Patent classifications
B01J2208/00176
SUBMERGED PROPYLENE HYDRATION MICRO-INTERFACE STRENGTHENING REACTION SYSTEM AND METHOD THEREOF
A submerged propylene hydration micro-interface strengthening reaction system and a method are proposed. The system includes a reactor, a first micro-interface generator and a second micro-interface generator. Through the micro-interface generators, the propylene is broken to form micron-scale bubbles, which are mixed with reactants and deionized water to form a gas-liquid emulsion, so as to increase a phase boundary area between gas and liquid phases, and achieve a strengthening mass transfer effect under a lower preset operating condition. The micro-scale bubbles can be fully mixed with the deionized water to from a gas-liquid emulsion. By fully mixing gas and liquid phases, it can ensure that the deionized water in the system is in full contact with propylene, and they are fully in contact with the catalyst, which effectively improves the efficiency of preparing isopropanol.
Hydrogen generation assemblies and hydrogen purification devices
Hydrogen generation assemblies, hydrogen purification devices, and their components, and methods of manufacturing those assemblies, devices, and components are disclosed. In some embodiments, the devices may include an insulation base having insulating material and at least one passage that extends through the insulating material. In some embodiments, the at least one passage may be in fluid communication with a combustion region.
PROCESS AND APPARATUS FOR UREA PRODUCTION
In a urea synthesis process, temperature distribution in a submerged condenser is reduced. The process includes: synthesizing urea from NH.sub.3 and CO.sub.2 to generate a urea synthesis solution; by heating the solution, decomposing ammonium carbamate and separating a gaseous mixture containing NH.sub.3 and CO.sub.2 from the solution to obtain a solution higher in urea concentration than the solution obtained in the synthesizing; with use of a submerged condenser including a shell and tube heat exchange structure including a U-tube, absorbing and condensing at least a part of the gaseous mixture in an absorption medium on a shell side, and generating steam on a tube side with use of heat generated during the condensation; and recycling at least a part of liquid, obtained from the shell side, to the synthesizing, wherein water is supplied to the tube side of the condenser at a mass flow rate that is three times or more of the steam generation rate.
Reactor for continuously treating polymeric material
A system for continuously treating recycled polymeric material includes a hopper configured to feed the recycled polymeric material into the system. An extruder can turn the recycled polymeric material in a molten material. In some embodiments, the extruder uses thermal fluids, electric heaters, and/or a separate heater. The molten material is depolymerized in a reactor. In some embodiments, a catalyst is used to aid in depolymerizing the material. In certain embodiments, the catalyst is contained in a permeable container. The depolymerized molten material can then be cooled via a heat exchanger. In some embodiments, multiple reactors are used. In certain embodiments, these reactors are connected in series. In some embodiments, the reactor(s) contain removable static mixer(s) and/or removable annular inserts.
Polymerization of propylene
Disclosed are a method and system for propylene polymerization utilizing a loop slurry reactor. The method can include polymerizing propylene in a loop slurry reactor under bulk polymerization conditions to produce polypropylene. The propylene polymerization system can include i) a loop slurry reactor and a heat exchange system that is configured to cool the legs of the loop slurry reactor and/or ii) an inlet manifold that is configured to connect flashline heaters to a separator.
METHOD AND DEVICE FOR PRODUCING LITHIUM TRANSITION METAL OXIDE
Provided is a method for producing a lithium transition metal oxide, comprising, A) mixing a lithium salt and a precursor, adding the mixture into a reactor for precalcination; the lithium salt has a particle size D50 of 10-20 μm and the precursor has a particle size D50 of 1-20 μm, and the precursor is one or more selected from transition metal oxyhydroxide, transition metal hydroxide and transition metal carbonate; and B) adding the product obtained from the precalcination into a fluidized bed reactor, subjecting to a first calcination and a second calcination to obtain the lithium transition metal oxide. Raw materials for the lithium transition metal oxide further includes a main-group metal compound containing oxygen, which is added in the precalcination, the first calcination or the second calcination; and the main-group metal compound containing oxygen has an average particle size of 10-100 nm. A fluidized bed reactor is also provided.
Method for Catalytic Conversion of Hydrocarbon with Downer Reactor and Device Thereof
Provided are a method for the catalytic conversion of hydrocarbons with a downer reactor and a device thereof. The specific process of the method is as follows: a raw material of hydrocarbons after being pre-heated (or not) and a low-temperature regenerant from a regenerant cooler entering an entry end of a downer reactor, flowing down along the reactor for reactions such as catalytic cracking, and a mixture of a reactive oil and gas and a catalyst descending to the end of the reactor for rapid separation, thereby achieving the rapid separation of the catalyst and the oil and gas. The main operation conditions thereof are as follows: the reaction temperature is 460 to 680° C., the reaction pressure is 0.11 to 0.4 MPa, the contact time is 0.05 to 2 seconds, and the weight ratio of the catalyst to the raw material (a catalyst-to-oil ratio) is 6 to 50. The separated catalyst to be regenerated (abbreviated as a spent agent) is stripped by means of a stripper, and enters a regenerator and is burned for regeneration, wherein the regeneration temperature is controlled at 630-730° C. The regenerant from the regenerator enters the regenerant cooler to be cooled to 200-720° C., and then enters the downer reactor for recycling
Mixing tee assembly and process
A mixing tee assembly suitable for phosphate acid attack reaction is described. The mixing tee assembly comprises an outer pipe having a mixing end and a tee end, wherein a tee structure is formed near the tee end to connect with additional piping; an inner pipe comprising a nozzle end connected to a nozzle and a open end; wherein the inner pipe is lined with a corrosion-resistant material on its inside surface; wherein when the inner pipe is assembled within the outer pipe, the nozzle extends beyond the mixing end of the outer pipe by at least ⅓ of the inside diameter of the outer pipe.
Polymerization of propylene
Disclosed are a method and system for propylene polymerization utilizing a loop slurry reactor. The method can include polymerizing propylene in a loop slurry reactor under bulk polymerization conditions to produce polypropylene. The propylene polymerization system can include i) a loop slurry reactor and a heat exchange system that is configured to cool the legs of the loop slurry reactor and/or ii) an inlet manifold that is configured to connect flashline heaters to a separator.
PROCESS FOR EFFICIENT POLYMER PARTICLE PURGING
A process comprising polymerizing olefin monomers and optionally comonomers in a first reactor vessel, thereby forming a raw product stream comprising polymerized solids, unreacted monomer and optionally comonomer, the polymerized solids comprising olefin polymer, volatile organic compounds (VOC) and catalyst system. Then the polymerized solids are contacted with a catalyst poison selected from carbon monoxide, carbon dioxide, oxygen, water, alcohols, amines, or mixtures thereof, thereby forming a passivated stream. The passivated stream is maintained in an agitated state within a second reactor. The passivated stream within the second reactor is then contacted with a circulating gas comprising unreacted monomer for a residence time, thereby reducing the concentration of VOC in the polymerized solids by at least 10 wt % compared to the level before entering the second reactor, thereby forming a purified olefin polymer solids stream.