Systems for reducing the content of residual pollutants from tailpipes emissions in an exhaust line having a cold part may include an ozone generation system; an MnO.sub.2 catalyst; and a lean NO.sub.x trap (LNT) catalyst. In these systems, the ozone, MnO.sub.2 catalyst, and LNT catalyst may be provided in the cold part of the exhaust line. In these systems, the residuals pollutants may be oxidized at temperatures of from about 20° C. to about 150° C. in rich or lean conditions and NO.sub.2 may have a concentration of less than 0.1 mg/km in the tailpipe emissions downstream of the cold part of the exhaust line. Corresponding methods may include generating ozone from an ozonizer; injecting the ozone in a mixing chamber comprising the residual pollutants to form a first mixture; converting the first mixture using an MnO.sub.2 catalyst to form a second mixture; and converting the second mixture using an LNT catalyst.

Proposed are a low-temperature DeNOx catalyst for selective catalytic reduction having improved sulfur resistance and a method of manufacturing the same. The low-temperature DeNOx catalyst for selective catalytic reduction having improved sulfur resistance accelerates the reduction reaction of nitrogen oxides even at low temperatures despite the small amount of vanadium supported, improves sulfur poisoning resistance, does not cause secondary environmental pollution by treated gas, has excellent abrasion resistance and strength and thus the removal efficiency of nitrogen oxides is not reduced even during long-term operation, and is easy to manufacture, thus contributing to commercialization.

Disclosed are a cerium-zirconium solid solution and a preparation method therefor and an application thereof, which belong to the field of adsorbing catalyst materials. The cerium-zirconium solid solution includes a cerium-zirconium solid solution phase with a Ce.sup.3+/Ce.sup.4+ molar ratio of 0.05-0.8:1. The cerium-zirconium solid solution phase in the cerium-zirconium solid solution of the present application includes trivalent cerium ions and tetravalent cerium ions in a specific ratio. The cerium-zirconium solid solution has a high oxygen storage and release rate, a high oxygen storage and release capacity, and the cerium-zirconium solid solution during the storage and release of oxygen has a stable structure and good catalytic performance; and the catalyst containing the cerium-zirconium solid solution has good catalytic performance under different fuel ratios.

Systems for reducing the content of residual pollutants from tailpipes emissions in an exhaust line having a cold part may include an ozone generation system; an MnO.sub.2 catalyst; and a lean NO.sub.x trap (LNT) catalyst. In these systems, the ozone, MnO.sub.2 catalyst, and LNT catalyst may be provided in the cold part of the exhaust line. In these systems, the residuals pollutants may be oxidized at temperatures of from about 20° C. to about 150° C. in rich or lean conditions and NO.sub.2 may have a concentration of less than 0.1 mg/km in the tailpipe emissions downstream of the cold part of the exhaust line. Corresponding methods may include generating ozone from an ozonizer; injecting the ozone in a mixing chamber comprising the residual pollutants to form a first mixture; converting the first mixture using an MnO.sub.2 catalyst to form a second mixture; and converting the second mixture using an LNT catalyst.

Provided is a catalyst which, when used in a selective catalytic reduction reaction in which ammonia serves as the reducing agent, further improves denitration efficiency at low temperatures compared to the prior art.

The denitration catalyst comprises vanadium oxide as a main component, and has a content of a second metal, in teams of oxide, of 1-40 wt %. The second metal is at least one type of metal element selected from the group consisting of Co, W, Mo, Nb, Ce, Sn, Ni, Fe, Cu, Zn, and Mn.

A process of reducing the content of nitrogen oxides in a gas, comprising passing the gas over a catalyst suitable for selective catalytic reduction of nitrogen oxides and in the presence of a reducing agent, wherein the catalyst is a FER-zeolite obtainable with a process which does not include a step of iron loading and does not include a step of loading with any transition metal so that said FER-zeolite does not contain ion-exchanged iron and is not loaded with iron or any transition metal.

The present invention pertains to a catalyst for use in the selective catalytic reduction (SCR) of nitrogen oxides comprising: • a monolithic substrate and • a coating A which comprises an oxidic metal carrier comprising an oxide of titanium and a catalytic metal oxide which comprises an oxide of vanadium wherein the mass ratio vanadium/titanium is 0.07 to 0.26.

JMZ-1, a zeolite having a CHA structure and containing trimethyl(cyclohexylmethyl)ammonium cations as a structure directing agent is described. A calcined zeolite, JMZ-1C, that does not contain a structure directing agent, is also described. Metal containing JMZ-1C has improved SCR activity compared to CHA-containing zeolites having the same metal loading and comparable silica:alumina ratios (SAR). Methods of preparing JMZ-1, JMZ-1C and metal containing calcined counterparts of JMZ-1C are described along with methods of using JMZ-1C and metal containing calcined counterparts of JMZ-1C in treating exhaust gases.

Disdosed is a method of preparing a high-performance zeolite catalyst for reducing nitrogen oxide emissions, and more particularly a technique for preparing a zeolite catalyst, suitable for use in effectively removing nitrogen oxide (NOx), among exhaust gases emitted from vehicle internal combustion engines through selective catalytic reduction (SCR), thereby exhibiting high efficiency, high chemical stability and high thermal durability upon SCR using the prepared catalyst.

A metal-containing chabazite zeolite, which has an FTIR peak area ratio between the peak at 900-1300 cm.sup.−1 (Si—O—Si asymmetric stretch) and the peak at 765-845 cm.sup.−1 (˜805 cm.sup.−1 is Si—O—Si symmetric stretch) of at least 55. A method for preparing metal-containing CHA zeolites with high SCR activity at low reaction temperatures from alkali cation-free reaction mixtures that contain the three OSDA structures: metal-polyamine, N,N,N-trimethyl-1-adamantyl ammonium (TMAda+) and TMAOH. The metal-containing CHA zeolites produced by the disclosed method can be identified by XRD, FTIR spectroscopy, FT-VIS spectroscopy, and scanning electron microscopy. A method of selective catalytic reduction of NOx in exhaust gas using the material described herein is also disclosed.