The removal of acid gases (e.g., non-carbon dioxide acid gases) using sorbents that include salts in molten form, and related systems and methods, are generally described.

Apparatus and methods for controlling ammonia escape in an ammonia-based decarbonization system, wherein ammonia may be used as the desulfurization and decarbonization agent, the gas may first enter the desulfurization device for desulfurization to produce ammonium sulfate fertilizer, and the desulfurized gas may enter the decarbonization device to remove carbon dioxide in the gas, and may produce ammonium bicarbonate fertilizer. The decarbonized gas may include free ammonia, and the free ammonia in the gas may be absorbed with the acidic ammonium sulfate solution and acidic water washing liquid of ammonia-based desulfurization.

A method for improving effectiveness of a steam generator system includes providing air to an air preheater at a mass flow such that the air preheater has a cold end outlet temperature defined by the improved air preheater operating with increased heat recovery (HR) of at least 1% calculated according to the equation: HR=100%((TgiTgoAdvX)/(TgiTgoSTD)1). The method requires either reducing the amount of heat that flows into the air preheater from the flue gas and/or increasing the amount of heat extracted from the flue gas. The method includes mitigating SO.sub.3 in the flue gas which is discharged directly from the air preheater to a particulate removal system and then directly into a flue gas desulfurization system. The method includes extracting heat from the Flue gas to create equipment preheat and/or flue gas stack reheat air with the latter being fed to heat the flue gas prior to entering a discharge stack to raise the temperature of the flue gas to mitigate visible plume exiting and to mitigate corrosion in, the discharge stack.

This disclosure provides a method for treating natural gas comprising causing at least some of a sour natural gas stream comprising hydrocarbon gas and hydrogen sulfide to contact an amine or pass through a separation system. A sweet natural gas stream comprising hydrocarbon gas and a waste gas stream comprising hydrogen sulfide are formed by contacting the sour natural gas with an amine or by passing it though a separation device. At least some of the hydrogen sulfide in the waste gas stream is oxidized, forming an exhaust gas stream comprising sulfur dioxide, which is then contacted with water or reactant and water solution or slurry to destroy or convert SO.sub.2 into a less environmentally harmful compound.

Provided is an operation support system for a desulfurization apparatus evaluates soundness of the desulfurization apparatus by comparing an analytic performance calculated based on operation data of the desulfurization apparatus and a measured performance and creates support information including an operation condition candidate set based on the evaluation result and a balance forecast.

Marine engine exhaust includes pollutants such as CO.sub.2, NOR.sub.x and SO.sub.x. An onboard system and method for the simultaneous removal of these pollutants includes obtaining seawater from the water on which the marine vessel travels, purifying the seawater to remove a portion of hard ions, concentrating the seawater to yield a concentrated brine solution, treating the concentrated brine solution with a chemical softener to yield a treated brine solution, acidifying the treated brine solution, and utilizing the acidified brine solution in a chlor-alkali process to yield sodium hydroxide. The sodium hydroxide can be used in an acid gas scrubber to remove CO.sub.2, NO.sub.x, and SO.sub.x from the marine engine exhaust gas.

A hydrated lime product exhibiting superior reactivity towards HCl and SO.sub.2 in air pollution control applications. Also disclosed is a method of providing highly reactive hydrated lime and the resultant lime hydrate where an initial lime feed comprising calcium and impurities is first ground to a particle-size distribution with relatively course particles. Smaller particles are then removed from this ground lime and the smaller particles are hydrated and flash dried to form a hydrated lime, which is then milled to a significantly smaller particle size than that of the relatively course particles. The resultant lime hydrate product has available CaOH of greater than 92%, a citric acid reactivity of less than 20 seconds, a BET surface area greater than 18, a D90 less than 10 m, a D50 less than 4 m, a D90/D50 less than 3, and a large pore volume of greater than 0.2 BJH.

A hydrated lime product exhibiting superior reactivity towards HCl and SO.sub.2 in air pollution control applications. Also disclosed is a method of providing highly reactive hydrated lime and the resultant lime hydrate where an initial lime feed comprising calcium and impurities is first ground to a particle-size distribution with relatively course particles. Smaller particles are then removed from this ground lime and the smaller particles are hydrated and flash dried to form a hydrated lime, which is then milled to a significantly smaller particle size than that of the relatively course particles. The resultant lime hydrate product has available CaOH of greater than 92%, a citric acid reactivity of less than 20 seconds, a BET surface area greater than 18, a D90 less than 10 m, a D50 less than 4 m, a D90/D50 less than 3, and a large pore volume of greater than 0.2 BJH.

The disclosure provides seven integrated methods for the chemical sequestration of carbon dioxide (CO.sub.2), nitric oxide (NO), nitrogen dioxide (NO.sub.2) (collectively NO.sub.x, where x=1, 2) and sulfur dioxide (SO.sub.2) using closed loop technology. The methods recycle process reagents and mass balance consumable reagents that can be made using electrochemical separation of sodium chloride (NaCl) or potassium chloride (KCl). The technology applies to marine and terrestrial exhaust gas sources for CO.sub.2, NOx and SO.sub.2. The integrated technology combines compatible and green processes that capture and/or convert CO.sub.2, NOx and SO.sub.2 into compounds that enhance the environment, many with commercial value.

Conversion methods and equipment for converting a calcium-based flue gas desulfurization (FGD) system to an ammonia-based FGD systems, including modifying a reagent system and absorber system of the calcium-based FGD system to be capable of, respectively, delivering an ammonia-based reagent to the absorber system rather than the calcium-based reagent, and modifying the absorber system to increase capacity of a reaction tank thereof.