Patent classifications
B01J29/7476
HYDROISOMERIZATION CATALYST
The present disclosure relates to a precursor for a catalytically active material or a catalytically active material comprising platinum, a molecular sieve and a metal oxide support, characterized in at least 80%, 90% or 95% of said platinum being dispersed on said molecular sieve and at least 80%, 90% or 95% of said platinum being dispersed in clusters having a size below 2 nm or 1 nm, as well as a method of producing such materials and process for hydroisomerization involving such materials. The disclosure has the associated benefit of such a catalytically active material being highly active and selective towards hydroisomerization.
Heavy Aromatics Conversion Processes and Catalyst Compositions Used Therein
Disclosed are processes for conversion of a feedstock comprising C.sub.8+ aromatic hydrocarbons to lighter aromatic products in which the feedstock and optionally hydrogen are contacted in the presence of the catalyst composition under conversion conditions effective to dealkylate and transalkylate said C.sub.8+ aromatic hydrocarbons to produce said lighter aromatic products comprising benzene, toluene and xylene. The catalyst composition comprises a zeolite, a first metal, and a second metal, and is treated with a source of sulfur and/or a source of steam.
Heavy Aromatics Conversion Processes and Catalyst Compositions Used Therein
Disclosed are processes for conversion of a feedstock comprising C.sub.8+ aromatic hydrocarbons to lighter aromatic products in which the feedstock and optionally hydrogen are contacted in the presence of a first and a second catalyst composition under conversion conditions effective to produce said lighter aromatic products comprising benzene, toluene and xylene. In the process, the C.sub.8+ aromatic hydrocarbons are dealkylated to form C.sub.6-C.sub.7 aromatic hydrocarbon and the C.sub.2+ olefins formed are saturated. The remaining C.sub.8+ aromatic hydrocarbons are transalkylated with the C.sub.6-C.sub.7 aromatic hydrocarbon. The first and second catalyst compositions each comprise a zeolite, a first metal, and optionally a second metal, and are treated with a source of sulfur and/or a source of steam.
VEHICLE POWERTRAIN WITH ON-BOARD CATALYTIC REFORMER
A power system comprises an engine configured to combust an air/fuel mixture and produce a flow of exhaust gas; an exhaust passageway fluidly connected to the engine to receive the flow of exhaust gas; an exhaust gas recirculation loop fluidly connecting the exhaust passageway to a fuel intake for the engine; a first conversion zone containing a fuel reforming catalyst located within the exhaust gas recirculation loop; and a second conversion zone located within the exhaust gas recirculation loop separate from and downstream of the first conversion zone stream, the second conversion zone containing a fuel cracking catalyst.
Conversion of synthesis gas to liquid fuels
Catalyst systems are provided, along with corresponding methods, for single stage conversion of synthesis gas to fuel boiling range products with increased selectivity for either naphtha production (C.sub.5-C.sub.9) or distillate production (C.sub.10-C.sub.20). The increased selectivity for naphtha production or distillate production is provided in conjunction with a reduced selectivity for higher boiling range components (C.sub.21+).
XENON ADSORBENT
A xenon adsorbent capable of efficiently adsorbing xenon, even at a low concentration, from a mixture gas is Provided.
A xenon adsorbent comprising a zeolite having a pore size in the range of 3.5 to 5 and a silica alumina molar ratio in the range of 10 to 30.
Modified composite molecular sieve and preparation method thereof, and paraffin isomerization catalyst
The present invention provides a modified composite molecular sieve, and a preparation method and an application of the modified composite molecular sieve. The modified composite molecular sieve comprises SiO.sub.2 and a composite molecular sieve that comprises molecular sieve MCM-22 and crystalline molecular sieve selected from at least one of ZSM-22, ZSM-23 and ZSM-48, wherein, the molecular sieve MCM-22 covers around the crystalline molecular sieve. The present invention further provides a catalyst and an application of the catalyst. The catalyst comprises a carrier and a noble metal loaded on the carrier, wherein, the carrier comprises a modified composite molecular sieve that is the modified composite molecular sieve provided in the present invention or the modified composite molecular sieve obtained with the method provided in the present invention. The catalyst that utilizes the composite molecular sieve as a carrier not only can decrease the solidifying point of waxy raw oil, but also can improve the yield of liquid product, is especially applicable to the isomerization dewaxing process of lube distillate, and has an advantage of remarkably improving the viscosity index of lube base oil.
CATALYSTS AND METHODS OF MAKING THE SAME
Catalysts including at least one microporous material (e.g., zeolite), an organosilica material binder, and at least one catalyst metal are provided herein. Methods of making the catalysts, preferably without surfactants and processes of using the catalysts, e.g., for aromatic hydrogenation, are also provided herein.
Method for preparing noble metal hydrogenation catalyst, noble metal hydrogenation catalyst and use thereof
- Xiaodong Yang ,
- Chunmei Yu ,
- Yanfeng Liu ,
- Sheng Hu ,
- Zhihua Zhang ,
- Famin Sun ,
- Wencheng Zhang ,
- Jintao Guo ,
- Wenyong Liu ,
- Xinmiao Wang ,
- Shanbin Gao ,
- Bin Xie ,
- Jinxian Jiang ,
- Yuhe Yang ,
- Rui Li ,
- Guojia Zhang ,
- Lili Jiang ,
- Tan Zhao ,
- Dongqing Wang ,
- Jingying Zhao ,
- Quanguo Zhang ,
- Ruifeng Li ,
- Shengbo Sun ,
- Hong Li ,
- Cheng Tang
Disclosed are a method for preparing a noble metal hydrogenation catalyst comprising preparing a carrier from a molecular sieve having a 10-member ring structure and/or an amorphous porous material; preparing a noble metal impregnation solution; and preparing noble metal impregnation solutions in a concentration gradient ranging from 0.05 to 5.0 wt % with deionized water, and sequentially impregnating the carrier with the impregnation solutions from low to high concentrations during the carrier impregnation process, or preparing a noble metal impregnation solution at a low concentration ranging from 0.05 to 0.5 wt % and impregnating the carrier by gradually increasing the concentration of the noble metal impregnation solution to 2.0 to 5.0 wt % in the impregnation process, followed by homogenization, drying, and calcination, as well as a noble metal hydrogenation catalyst, use thereof, and a method for preparing lubricant base oil.
Catalysts and methods of making the same
Catalysts including at least one microporous material (e.g., zeolite), an organosilica material binder, and at least one catalyst metal are provided herein. Methods of making the catalysts, preferably without surfactants and processes of using the catalysts, e.g., for aromatic hydrogenation, are also provided herein.