In an embodiment, a method of producing a carbonate comprises reacting carbon monoxide and chlorine in a phosgene reactor in the presence of a catalyst to produce a first product comprising phosgene; wherein carbon tetrachloride is present in the first product in an amount of 0 to 10 ppm by volume based on the total volume of phosgene; and reacting a monohydroxy compound with the phosgene to produce the carbonate; wherein the phosgene reactor comprises a tube, a shell, and a space located between the tube and the shell; wherein the tube comprises one or more of a mini-tube section and a second tube section; a first concentric tube concentrically located in the shell; a twisted tube; an internal scaffold; and an external scaffold.

A multi-bed catalytic converter (1) with inter-bed heat exchangers, comprising a plurality of superimposed catalytic beds and a common heat exchanger (5) which is shared between two or more consecutive catalytic beds, said common heat exchanger including heat exchange bodies such as a tube bundle (6), and a wall system (9, 10) to define a tube side and a shell side respectively, and the shell side comprising at least a first space (12) and a second space (13), wherein the first space (12) receives the product gas leaving the first of said consecutive beds, and the inter-cooled gas leaving said first space (12) is admitted in the second bed (3-3) for further conversion, and a sealing means (14) preventing a direct gas passage from said first space to said second space.

A method for generating hydrogen is provided. In certain embodiments, the method can include the steps of: introducing a hydrocarbon feed stream, at a first temperature, into a first reaction zone under conditions effective for producing a first process stream, wherein the first process stream is at a second temperature that is greater than the first temperature; introducing a second feed stream into a second reaction zone under conditions effective for producing a hydrogen product stream, wherein heat needed for producing the hydrogen product stream from the second feed stream is at least partially provided by heat exchange with the first process stream; and withdrawing the hydrogen product stream from the second reaction zone.

A reactor for producing phosgene, the reactor comprising: tube located in a shell and a space located between the tube and the shell; a cooling medium located in the space and a catalyst located in the tube or cooling medium located in the tube and a catalyst located in the space; a feed inlet; and a product mixture outlet; wherein the tube comprises one or more of: a mini-tube and a second tube section; a first concentric tube concentrically located in the shell; a twisted tube; an internal scaffold; and an external scaffold.

Horizontal adiabatic reactor (1) for heterogeneous catalytic reactions, comprising an outer cylindrical shell (2), an inlet (6) for reagent gases and an outlet (7) for gaseous products, a basket (10, 13) containing a catalytic bed (5a, 5b) positioned horizontally inside said reactor, wherein said reactor is configured in such a way that the gases cross said catalytic bed in a radial or axial-radial manner, said shell (2) has a cover (4) which can be opened and which defines an opening (20), and said basket (10, 13) is extractable horizontally from said opening.

A reactor for catalytic conversion of gas mixtures may include a catalyst bed. An upper side of the catalyst bed may include a gas lock that is movable in a vertical direction. The gas lock may be lowered when the catalyst bed contracts. In some examples, the gas lock prevents a gas mixture from flowing out of the catalyst bed via the upper side of the catalyst bed.

In a urea synthesis process, temperature distribution in a submerged condenser is reduced. The process includes: synthesizing urea from NH.sub.3 and CO.sub.2 to generate a urea synthesis solution; by heating the solution, decomposing ammonium carbamate and separating a gaseous mixture containing NH.sub.3 and CO.sub.2 from the solution to obtain a solution higher in urea concentration than the solution obtained in the synthesizing; with use of a submerged condenser including a shell and tube heat exchange structure including a U-tube, absorbing and condensing at least a part of the gaseous mixture in an absorption medium on a shell side, and generating steam on a tube side with use of heat generated during the condensation; and recycling at least a part of liquid, obtained from the shell side, to the synthesizing, wherein water is supplied to the tube side of the condenser at a mass flow rate that is three times or more of the steam generation rate.

The invention relates to an oxidation reactor for partial oxidation of a feed stream with an oxygen-containing oxidant stream to give a hydrogen-containing product stream. This partial oxidation may be conducted as a noncatalytic partial oxidation (POX) or as an autothermal reforming (ATR). Useful feed streams here include hydrocarbonaceous streams, but also ammonia-containing streams. According to the invention, the oxidation reactor is equipped with multiple cooling zones surrounding the reactor shell. As a result, operation of the oxidation reactor can continue if, for example, merely an inspection or repair at a particular point in the reactor shell is required. Operation of the oxidation reactor can continue over the duration of the inspection or repair measures, such that production shutdowns are avoided.

In an embodiment, a method of producing a carbonate comprises reacting carbon monoxide and chlorine in a phosgene reactor in the presence of a catalyst to produce a first product comprising phosgene; wherein carbon tetrachloride is present in the first product in an amount of 0 to 10 ppm by volume based on the total volume of phosgene; and reacting a monohydroxy compound with the phosgene to produce the carbonate; wherein the phosgene reactor comprises a tube, a shell, and a space located between the tube and the shell; wherein the tube comprises one or more of a mini-tube section and a second tube section; a first concentric tube concentrically located in the shell; a twisted tube; an internal scaffold; and an external scaffold.

A fuel cell module (includes a first area where an exhaust gas combustor and a start-up combustor are provided, an annular second area around the first area and where a reformer and a heat exchanger are provided, and an annular third area around the second area and where an evaporator is provided. Second circumscribed non-uniform-flow suppression plates are provided along the minimum circumscribed circles which contact outer surfaces of heat exchange pipes of the heat exchanger.