B01J20/186

MODIFIED ZEOLITE FOR HEAVY METAL REMOVAL
20220323929 · 2022-10-13 · ·

The present invention relates to the use of particulate mineral material comprising modified heulandite group zeolite for removing heavy metal cations from a liquid medium, wherein at least a part of the exchangeable cations in the heulandite group zeolite is replaced by ammonium cations.

Potassium-merlinoite zeolite, its synthesis and use
11465122 · 2022-10-11 · ·

The present disclosure is directed to a method for making a MER framework type zeolite, a MER framework type zeolite having a stick-like morphology, and processes for the selective separation of carbon dioxide (CO.sub.2) from multi-component feedstreams containing CO.sub.2 using the zeolite.

Adsorptive xenon recovery process from a gas or liquid stream at cryogenic temperature

The present invention relates to an adsorption process for xenon recovery from a cryogenic liquid or gas stream wherein a bed of adsorbent is contacted with a xenon-containing liquid or gas stream selectively adsorbing the xenon from said stream. The adsorption bed is operated to at least near full breakthrough with xenon to enable a deep rejection of other stream components, prior to regeneration using the temperature swing method. After the stripping step, the xenon adsorbent bed is drained to clear out the liquid residue left in the nonselective void space and the xenon molecules in those void spaces is recycled upstream to the ASU distillation column for increasing xenon recovery. The xenon adsorbent bed is optionally purged with oxygen, followed by purging with gaseous argon at cryogenic temperature (≤160 K) to displace the oxygen co-adsorbed on the AgX adsorbent due to higher selectivity of argon over oxygen on the AgX adsorbent. By the end of this step, the xenon adsorbent bed is filled with argon and xenon. Then the entire adsorbent bed is heated indirectly without utilizing any of the purge gas for direct heating. Operating the adsorption bed to near full breakthrough with xenon and displacing the adsorbed oxygen and other residues with argon, prior to regeneration, along with indirect heating of the bed, enables production of a high purity product ≥40 vol % xenon from the adsorption bed and further enables safely heating without any purge gas and ease for downstream product collection, even in cases where hydrocarbons are co-present in the feed stream.

Hydrocarbon adsorbent
11648527 · 2023-05-16 · ·

To provide a hydrocarbon adsorbent having high hydrocarbon adsorbing properties even after exposed to a high temperature/high humidity reducing atmosphere. A hydrocarbon adsorbent, which includes a FAU type zeolite having a lattice constant of at least 24.29 Å and containing copper. Such a hydrocarbon adsorbent may be used for a method for adsorbing hydrocarbons to be exposed to a high temperature/high humidity environment, and may be used particularly for a method for adsorbing hydrocarbons in an exhaust gas of an internal combustion engine, such as an automobile exhaust gas.

HYDROCARBON ADSORBENT AND METHOD FOR ADSORBING HYDROCARBONS
20230148413 · 2023-05-11 · ·

A hydrocarbon adsorbent having a high hydrocarbon desorption start temperature and a method for adsorbing hydrocarbons that uses the hydrocarbon adsorbent are provided. The hydrocarbon adsorbent includes an alkali metal and a zeolite having a ring structure that includes at least 10 members is used. In the hydrocarbon adsorbent, a content of the alkali metal is 1 to 40 mass % based on a total mass of the hydrocarbon adsorbent, a content of the zeolite having a ring structure that includes at least 10 members is 99 to 60 mass % based on the total mass of the hydrocarbon adsorbent, and at least a portion of the alkali metal is in a state of being ion-exchangeable.

Method for preparing a high-purity AFX structural zeolite with a nitrogen-containing organic structuring agent

The invention relates to a process for preparing an AFX-structure zeolite comprising at least the following steps: i) mixing, in an aqueous medium, an FAU-structure zeolite having an SiO.sub.2 (FAU)/Al.sub.2O.sub.3 (FAU) molar ratio of between 2.00 (limit included) and 6.00 (limit excluded), an organic nitrogenous compound R, at least one source of at least one alkali and/or alkaline-earth metal M, the reaction mixture having the following molar composition: (SiO.sub.2 (FAU))/(Al.sub.2O.sub.3 (FAU)) between 2.00 (limit included) and 6.00 (limit excluded), H.sub.2O/(SiO.sub.2 (FAU)) between 1 and 100, R/(SiO.sub.2 (FAU)) between 0.01 and 0.6, M.sub.2/nO/(SiO.sub.2 (FAU)) between 0.005 and 0.7, limits included, until a homogeneous precursor gel is obtained; ii) hydrothermal treatment of said precursor gel obtained on conclusion of step i) at a temperature of between 120° C. and 220° C., for a time of between 12 hours and 15 days.

Process For Recovering Precious Metals From Molecular Sieve Bodies
20230141211 · 2023-05-11 ·

Precious metals such as those of the platinum group can be effectively recovered from crystalline aluminosilicate supports, for example from spent catalysts, without appreciable degradation of the crystal structure by ion-exchange using a base metal ion containing medium and subsequent sequestration of the precious metal in elemental form on a nonionic cross linked borane reducing resin.

PACKAGING MATERIALS

The use of a palladium-doped zeolite for the adsorption of volatile organic compounds is described wherein the zeolite has a CHA framework type and is polymer-bound. Such zeolites have been found to have particular utility as packaging materials for the adsorption of volatile organic compounds, such as those originating from organic matter.

FOOD CONTAINER FOR PRESERVING FRESHNESS OF FOOD ITEMS
20230202736 · 2023-06-29 ·

The invention discloses a food container for preserving freshness of food, comprising a container body having a cavity adapted for containing food items; a lid detachably secured on the container body to close the cavity of the container; and one or more food preserving elements capable of absorbing food spoiling gas to preserve freshness of the food items. The one or more food preserving elements are disposed inside the cavity and/or into a material of the food container to preserve the food items for an extended period of time and remove odors.

HYDROCARBON ADSORBENT WITH METAL-IMPREGNATED ZEOLITE PARTICLE HAVING REGULAR MESOPORE AND MANUFACTURING METHOD THEREFOR

The present invention relates to a hydrocarbon adsorbent with metal-impregnated zeolite particles having regular mesopores and a manufacturing method therefor. The hydrocarbon adsorbent includes a metal cation and a metal oxide that are impregnated in zeolite particles, in particular, the zeolite particles include regularly formed mesopores having a size of 2 to 10. By adjusting a Si/Al ratio and mesoporosity of the mesopores, a hydrocarbon adsorbent may have increased adsorption capacity for hydrocarbons in a cold-start section and can rapidly oxidize the hydrocarbon upon desorption thereof, thereby reducing the discharge of exhaust gas produced in automobiles and industries.