Methods of forming contacts for source/drain regions and a contact plug for a gate stack of a finFET device are disclosed herein. Methods include etching a contact opening through a dielectric layer to expose surfaces of a first source/drain contact and repairing silicon oxide structures along sidewall surfaces of the contact opening and along planar surfaces of the dielectric layer to prevent selective loss defects from occurring during a subsequent selective deposition of conductive fill materials and during subsequent etching of other contact openings. The methods further include performing a selective bottom-up deposition of conductive fill material to form a second source/drain contact. According to some of the methods, once the second source/drain contact has been formed, the contact plug may be formed over the gate stack.

Interconnect structures having dielectric layers with nitrogen-containing crusts and methods of fabrication thereof are disclosed herein. An exemplary method includes forming a first interconnect opening in a first interlayer dielectric (ILD) layer that exposes an underlying conductive feature, such as a source/drain, a gate, a contact, a via, or a conductive line. The method includes nitridizing sidewalls of the first interconnect opening, which are formed by the first ILD layer, before forming a first metal contact in the first interconnect opening. The nitridizing converts a portion of the first ILD layer into a nitrogen-containing crust. The first metal contact can include a metal plug and dielectric spacers between the metal plug and the nitrogen-containing crust of the first ILD layer. The method can include forming a second interconnect opening in a second ILD layer that exposes the first metal contact and forming a second metal contact in the second interconnect opening.

Methods used in electronic device manufacturing and, more particularly, to methods used for forming metal containing interconnect features in a semiconductor device. In one aspect, a method of forming a boron nitride layer on a metal surface is provided. The method includes exposing a surface of a metal layer to a nitrogen-containing plasma to form a metal nitride layer on the surface. The method further includes performing a chemical vapor deposition (CVD) soak process in which the metal nitride layer is exposed to a boron (B)-containing precursor gas, form a boron nitride monolayer.

In an embodiment, a device includes: a source/drain region over a semiconductor substrate; a dielectric layer over the source/drain region, the dielectric layer including a first dielectric material; an inter-layer dielectric over the dielectric layer, the inter-layer dielectric including a second dielectric material and an impurity, the second dielectric material different from the first dielectric material, a first portion of the inter-layer dielectric having a first concentration of the impurity, a second portion of the inter-layer dielectric having a second concentration of the impurity, the first concentration less than the second concentration; and a source/drain contact extending through the inter-layer dielectric and the dielectric layer to contact the source/drain region, the first portion of the inter-layer dielectric disposed between the source/drain contact and the second portion of the inter-layer dielectric.

There is provided a semiconductor device capable of improving the performance and reliability of a device. The semiconductor device may include a first interlayer insulating film containing therein a plurality of pores, a first line structure in the first interlayer insulating film, an inserted insulating film extending along and on a upper surface of the first interlayer insulating film and in contact with the first interlayer insulating film, a barrier insulating film in contact with the inserted insulating film and extending along an upper surface of the inserted insulating film and an upper surface of the first line structure, a second interlayer insulating film on the barrier insulating film and a second line structure disposed in the second interlayer insulating film and connected to the first line structure.

Embodiments herein provide for oxygen based treatment of low-k dielectric layers deposited using a flowable chemical vapor deposition (FCVD) process. Oxygen based treatment of the FCVD deposited low-k dielectric layers desirably increases the Ebd to capacitance and reliability of the devices while removing voids. Embodiments include methods and apparatus for making a semiconductor device including: etching a metal layer disposed atop a substrate to form one or more metal lines having a top surface, a first side, and a second side; depositing a passivation layer atop the top surface, the first side, and the second side under conditions sufficient to reduce or eliminate oxygen contact with the one or more metal lines; depositing a flowable layer of low-k dielectric material atop the passivation layer in a thickness sufficient to cover the one or more metal lines; and contacting the flowable layer of low-k dielectric material with oxygen under conditions sufficient to anneal and increase a density of the low-k dielectric material.

A method for manufacturing a semiconductor device includes: forming on a substrate, a structure including a plurality of dielectric spacers and a plurality of dielectric portions that are disposed to form a plurality of recesses, such that each of the recesses is formed between a corresponding one of the dielectric spacers and a corresponding one of the dielectric portions; and subjecting the dielectric spacers and the dielectric portions to a plasma treatment process such that the dielectric spacers and the dielectric portions are deformed to form a plurality of capping portions to cap the recesses, respectively, so as to form a plurality of air gaps.

A semiconductor device includes a gate structure on a substrate, an offset spacer adjacent to the gate structure, a main spacer around the offset spacer, a source/drain region adjacent to two sides of the main spacer, a contact etch stop layer (CESL) adjacent to the main spacer, and an interlayer dielectric (ILD) layer around the CESL. Preferably, a dielectric constant of the offset spacer is higher than a dielectric constant of the main spacer.

A method of forming a semiconductor structure includes forming a conductive structure in a first dielectric layer. A second dielectric layer is formed over the first dielectric layer. A conductive contact is formed in the second dielectric layer. The second dielectric layer is etched to form a recess on a top surface of the conductive structure. A native oxide layer is formed on a top surface and a sidewall of the second dielectric layer, the top surface of the conductive structure, and a sidewall of the conductive contact. A first plasma process is performed to form a first material layer over the native oxide layer by using a first plasma gas. A second plasma process is performed to form a second material layer over the first material layer by a second plasma gas different from the first plasma gas. A spacer layer is formed on the second material layer.

A dielectric structure is formed over a layer than contains a conductive component. An opening is formed in the dielectric structure. The opening exposes an upper surface of the conductive component. A first deposition process is performed that deposits a first conductive layer over the dielectric structure and partially in the opening. A treatment process is performed on a first portion of the first conductive layer formed over the dielectric structure. The treatment process introduces a non-metal material to the first portion of the first conductive layer. After the treatment process has been performed, a second deposition process is performed that at least partially fills the opening with a second conductive layer without trapping a gap therein.