Proposed are a low-temperature DeNOx catalyst for selective catalytic reduction having improved sulfur resistance and a method of manufacturing the same. The low-temperature DeNOx catalyst for selective catalytic reduction having improved sulfur resistance accelerates the reduction reaction of nitrogen oxides even at low temperatures despite the small amount of vanadium supported, improves sulfur poisoning resistance, does not cause secondary environmental pollution by treated gas, has excellent abrasion resistance and strength and thus the removal efficiency of nitrogen oxides is not reduced even during long-term operation, and is easy to manufacture, thus contributing to commercialization.

A copper-CHA zeolite catalyst for SCR of NO.sub.x is disclosed.

An improved cluster-supporting catalyst has heteroatom-removed zeolite particles, and catalyst metal clusters supported within the pores of the heteroatom-removed zeolite particles. A method for producing a cluster-supporting catalyst includes the following steps: providing a dispersion liquid containing a dispersion medium and the heteroatom-removed zeolite particles dispersed in the dispersion medium; and in the dispersion liquid, forming catalyst metal clusters having a positive charge, and supporting the catalyst metal clusters within the pores of the heteroatom-removed zeolite particles through an electrostatic interaction.

An as-synthesized microporous material having a CHA structure and containing at least one organic structure directing agent that has the following general structure of the quaternary ammonium cation is disclosed: ##STR00001##
A microporous crystalline material made from the as-synthesized material is also disclosed. A method of making microporous crystalline material using one or more organic structure directing agents is also disclosed. A method of selective catalytic reduction of nitrogen oxides in exhaust gas that comprises contacting exhaust gases, typically in the presence of ammonia, urea, an ammonia generating compound, or a hydrocarbon compound, with an article comprising the disclosed microporous crystalline is also disclosed.

A method for simultaneous removal of NO and carbonic particles and inorganic dust from flue gases in a reactor with a catalyst for direct decomposition of nitric oxide located on a metallic monolith, includes tangential introduction of flue gases to the reactor circumference. Flue gases flow rotationally and downwards in the reactor in contact with an undulating surface of metallic foil located on an inner wall of the reactor chamber and in contact with the catalyst on a spiral band falling to the lower part of the reactor, and next flue gases jet direction counter-currently to a cylindrical inner chamber containing slices of the monolithic catalyst disturbing laminar flow of the flue gases jet. The reactor arrangement provides for simultaneous removal of NO and carbon particles and inorganic dust from flue gases.

A method of reducing NO.sub.x in tail gas obtained during startup of a plant for preparing nitric acid may involve heating the tail gas from a starting temperature T.sub.0, through a threshold temperature T.sub.G, to an operating temperature T.sub.B at which steady-state operation of the plant can occur (T.sub.0<T.sub.G<T.sub.B). NO.sub.x-containing tail gas may be passed through a storage medium and at least partially stored while the temperature of the tail gas is lower than the threshold temperature T.sub.G. The NO.sub.x may be released, preferably when the temperature of the tail gas has attained the threshold temperature T.sub.G. The NO.sub.x may be combined with a reducing agent in the presence of an SCR catalyst after the temperature of the tail gas has exceeded the threshold temperature T.sub.G, but not before, resulting in catalytic reduction of at least a portion of the NO.sub.x.

The present disclosure relates to methods of preparing sols of titanium dioxide nanoparticles that are photoactive, neutral, and in a substantially concentrated form. The methods particularly provide for concentrated sols in light of washing and dewatering under low cation concentrations and utilizing rapid peptizing through addition of the filter case to the peptizing agent. Concentrated acid may be utilized to maintain high TiO.sub.2 concentration while still avoiding precipitation of the colloidal TiO.sub.2. Concentrated photoactive, neutral titanium dioxide sols are also provided as well as compositions thereof and photoactive coatings formed therewith.

A nano-functionalized support comprises an application surface and a photocatalytic nanoparticle coating deposited on the application surface. The photocatalytic nanoparticle coating comprises titanium dioxide doped with a nitrogen-containing doping agent.

Method and system for the removal of nitrogen oxides, from flue gas at low temperatures.

CeO.sub.2 nanoparticles having a copper domain disposed on at least a portion of the nanoparticle. The material can catalyze a nitrogen oxide decomposition, such as a deN.sub.xO.sub.y reaction. Methods of making and using the material are also provided.