A method for preparing, in the internal volume of at least one channel, a monolithic support on which uranyl cations are immobilised. The method comprises: (a) activating the inner surface of the channel(s); (b) introducing, into the internal volume of the channel(s), a polymerisation solution comprising: a monomer comprising a phosphate group, at least one crosslinking agent, several solvents, and a radical polymerisation initiator; (c) polymerising the polymerisation solution; (d) rinsing the monolithic support obtained in step (c); and (e) contacting the monolithic support previously rinsed, with a solution comprising uranyl cations. A method for capturing proteins that selectively bind uranium by means of a monolithic support prepared by the above-mentioned method, as well as to a method for recovering proteins that selectively bind uranium with the capture method.

The methods of the invention employ targeted magnetic particles, preferably targeted nanomagnetic particles, and targeted buoyant particles such as buoyant microparticles and microbubbles. Among the benefits of the invention is the ability to combine targeted magnetic particles with differentially targeted buoyant particles to achieve separation of two or more specifically cell targeted populations during the same work flow.

The present invention provides novel chromatographic materials, e.g., for chromatographic separations, processes for its preparation and separations devices containing the chromatographic material; separations devices, chromatographic columns and kits comprising the same; and methods for the preparation thereof. The chromatographic materials of the invention are chromatographic materials comprising having a narrow particle size distribution.

Magnetic nanoparticle coated porous materials for recovering a contaminant from contaminated water are provided. In embodiments, such a material comprises a porous substrate having a solid matrix defining a plurality of pores distributed through the solid matrix and further comprising a coating comprising magnetic nanoparticles on surfaces of the solid matrix.

A thermochemical energy storage system and method of storing thermal energy are described. The energy storing system described herein comprises a reactor comprising: a) a reactor with a CO.sub.2 sorbent including MgO; and b) a supercritical CO.sub.2 source with supercritical CO.sub.2 and H.sub.2O, wherein the supercritical CO.sub.2 source is in fluid communication with the reactor and the CO.sub.2 sorbent including MgO to allow flow of the supercritical CO.sub.2 and H.sub.2O between the supercritical CO.sub.2 source and the reactor, thereby allowing contact of CO.sub.2 with the CO.sub.2 sorbent comprising MgO.

The invention relates to a process for preparing core-shell particles comprising the steps of (i) providing a dispersion of primary magnetic particles having a mean diameter lower than 200 nm in a solvent; (ii) adding one or more (semi-)metal (oxyhydr)oxide(s) and/or one or more precursor(s) of a (semi-)metal (oxyhydr)oxide to said dispersion; (iii) optionally adding a hydrolysis agent for said one or more precursor(s); (iv) injecting the dispersion in a spray dryer; whereby a (semi-)metal (oxyhydr)oxide shell is formed on the magnetic particles during spray drying. The invention also relates to particles obtainable by said process, to a formulation of said particles in a solvent and to the use of said particles or said formulation for RNA or DNA extraction.

A filter medium for removal of contaminants from wastewater. The filter medium includes a walnut shell particle having a metal hydro(oxide) nanoparticle bonded to the surface of the nut shell particle. The filter medium is particularly useful for treating produced water and wastewater generated in steam-assisted gravity drainage (SAGD) in recovery of hydrocarbons from oil sands to remove total organic carbon and silica. Processes for preparing the filter medium and for treating wastewater using the filter medium are also provided.

A preparation method of a lanthanum-iron-loaded carbon nanotube film for environmental restoration is provided, it belongs to the technical field of composite materials. The preparation method includes: mixing carbon nanotubes with a lanthanum-iron mixed solution to obtain a suspension, then obtaining a first reaction solution by a constant temperature oscillation reaction; adding alkali liquor into the first reaction solution to obtain a second reaction solution by an oscillation reaction; carrying out a solid-liquid separation on the second reaction solution, adding the obtained solid after drying into an organic solution, and obtaining a third reaction solution by ultrasonic mixing; centrifuging the third reaction solution to obtain a supernatant; obtaining a lanthanum-iron-loaded carbon nanotube film by suction filtration. Compared with powdered adsorbent and single adsorbent, the material prepared by the preparation method has advantages of strong stability, high adsorption efficiency, good regeneration effect, high recycling efficiency, and low production.

A composite comprising a hydroxyapatite and at least one additive which is present during hydroxyapatite synthesis. The additive may be embedded or incorporated into or coated onto the hydroxyapatite. The additive preferably increases the hydroxyapatite porosity, e.g., providing a higher pore volume and/or BET surface area than a hydroxyapatite material without additive. The additive preferably comprises an activated carbon, chitosan, hopcalite, clays, zeolites, sulfur, and/or a metal such as Al, Sn, Ti, Fe, Cu, Zn, Ni, Cu, Zr, La, Ce, in the form of metal, salt, oxide, oxyhydroxide, and/or hydroxide. The hydroxyapatite may be calcium-deficient. The composite is in the form of particles having a D50 of at least 20 μm, a BET surface area of at least 120 m.sup.2/g; and/or a total pore volume of at least 0.3 cm.sup.3/g. An adsorbent material comprising a composite or a blend of composite with a hydroxyapatite without additive, and its use for removal of contaminants such as Hg, Se, As, and/or B from an effluent.

Described are boron oxide-containing adsorbents that include porous adsorbent base and boron oxide on surfaces of the base, as well as devices that include the boron oxide-containing adsorbent, and related methods of preparing and using the boron oxide-containing adsorbent.