A catalyst structure includes a porous support structure, where the support structure includes an aluminosilicate material and any two or more metals loaded in the porous support structure selected from Ga, Ag, Mo, Zn, Co and Ce. The catalyst structure is used in a hydrocarbon upgrading process that is conducted in the presence of methane, nitrogen or hydrogen.

Disclosed is a hydrocracking catalyst, a preparation method and an application thereof. The catalyst comprises a carrier, silicon dioxide and active ingredients loaded on the carrier, wherein the carrier comprises Y molecular sieves and SAPO-34 molecular sieves. The preparation method of the hydrocracking catalyst comprises the following steps: (1) mixing materials comprising Y molecular sieves and SAPO-34 molecular sieves, and then subjecting the mixture to molding, drying and calcinating to obtain a carrier; (2) introducing silane and the active ingredients into the carrier prepared in the step (1), subsequently performing the drying and calcinating to prepare the hydrocracking catalyst. The catalyst prepared with the method can be used for hydrocracking reaction, thereby significantly increase yield of jet fuel.

A cluster-supporting catalyst including porous carrier particles having acid sites, and catalyst metal clusters supported within the pores of the porous carrier particles. In the cluster-supporting catalyst including porous carrier particles having acid sites, and catalyst metal clusters supported within the pores of the porous carrier particles, the catalyst metal may be rhodium, the catalyst metal may be palladium, the catalyst metal may be platinum, or the catalyst metal may be copper.

A cluster-supporting catalyst including porous carrier particles having acid sites, and catalyst metal clusters supported within the pores of the porous carrier particles. The catalyst metal clusters are obtained by supporting catalyst metal clusters having a positive charge, which is formed in a dispersion liquid containing a dispersion medium and the porous carrier particles dispersed in the dispersion medium, on the acid sites within the pores of the porous carrier particles through an electrostatic interaction.

Improvements in catalyst systems and associated processes for the conversion of glycolaldehyde to monoethanolamine are disclosed. The catalyst systems exhibit improved selectivity to this desired product and consequently reduced selectivity to byproducts such as diethanolamine and ethylene glycol. These beneficial effects are achieved through the use of acids, and particularly Lewis acids, as co-catalysts of the reductive amination reaction, in conjunction with a hydrogenation catalyst.

A catalyst for the carbonylation of dimethyl ether to methyl acetate. The catalyst comprises a zeolite, such as a mordenite zeolite, at least one Group IB metal, such as copper, and/or at least one Group VIII metal, such as iron, and at least one Group IIB metal, such as zinc. Such a catalyst with combined metals provides enhanced catalytic activity, improved stability, and improved selectivity to methyl acetate, and does not require a halogen promoter, as compared to a metal-free or copper only zeolite.

A preparation method for modified molecular sieve and a modified molecular sieve-containing catalytic cracking catalyst. The preparation method comprises: mixing molecular sieve slurry, a compound solution containing ions of group IIIB metals of the periodic table of elements, organic complexing agent and/or dispersing agent and precipitating agent to obtain mixed slurry containing molecular sieve and precipitates of group IIIB elements in the periodic table of elements; and drying, and roasting or not roasting to obtain molecular sieve modified by the group IIIB elements. A weight ratio of group IIIB elements calculated based on oxides to molecular sieve dry basis is equal to (0.3-10):100, a molar ratio of organic complexing agent to ions of group IIIB metals is equal to (0.3-10):1, and a molar ratio of dispersing agent to the ions of group IIIB metals is equal to (0.2-16):1. Also related to is the catalytic cracking catalyst containing the modified molecular sieve prepared according to the method. The molecular sieve prepared by the method or the catalytic cracking catalyst containing same has good activity stability and heavy metal pollution resistance.

The present disclosure discloses an immobilized metalloporphyrin catalyst and its utilization in maleic acid preparation, belonging to the technical field of metalloporphyrin catalytic application. The immobilized metalloporphyrin catalyst is used for catalyzing furfural to prepare maleic acid and is good in catalytic effect, mild in reaction conditions and capable of greatly reducing the energy consumption required in the prior art. The catalyst disclosed by the present disclosure can provide a good microenvironment for a reaction, so that the yield and selectivity of maleic acid are increased; and according to a method disclosed by the present disclosure, the conversion ratio of furfural is 20.4%-95.6%, the yield of maleic acid is 10%-56.1%, and the selectivity is 43.6%-76.1%. Meanwhile, the catalyst is easy to separate and environmentally friendly and may be recycled for many times.

The present disclosure discloses an immobilized metalloporphyrin catalyst and its utilization in maleic acid preparation, belonging to the technical field of metalloporphyrin catalytic application. The immobilized metalloporphyrin catalyst is used for catalyzing furfural to prepare maleic acid and is good in catalytic effect, mild in reaction conditions and capable of greatly reducing the energy consumption required in the prior art. The catalyst disclosed by the present disclosure can provide a good microenvironment for a reaction, so that the yield and selectivity of maleic acid are increased; and according to a method disclosed by the present disclosure, the conversion ratio of furfural is 20.4%-95.6%, the yield of maleic acid is 10%-56.1%, and the selectivity is 43.6%-76.1%. Meanwhile, the catalyst is easy to separate and environmentally friendly and may be recycled for many times.

The present invention relates to crystalline zeolites with an ERI/CHA intergrowth framework type and to a process for making said zeolites. The ERI content of the zeolites ranges from 10 to 85 wt.-%, based on the total weight of ERI and CHA. The zeolites may further comprise 0.1 to 10 wt.-% copper, calculated as CuO, and one or more alkali and alkaline earth metal cations in an amount of 0.1 to 5 wt.-%, calculated as pure metals. The process for making the zeolites with an ERI/CAH intergrowth framework type comprises a) the preparation of a first aqueous reaction mixture comprising a zeolite of the faujasite framework type, Cu-TEPA and a base M(OH), b) the preparation of a second aqueous reaction mixture comprising a silica source, an alumina source, an alkali or alkaline earth metal chloride, bromide or hydroxide, a quaternary alkylammonium salt and hexamethonium bromide, c) combining the two reaction mixtures, and d) heating the combination of the two reaction mixtures to obtain a zeolite with an ERI/CHA intergrowth framework type. The ERI/CHA intergrowth zeolite may subsequently be calcined. The zeolites according to the present invention are suitable SCR catalysts.