y, with a large external surface area.
ZEOLITIC ABSORBENTS COMPRISING A ZEOLITE WITH HIERARCHICAL POROSITY
The invention relates to zeolitic absorbents based on at least one zeolite with hierarchical porosity, containing barium or barium and potassium, to the uses thereof for separating para-xylene from aromatic fractions containing 8 carbon atoms, and to the method for separating para-xylene from aromatic fractions containing 8 carbon atoms.