A process for producing an alkylaromatic compound comprises providing a first feed comprising an alkylatable aromatic compound and a second feed comprising an alkylating agent, wherein at least the first feed contains an impurity compound comprising at least one of nitrogen, halogens, oxygen, sulfur, arsenic, selenium, tellurium, phosphorus, and Group 1 through Group 12 metals The first feed is passed through an adsorbent comprising a metal-organic framework material under conditions effective to reduce the amount of impurity compound in the first feed and produce a purified first feed. The purified first feed and at least part of the second feed are then contacted with an alkylation catalyst composition under alkylation conditions effective to convert at least part of the alkylatable aromatic compound in the purified first feed to the desired alkylaromatic compound and produce an alkylation effluent.

There are provided herein methods and systems for increasing efficiency in a multi-stage activated carbon system. The methods and systems provide a cleaned carbon solids fraction and a waste liquor from wet air regeneration, and direct the same to a second stage and a first stage, respectively, of the multi-stage activated carbon system to enhance removal efficiency therein.

A method and system are disclosed for regenerating carbonaceous adsorbent, the method comprising the steps of: a) providing a carbonaceous adsorbent comprising a catalyst and adsorbed contaminants, b) pyrolysing of the adsorbed contaminants, c) reactivating the carbonaceous adsorbent by subjecting the carbonaceous adsorbent to steam thereby obtaining a reactivated carbonaceous adsorbent, d) cooling the thus obtained reactivated carbonaceous adsorbent to a temperature of less than 250? C. and e) oxidizing catalyst that is in a reduced state following steps b) and c) comprised in the reactivated carbonaceous adsorbent.

A process for producing an alkylaromatic compound comprises providing a first feed comprising an alkylatable aromatic compound and a second feed comprising an alkylating agent, wherein at least the first feed contains an impurity compound comprising at least one of nitrogen, halogens, oxygen, sulfur, arsenic, selenium, tellurium, phosphorus, and Group 1 through Group 12 metals The first feed is passed through an adsorbent comprising a metal-organic framework material under conditions effective to reduce the amount of impurity compound in the first feed and produce a purified first feed. The purified first feed and at least part of the second feed are then contacted with an alkylation catalyst composition under alkylation conditions effective to convert at least part of the alkylatable aromatic compound in the purified first feed to the desired alkylaromatic compound and produce an alkylation effluent.

A composite sorbent polymer composite article is disclosed for adsorption. The sorbent polymer composite article includes a sorbent and a flexible porous polymer, the sorbent polymer composite article having an adsorptive configuration in which the sorbent polymer composite article is configured to adsorb one or more components of a feed stream, and a desorptive configuration in which the sorbent polymer composite article is configured to remove one or more components from the sorbent polymer composite article.

A process for altering the composition of a feed gas containing H.sub.2S equivalents is disclosed. The process comprises (a) contacting the feed gas with a solid adsorbent at a temperature of 250-500 C., to obtain a loaded adsorbent, (b) purging the loaded adsorbent with a purge gas comprising steam, thus producing a product stream which typically contains substantially equal levels of CO.sub.2 and H.sub.2S. The process further comprises a step (c) of regenerating the purged adsorbent by removal of water. The adsorbent comprises alumina and one or more alkali metals, such as potassium oxides, hydroxide or the like.

A method and a system capable of removing carbon dioxide directly from ambient air, and obtaining relatively pure CO.sub.2. The method comprises the steps of generating usable and process heat from a primary production process; applying the process heat from said primary process to co-generate substantially saturated steam, alternately repeatedly exposing a sorbent to removal and to capture regeneration system phases, wherein said sorbent is alternately exposed to a flow of ambient air during said removal phase, to sorb, and therefore remove, carbon dioxide from said ambient air, and to a flow of the process steam during the regeneration and capture phase, to remove the sorbed carbon dioxide, thus regenerating such sorbent, and capturing in relatively pure form the removed carbon dioxide. The sorbent can be carried on a porous thin flexible sheet constantly in motion between the removal location and the regeneration location.

The present disclosure relates to improved solid state sorbent materials and methods for controlling and enhancing carbon dioxide adsorption performance for selected metal-organic framework (MOF) materials. The present disclosure further relates to inventive methods using a novel class of diamine-appended metal-organic frameworks MOF absorbents displaying step-shaped adsorption isotherms with large carbon dioxide capacities. More specifically, the present disclosure relates to diamine-appended MOF materials exhibiting step-shaped adsorption isotherms that are employed in a method utilizing humidity to control and improve carbon dioxide adsorption performance. In addition, the present disclosure relates to diamine-appended MOF materials used in a process including a regeneration step with carbon dioxide and humidity level control to achieve deep carbon dioxide removal even from dilute, near ambient condition carbon dioxide streams as well as more concentrated industrial output streams spanning multiple orders of magnitude. The present disclosure also relates to scrubbing apparatus and methods employing the inventive MOF materials, methods, process steps and apparatus as disclosed to achieve rapid and deeper carbon dioxide capture without the need to pretreat column materials.

A volatile organic compound condensation system and method thereof for enhancing drying efficiency of a filter using VOC condensation heat including high-temperature steam condensation heat are disclosed. A volatile organic compound condensing system according to the present invention is characterized by comprising: an adsorption-desorption unit repeating an adsorption process of adsorbing volatile organic compound (VOC) from a supply gas and a desorption process of desorbing the adsorbed VOC by supplying high-temperature steam to the VOC adsorbed by the adsorption process; a condensation heat storage unit for storing VOC condensation heat being generated in the adsorption-desorption unit by using phase change material (PCM); and a drying control unit that dries the adsorption-desorption unit after the desorption process by using the condensation heat stored in the condensation heat storage unit.

Systems and methods of direct air capture are described. Systems include a plurality of moving adsorber panels in a linear direction (or circular configuration) and one or more fans configured to move air across the adsorber panels; such adsorber panels may be oriented vertically or horizontally, relative to the ground. Systems may include an independent regeneration box that comprises a system of headers, ducts and valves configured to deliver and remove a plurality of gases to the regeneration box. The regeneration box contains multiple chambers such that steps such as oxygen removal and panel cooling may be performed independently from and simultaneously to thermal preheating and desorption of the CO.sub.2 on the panels. The desorption panels may be configured to achieve counter-current flow to the hot gases used for thermal preheating and desorption. A multi-stage heat pump may facilitate reuse of waste heat and decarbonization of the process heating requirements.