A low pressure process for producing thin film crystalline black phosphorus on a substrate and a black phosphorus thin film made by the process. The process includes flowing a phosphorus-containing gas into a deposition chamber and depositing phosphorus from the phosphorus-containing gas onto the substrate in the chamber. The substrate is selected from (i) a gold substrate, a gold-tin alloy substrate, a silver substrate and a copper substrate and (ii) a substrate comprising a thin film of metal selected from gold, tin, silver, copper and alloys of the foregoing metals. The substrate and phosphorus are heated to a temperature ranging from about 350 to less than about 500 C. to form a phosphorus intermediate composition. The substrate and intermediate composition are heated to a temperature of greater than 500 C. to less than about 1000 C. convert the metal phosphorus intermediate composition to the black phosphorus thin film.

A single-step, in situ bipolar exfoliation system, and methods for exfoliations of multi-layer bulk black phosphorous into single-layer (two-dimensional), few-layer, or even nano-platelets phosphorene are provided. The bipolar exfoliation system can include: a first driving electrode; a second driving electrode electrically connected to the first driving electrode through an external power supply; at least one bipolar electrode comprising multi-layer bulk black phosphorous; and a solvent in physical contact with the first driving electrode, the second driving electrode, and the at least one bipolar electrode. The system can be configured such that the electric conditions between the first and second driving electrodes can be used to turn one end of the at least one bipolar electrode into an anodic pole and the other end of the at least one bipolar electrode into a cathodic pole such that the multi-layer black phosphorous is exfoliated into the single-layer, few-layer, or nano-platelets phosphorene.

A single-step, in situ bipolar exfoliation system, and methods for exfoliations of multi-layer bulk black phosphorous into single-layer (two-dimensional), few-layer, or even nano-platelets phosphorene are provided. The bipolar exfoliation system can include: a first driving electrode; a second driving electrode electrically connected to the first driving electrode through an external power supply; at least one bipolar electrode comprising multi-layer bulk black phosphorous; and a solvent in physical contact with the first driving electrode, the second driving electrode, and the at least one bipolar electrode. The system can be configured such that the electric conditions between the first and second driving electrodes can be used to turn one end of the at least one bipolar electrode into an anodic pole and the other end of the at least one bipolar electrode into a cathodic pole such that the multi-layer black phosphorous is exfoliated into the single-layer, few-layer, or nano-platelets phosphorene.

Disclosed is a method of obtaining an inorganic nanostructured complex (CFI-1), a protein-associated nanostructured complex (MRB-CFI-1) and antitumor use. The main use is in treating urinary bladder cancer, both in animals arid humans. The complex has singular antitumor activity, and can potentially be used as a substitute and/or act as an adjuvant for other commercial antineoplastic drugs.

Disclosed is a method of obtaining an inorganic nanostructured complex (CFI-1), a protein-associated nanostructured complex (MRB-CFI-1) and antitumor use. The main use is in treating urinary bladder cancer, both in animals arid humans. The complex has singular antitumor activity, and can potentially be used as a substitute and/or act as an adjuvant for other commercial antineoplastic drugs.

A black phosphorus crystal having a high photoelectric response rate, a two-dimensional black phosphorus PN junction, and preparation method and use thereof. The black phosphorus crystal is a single crystal with a spatial point group Cmca (No. 64), cell parameters a=3.2-3.4 , b=10.4-10.6 , c=4.3-4.5 , and an interlayer spacing of 4-6 , and is characterized by a high photoelectric response rate, an adjustable semiconductor type, and the like. The two-dimensional black phosphorus PN junction includes a two-dimensional black phosphorus film, a first area of the film forming an n-type semiconductor by n-type doping, a second area of the film is maintained as a p-type semiconductor, and the first area is adjacent to the second area, to enable the n-type semiconductor to be combined with the p-type semiconductor to form the PN junction. The two-dimensional black phosphorus PN junction has properties such as a unidirectional conductivity, or a special photovoltaic effect.

A black phosphorus crystal having a high photoelectric response rate, a two-dimensional black phosphorus PN junction, and preparation method and use thereof. The black phosphorus crystal is a single crystal with a spatial point group Cmca (No. 64), cell parameters a=3.2-3.4 , b=10.4-10.6 , c=4.3-4.5 , and an interlayer spacing of 4-6 , and is characterized by a high photoelectric response rate, an adjustable semiconductor type, and the like. The two-dimensional black phosphorus PN junction includes a two-dimensional black phosphorus film, a first area of the film forming an n-type semiconductor by n-type doping, a second area of the film is maintained as a p-type semiconductor, and the first area is adjacent to the second area, to enable the n-type semiconductor to be combined with the p-type semiconductor to form the PN junction. The two-dimensional black phosphorus PN junction has properties such as a unidirectional conductivity, or a special photovoltaic effect.

A device for producing black phosphorus which includes a reactor having one end connected to a feeding pipe and another end connected to a discharge pipe; a propeller blade unit including a rotating shaft mounted between the two ends of the reactor and a blade element mounted on the rotating shaft; a motor connected to the rotating shaft for controlling a rotation speed of the blade element; a heating device enclosing the reactor at an outer side and defines the reactor into a plurality of heating zones; and an inert gas input connected to the discharge pipe. The device is simple and safe in operation, can optimize the production process at low cost, and has high level of automation, thus facilitating a continuous production of black phosphorus under normal pressure.

A device for producing black phosphorus which includes a reactor having one end connected to a feeding pipe and another end connected to a discharge pipe; a propeller blade unit including a rotating shaft mounted between the two ends of the reactor and a blade element mounted on the rotating shaft; a motor connected to the rotating shaft for controlling a rotation speed of the blade element; a heating device enclosing the reactor at an outer side and defines the reactor into a plurality of heating zones; and an inert gas input connected to the discharge pipe. The device is simple and safe in operation, can optimize the production process at low cost, and has high level of automation, thus facilitating a continuous production of black phosphorus under normal pressure.

A method of producing black phosphorus which includes the steps of: weighing and mixing reaction raw materials which comprises metallic tin, red phosphorus and monocrystalline iodine, wherein a weight ratio of tin: red phosphorus: iodine is 0.6-3.5: 5-45: 0.1-0.8; feeding the mixture to a high-temperature resistant metal reaction tube; removing air by introducing inert gas and sealing the reaction tube tightly; placing the metal reaction tube inside a muffle furnace for carrying out calcination reaction by first increasing a temperature at a preset rate to a maximum temperature and keeping warm and then decreasing a temperature at a preset rate and keeping warm, then to room temperature so that the black phosphorus is produced. The conversion rate is very high and the quality of the produced product is classified as high quality.