The present invention provides a semiconductor structure comprising: a silicon substrate in [100] orientation; a scandium oxide layer over the substrate, in [111] orientation; and a scandium-rare earth-oxide layer over the scandium oxide layer. The scandium-rare earth-oxide layer can have a graded composition to transition lattice constant to match to a subsequent layer, such as an indium nitride layer having very high electron drift velocity. InN over Si (100) offers transistors, photonics and passive electronics that operate in the terahertz frequency range.

A Group-III element nitride substrate includes a first main surface and a second main surface facing each other, wherein, in the first main surface, crystallinity of a first part positioned on a central portion thereof is higher than crystallinity of a second part positioned outside the first part.

Disclosed herein is the controlled epitaxy of Al.sub.xGa.sub.1-xAs, Al.sub.xIn.sub.1-xP, and Al.sub.xGa.sub.yIn.sub.1-x-yP by hydride vapor phase epitaxy (HVPE) through use of an external AlCl.sub.3 generator.

Methods for forming structures that include forming a heteroepitaxial layer on a substrate are disclosed. The presently disclosed methods comprise epitaxially forming a buffer layer on the substrate. The substrate has a substrate composition. The buffer layer has a buffer layer composition. The buffer layer composition is substantially identical to the substrate composition. The presently disclosed methods further comprise epitaxially forming a heteroepitaxial layer on the buffer layer. The heteroepitaxial layer has a heteroepitaxial layer composition which is different from the substrate composition.

A method for fabricating a semiconductor device, the method comprising the steps of: providing a silicon-on-insulator (SOI) substrate, the SOI substrate comprising a groove exposing different crystal facing a planar surface; depositing a buffer layer over the substrate; epitaxially growing a semiconductor layer over the buffer layer, whereby least a portion of the buffer layer exhibits a cubic crystalline phase structure.

A film formation method of forming a film on a surface of a wafer using a vapor growth apparatus is provided. The film formation method includes a film forming process of forming a film on the surface of the wafer. The vapor growth apparatus includes a susceptor that supports the wafer. The susceptor includes a plurality of wafer supports that support the wafer from below and rotates around a rotation axis extending in a vertical direction. The plurality of wafer supports are arranged at intervals in a circumferential direction around the rotation axis. The film forming process includes supporting the wafer using the plurality of wafer supports such that a direction in which the rotation axis and each wafer support are connected when seen in the vertical direction is a direction which is different from a cleaving direction of the wafer.

An underlying substrate for a single crystal diamond laminate substrate, the underlying substrate including an initial substrate being any of a single crystal Si substrate, a single crystal -Al.sub.2O.sub.3 substrate, etc., and an intermediate layer on the initial substrate, in which an outermost surface on the initial substrate has an off angle in a crystal axis <1-12> direction relative to a cubic crystal plane orientation, or has an off angle in a crystal axis <10-10> or <11-20> direction relative to a hexagonal crystal plane orientation, etc. This provides the underlying substrate capable of forming a single crystal diamond layer having a large area (large diameter), high crystallinity, few hillocks, few abnormal growth particles such as twin crystals, few dislocation defects, etc., high purity, low stress, and high quality and applicable to an electronic and magnetic device.

The present application provides a substrate and a manufacturing method therefor. The substrate includes a silicon substrate and a protective layer, the silicon substrate includes a middle part and an edge part, and a thickness of the middle part is greater than a thickness of the edge part. The middle part has a to-be-grown surface, and a crystal orientation of the to-be-grown surface is different from a crystal orientation of surface of the edge part. The protective layer covers the edge part and is configured to prevent defects in the edge part from extending to the middle part during high-temperature processing.

A method for forming an epitaxial stack on a plurality of substrates comprises providing a plurality of substrates to a process chamber and executing deposition cycles, wherein each deposition cycle comprises a first deposition pulse and a second deposition pulse. The epitaxial stack comprises a first epitaxial layer stacked alternatingly and repeatedly with a second epitaxial layer, the second epitaxial layer being different from the first epitaxial layer. The first deposition pulse comprises a provision of a first reaction gas mixture to the process chamber, thereby forming the first epitaxial layer having a first native lattice parameter. The second deposition pulse comprises a provision of a second reaction gas mixture to the process chamber, thereby forming the second epitaxial layer having a second native lattice parameter, wherein the first native lattice parameter lies in a range within 1.5% larger than and 0.9% smaller than the second native lattice parameter.

A method of processing a silicon surface includes using a first radical species to remove contamination from the surface and to roughen the surface; and using a second radical species to smooth the roughened surface. Reaction systems for performing such a method, and silicon surfaces prepared using such a method, also are provided.